[PDF] Top 20 Diaquabis(1,10 phenanthroline)cobalt(II) diorotate 2 25 hydrate
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Diaquabis(1,10 phenanthroline)cobalt(II) diorotate 2 25 hydrate
... Orotic acid (uracil-6-carboxylic acid, vitamin B13) and its metal-ion complexes play a crucial role in the metabolism of pyridine nucleotides and in many living organisms (Lalioti et al., 1998). Its metal-ion complexes ... See full document
11
Bis(2,5 dihydroxybenzoato κO)bis(1,10 phenathroline κ2N,N′)cadmium(II) 1 25 hydrate
... C30 0.058 (2) 0.046 (2) 0.062 (3) −0.0027 (19) 0.010 (2) 0.000 (2) C31 0.049 (2) 0.044 (2) 0.032 (2) −0.0084 (17) −0.0033 (18) 0.0103 (18) C32 0.042 (2) 0.054 ... See full document
12
catena Poly[[bis(pyridine κN)cobalt(II)] μ oxalato] 0 25 hydrate]
... The molecular structure of the asymmetric unit of (I), showing the atom- labeling scheme. To indicate bonding continuity, several atoms of adjacent units related by inversion at the centers of the oxalate CÐC bonds are ... See full document
7
Di μ acetato μ aqua bis[acetatobis(1H benzimidazole)cobalt(II)]
... benzimidazole, cobalt acetate tetrahydrate and oxalic acid dihydrate in methanol which was left to evaporate over five days at room ...(Fig. 2, Table ...(Fig. 2, Table ... See full document
9
catena Poly[[[diaqua(2 sulfonatobenzoato)nickel(II)] μ 1,2 di 4 pyridylethylene] 0 25 hydrate]
... with 2-sulfonatobenzoate (o-sb), a ligand with a combination of sulfonate and carboxylate groups, are rather limited (Li & Yang, 2004; Su et ...{[Ni(o-sb)(bpe)(H 2 O) 2 ]0.25H 2 O} (bpe is ... See full document
8
2′,6′ Bis(4 carboxyphenyl) 4,4′ bipyridin 1 ium nitrate 0 25 hydrate
... In the title compound (Fig. 1), the central pyridine ring of the cation is almost coplanar with one benzene ring, making a dihedral angle of 1.03 (5)°, while it makes dihedral angles of 9.59 (5)° with the other ... See full document
9
Bis[tetraaqua(1,10 phenanthroline κ2N,N′)cobalt(II)] 1,2,4,5 benzenetetracarboxylate
... of cobalt(II) acetate tetrahydrate (25 mg, ...ethanol/water, 25:75) of sodium 1,2,4,5-benzenetetracarboxylate (34 mg, ...and phenanthroline (18 mg, ...CoN 2 O 8 : C ... See full document
8
Bis(benzimidazole)bis(4 hydroxybenzoato)cobalt(II) 0 25 hydrate
... (C33) to 3.750 (5) A ˚ (C35) [average distance = 3.724 (6) A˚]. These are identical to the van der Waals thickness of the benzene ring and suggest there is little, if any, significant – stacking interaction between the ... See full document
9
Bis{1 [3 (cyclohexylaminio)propyliminomethyl] 2 naphtholato}nickel(II) dichloride 1 24 hydrate
... Ni II atom is four-coordinated in a square-planar geometry by two imine N and two phenolate O atoms from two Schiff ...(Table 1) subtended at the Ni II centre are comparable with the values observed ... See full document
11
Bis[2 (cyclohexyliminomethyl) 4 nitrophenolato]cobalt(II)
... mononuclear cobalt(II) compound (Fig. 1), which is isostructural with the zinc compound bis[2-(cyclo- hexyliminomethyl)-4-nitrophenolato]zinc(II) (You, 2005), and structurally ... See full document
9
Bis[1 hydroxyethylidenediphosphonato(1−)](1,10 phenanthroline)nickel(II) monohydrate
