• No results found

[PDF] Top 20 Synthesis and Reactivity of Ruthenium Amine and Amido Complexes.

Has 10000 "Synthesis and Reactivity of Ruthenium Amine and Amido Complexes." found on our website. Below are the top 20 most common "Synthesis and Reactivity of Ruthenium Amine and Amido Complexes.".

Synthesis and Reactivity of Ruthenium Amine and Amido Complexes.

Synthesis and Reactivity of Ruthenium Amine and Amido Complexes.

... their synthesis has been an area of significant study (Figure ...the synthesis of marine alkaloids has been an area of significant interest due to their high biological ... See full document

425

Synthesis and Reactivity of Ruthenium and Platinum Amido and Carbene Complexes: Application Toward Carbon-Nitrogen Bond Forming Reactions

Synthesis and Reactivity of Ruthenium and Platinum Amido and Carbene Complexes: Application Toward Carbon-Nitrogen Bond Forming Reactions

... II amido complexes exhibit reactivity consistent with highly basic amido ...such amido ligands can be combined with the activating ability of a Lewis acidic site on the metal center to ... See full document

254

(Benzo­phenone imine N)­nona­carbonyldirhenium(0)(Re—Re)

(Benzo­phenone imine N)­nona­carbonyldirhenium(0)(Re—Re)

... the synthesis and reactivity of late-transition-metal amido complexes has grown considerably in recent years as a consequence of the relative scarcity of such compounds and of their potential ... See full document

9

Synthesis, Characterization, and Reactivity of Monomeric Copper(I) Complexes Possessing pi-Donor Ligands.

Synthesis, Characterization, and Reactivity of Monomeric Copper(I) Complexes Possessing pi-Donor Ligands.

... actinide) amido complexes have been shown to catalyze hydroamination of olefins by this ...the amido ligand can occur via proton transfer from the amine to a metal ligand, such as an alkyl ... See full document

203

Synthesis and Reactivity of Ruthenium Alkyl and Aryl Complexes and Their Application towards Aromatic C-H Bond Activation and Olefin Hydroarylation

Synthesis and Reactivity of Ruthenium Alkyl and Aryl Complexes and Their Application towards Aromatic C-H Bond Activation and Olefin Hydroarylation

... contrast, following insertion of an α-olefin into the Ru-Ph bond, β-hydride elimination and olefin dissociation are competitive with catalytic hydrophenylation of the olefin. The similarities between catalytic olefin ... See full document

190

Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands

Synthesis and Characterization of Ruthenium(II) and Platinum(IV) Complexes with Anionic Heteroatomic Ligands

... The amalgam of studies suggest that one mode of C-H activation for by late transition metal systems with alkoxo or amido ligands is an intramolecular proton transfer (IPT). 87 This process occurs by initial ... See full document

110

Bipyrimidine ruthenium(II) arene complexes : structure, reactivity and cytotoxicity

Bipyrimidine ruthenium(II) arene complexes : structure, reactivity and cytotoxicity

... RNA synthesis by T7 RNA polymerase on the NdeI/HpaI fragment containing adducts of Ru II arene complexes and ...arene complexes 1 at r b = ... See full document

63

Synthesis and Reactivity or Ruthenium(II) and Platinum(IV) complexes

Synthesis and Reactivity or Ruthenium(II) and Platinum(IV) complexes

... Homogeneous single-site catalysts have had a significant impact on the commodity chemical industry as well as fine chemical synthesis in the past few decades. In general, characteristics of efficient catalyst ... See full document

132

Design, synthesis and activation of ruthenium arene anticancer complexes

Design, synthesis and activation of ruthenium arene anticancer complexes

... the synthesis of titanocene derivatives 43,44,45 with bridged-cyclopentadienyls (ansa- titanocenes) and non-bridged organotitanium titanocenes 46 which have shown in vivo activity against A431 and PC-3 xenografts, ... See full document

397

Synthesis and Characterization of the Peroxo Complexes of Uranium (VI) Containing Organic Acids and Amine Bases Ligands

Synthesis and Characterization of the Peroxo Complexes of Uranium (VI) Containing Organic Acids and Amine Bases Ligands

... peroxo complexes were found to liberate iodine within 1-2 minutes on treatment with aqueous potassium ...possible reactivity of the complexes towards olefinic compounds could be ... See full document

6

Synthesis and Reactivity of Ruthenium and Platinum Complexes with Non-dative Heteroatomic Ligands: Studies of Carbon-hydrogen Bond Activation

