[PDF] Top 20 (Cyclopentadienone)iron shvo complexes : synthesis and applications to hydrogen transfer reactions
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(Cyclopentadienone)iron shvo complexes : synthesis and applications to hydrogen transfer reactions
... the transfer of hydrogen atoms between organic molecules, in order to produce a convenient liquid fuel from alcohols available in biomass residues ...metal complexes for this purpose is well ... See full document
30
Synthesis and applications to catalysis of novel cyclopentadienone iron tricarbonyl complexes
... ee. Reactions at slightly lower temperatures (60 °C and 40 °C) resulted in lower conversions, and the reduction of a series of acetophe- none derivatives were also ... See full document
21
Iron cyclopentadienone complexes derived from C2 symmetric bis propargylic alcohols; preparation and applications to catalysis
... the synthesis of complexes and cata- lytic reactions were degassed prior to use and all reactions were carried out under either a nitrogen or argon ...baths. Reactions were monitored by ... See full document
15
Asymmetric ruthenium tricarbonyl cyclopentadienone complexes ; synthesis and application to asymmetric hydrogenation of ketones
... Metal complexes of cyclopentadienones, notably ruthenium [1] and iron [2] derivatives of general structure 1 and 2, have been applied as catalysts in hydrogen transfer reactions [3], ... See full document
7
Iron and ruthenium catalysts for hydrogen transfer reactions
... the iron pentacarbonyl reagent could take place and inhibit the cycloaddition ...two reactions were carried out; In one reaction compound 124 was reacted with one equivalent of iron pentacarbonyl ... See full document
249
The use of (cyclopentadienone)iron tricarbonyl complexes and ruthenium complexes for hydrogen transfer reactions
... the iron complex present and the air instability of the activated iron complex caused all catalytic iron species to decompose upon reaction work up, producing only low polarity impurities to remain ... See full document
152
Ether tethered Ru(ii)/TsDPEN complexes : synthesis and applications to asymmetric transfer hydrogenation
... employed in ATH reactions, in common with related complexes which are directly converted from their dimer forms to monomers in situ under ATH conditions (FA/TEA). 8a,e,f The formation of monomer 5 using ... See full document
10
Synthesis, characterization, applications, and challenges of iron oxide nanoparticles
... environment, iron oxide soluble in an aqueous solution and in colloidal form is the main consideration when selecting synthesis ...soluble iron oxide NPs directly, the slow crystallization and the ... See full document
19
Synthesis, Crystal Structure and Infrared Characterization of Bis(4 dimethylamino pyridinium) Tetrachlorocuprate
... Non-covalent interactions, such as hydrogen bonding and π-π stacking, play a very prominent role in the organiza- tion of structural units in both biochemistry and material science [1]-[3]. These weak interactions ... See full document
11
Synthesis and Reactivity of Ruthenium and Platinum Amido and Carbene Complexes: Application Toward Carbon-Nitrogen Bond Forming Reactions
... imido-oxo complexes, metallacyclization and imine metathesis using zirconocene imido complexes and C-H activation using titanium and zirconium imido ...imido complexes, especially monomeric, are ... See full document
254
Part 1 Design, Synthesis, and Validation of Polymer-Supported Siloxane Transfer Agents for Transition-Metal-Mediated Cross-Coupling Reactions of Organolithiums Part 2 Total Synthesis of (-)-Mandelalide a Exploiting Anion Relay Chemistry
... siloxane transfer agents for use in the cross- coupling reactions of organolithium ...the transfer agent tactic was expanded for the construction for carbon-nitrogen ...and synthesis, we have ... See full document
403
Synthesis and Spectroscopic Characterization of Iron Complexes with Bidentate Schiff’s Base Ligands Derived from 2-Benzoylpyridine, 2-Benzoylthiophene and Thiosemicarbazone, Semicarbazone, and their Biological Activity
... of iron (III) is less, because of much greater tendency of the trivalent ion to have charge transfer bands in the near UV region with strong low energy wings in the visible that obscure the very weak, spin ... See full document
8
METAL COMPLEXES OF RIBAVIRIN; SYNTHESIS, CHARACTERIZATION AND IN VITRO BIOLOGICAL SCREENING
... Medicinal applications of metals and its compound were reported centuries ago but it gained huge appreciation after the discovery of anticancer activity of metal based drug ...metal complexes, giving birth ... See full document
7
Oxidative Desulfurization of kerosene in the presence of iron chlorideionic liquid catalyst and ultrasound waves
... with iron chloride - hydrogen peroxide and ultra sonic liquid catalysts in the presence of acetic acid - formic acid and an oxidizing hydrogen peroxide has been ...from iron chloride catalyst ... See full document
5
Synthesis and Characterization of Nanostructured Materials for Hydrogen Storage Applications
... The top-down approach consists of building nanomaterials moving from top (larger) to bottom (smaller). NPs are synthesized by breaking down bulk materials gradually into smaller sizes, e.g. by using high-energy ball ... See full document
164
Versatile Applications of Metal/Mixed Metal Oxides as Superconductors
... various applications as catalyst, photocatalyst, sensors, superconductors, adsorbent, ceramics, fuels, antifungal agents and have large number of applications in ...their applications as ... See full document
10
Synthesis and Reactivity of Ruthenium and Platinum Complexes with Non-dative Heteroatomic Ligands: Studies of Carbon-hydrogen Bond Activation
... initial interaction of alkane with Pt(II) to give an alkane complex (Scheme 4.1). 126 The alkane complex can lead to oxidative addition of the alkane (i.e., metal insertion into the C-H bond) with subsequent loss of a ... See full document
224
Synthesis of Polyamide [1,3-Dicarboxymethoxy Benzene and Proplenediamine] Complexes with Lead, Iron and Copper
... its complexes measuresd using the Nujol mull technique, show mainly the charge transfer band of the free molecule at 25974 cm –1 whil Pb 2+ complex ... See full document
6
Synthesis and Characterization of Transition Metal Complexes for Oxidation, Reduction, and Carbonylation Reactions.
... the complexes with ligand sets that have a furan ring in the backbone (DAF, DMDAF, TMSDAF, DOF) are significanly lowered (Entries ...13) complexes to obtain useful kinetic data to make any ... See full document
259
Thermodynamic Properties of Organometallic Dihydrogen Complexes for Hydrogen Storage Applications
... bind hydrogen to the material surface through van der Waals ...between hydrogen gas and a solid material. The bonds formed between hydrogen and the solid in these materials are typically made over ... See full document
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