... P1 0.0134 (5) 0.0183 (5) 0.0165 (5) 0.0021 (4) −0.0013 (4) −0.0034 (4) P2 0.0128 (5) 0.0219 (6) 0.0124 (5) 0.0008 (4) −0.0010 (4) −0.0011 (4) O3 0.0180 (13) 0.0239 (15) 0.0156 (14) 0.0043 (11) 0.0016 (11) −0.0013 (11) O4 ... See full document
7
Aquadicrotonato(di 2 pyridylamine)cobalt(II)
... C13 0.085 (3) 0.059 (2) 0.072 (2) −0.0010 (18) 0.0074 (18) −0.0033 (16) C14 0.133 (4) 0.057 (2) 0.098 (3) 0.024 (2) 0.007 (3) 0.0036 (18) C15 0.092 (3) 0.0445 (17) 0.054 (2) 0.0105 (17) ... See full document
9
Bis{1 [(E) 2 pyridinylmethylidene]semicarbazide}cobalt(II) diperchlorate monohydrate
... The Schiff base of pyridine-2-carbaldehyde semicarbazone was prepared according to Gong et al. (1994). Single crystals of the title complex suitable for X-ray crystallographic analysis were obtained by ... See full document
9
Bis[tris(1,10 phenanthroline)nickel(II)] tris[dicyanidoargentate(I)] nitrate 4 2 hydrate
... Mixed-ligand metal complexes of 1,10-phenanthroline (phen), and its substituted derivatives, are also interesting because they play an important role in biological systems, such as binding small molecules to DNA ... See full document
13
Di μ hydroxo bis[aqua(1,10 phenanthroline κ2N,N′)copper(II)] dinitrate hexahydrate
... is shorter than in both reported compounds (see Table 3). The hydrogen-bonding geometry in (I) is listed in Table 2 and illustrated in Figs. 1 and 2. The nitrate anions, coordinated water molecules ... See full document
8
Aqua(1,10 phenanthroline)(thiodiglycolato)cobalt(II)
... In the title compound, (I), the coordination polyhedron around the Co atom can be described as a distorted octa- hedron consisting of two N-atom donors from a 1,10-phen- anthroline, one O atom from the water molecule and ... See full document
9
Bis[μ 3 phosphonopropionato(2–)]bis[aqua(1,10 phenanthroline)copper(II)]
... were located and re®ned, with distance restraints of OÐH = 0.85 (1) and H H = 1.38 (1) AÊ. The aliphatic and aromatic H atoms were placed in calculated positions and re®ned using a riding model, with CÐH ... See full document
7
Bis{1 [3 (cyclohexylamino)propyliminomethyl]naphth 2 olato}cobalt(II) tetrahydrate
... Atoms H2, H2A, H3A and H3B were located in a difference Fourier map and refined isotropically, with the N—H distance restrained to 0.90 (1) A ˚ , the O—H distance restrained to 0.85 (1) A˚ and the H H ... See full document
8
μ Aqua bis(μ 2′ carboxybiphenyl 2 carboxylato κ2O:O′)bis[bis(2′ carboxybiphenyl 2 carboxylato κO)(1,10 phenanthroline κ2N,N′)cobalt(II)]
... 0.20 g), 1,10-phenanthroline (3 mmol, 0.54 g) and water (20 ml) in a 30 ml Te¯on-lined stainless steel reactor. The solution was heated to 420 K for 3 d. After the reaction system had been slowly cooled to room ... See full document
10
μ Aqua κ2O:O di μ phenylacetato κ4O:O′ bis[(1,10 phenanthroline κ2N,N′)(phenylacetato κO)cobalt(II)]
... Co II atom shows an approximate octahedral geometry, with three carboxylate O atoms from different phenylacetate ligands, two N atoms from 1,10-phenanthroline ligands and one water ... See full document
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