Synthesis and Reactivity of Ruthenium and Platinum Complexes with Non-dative Heteroatomic Ligands: Studies of Carbon-hydrogen Bond Activation

... initial interaction of alkane with Pt(II) to give an alkane complex (Scheme 4.1). 126 The alkane complex can lead to oxidative addition of the alkane (i.e., metal insertion into the C-H bond) with subsequent loss of a ... See full document

224

Ruthenium Complexes Bearing N-Heterocyclic Carbene (NHC) Ligands183-188

Ruthenium Complexes Bearing N-Heterocyclic Carbene (NHC) Ligands183-188

... NHC ruthenium complexes, a very broad panel of total syntheses of natural products and biologically active complex molecules has been ...total synthesis (Scheme III) of (-)- nakadomarin A, 1, a ... See full document

6

Synthesis and Characterization of Metal-B-diketonate Coordination Complexes and Polymers

Synthesis and Characterization of Metal-B-diketonate Coordination Complexes and Polymers

... [11]. Complexes 3 - 5 can be extended to infinite metal-organic coordination polymers of [M(tba) 2 (4,4'-bipy)] n (6: M = Mn, 7: M = Ni, 8: M = Zn; tba = ... See full document

5

Synthesis and Characterization of New Ruthenium Nitrosyl Complexes from [RuCl2L2(PPh3)2] (L = Acetonitril, Acrylonitril, Isobutyronitril, N-benzonitril, Pyridine, Malonitril and Succinonitril)

Synthesis and Characterization of New Ruthenium Nitrosyl Complexes from [RuCl2L2(PPh3)2] (L = Acetonitril, Acrylonitril, Isobutyronitril, N-benzonitril, Pyridine, Malonitril and Succinonitril)

... the complexes [RuCl 2 (NO)L(PPh 3 ) 2 ] (L= aceto nitrile, acrynitrile, isobutyronitrile, n-butyronitrile, benzonitrile and pyridine) and [RuCl 2 (NO)L 2 (PPh 3 ) 4 ] (L= malonitrile and succinonitrile) were ... See full document

7

Synthesis and characterisation of metal complexes of orthovanillin thiosemicarbazone

Synthesis and characterisation of metal complexes of orthovanillin thiosemicarbazone

... thermogravimetric (DTG) and differential thermal analysis (DTA) curves of the samples were obtained from a Perkin Elmer Diamond simultaneous TG/DTA analyser. A constant heating rate of 100C/min and sample mass of 2 mg to ... See full document

8

Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands

Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands

... Three new chiral monoanionic [ON] ancillary phenolate ligands with varying pendant arms have been synthesized in moderate to high yields (50% - 85%) via Mannich-type condensation reaction of chiral substituted phenol, ... See full document

8

Synthesis and Characterization of Phosphine and Arsine Complexes of Ruthenium (Ii & Iii) Ligated With 3-(4-Pyridyl)-4-Substituted-Triazoline-5-Thione

Synthesis and Characterization of Phosphine and Arsine Complexes of Ruthenium (Ii & Iii) Ligated With 3-(4-Pyridyl)-4-Substituted-Triazoline-5-Thione

... Organometallic complexes of ruthenium (II & III) with the formula [RuH(CO)(E 3 ) 2 L] and [RuCl 2 (E 3 ) 2 L] (E = P/As; L = deprotonated mononegative bidentate 3-(4-pyridyl)-triazoline-5- thione and ... See full document

7

Aqua­(pyridine N oxide κO)[tris­(2 hy­droxy­amino­propyl)­amine κ4N]­nickel(II) dinitrate

Aqua­(pyridine N oxide κO)[tris­(2 hy­droxy­amino­propyl)­amine κ4N]­nickel(II) dinitrate

... center bound to four ligand N atoms from three oximes and one amine. One water and a pyridine N-oxide, bound in a monodentate fashion through the O atom, complete the octahedral coordination. Complex (I) contains ... See full document

8

Hydroxide complexes of the late transition metals : organometallic chemistry and catalysis

Hydroxide complexes of the late transition metals : organometallic chemistry and catalysis

... Several examples of gold hydroxide complexes supported by other ligand types have been discosed. A bis(2‐pyridylimino)isoindole (BPI) gold(III) chloride complex has been prepared, and could be converted to the ... See full document

34

Synthesis and Characterisation of Glimeperide Complexes of Copper, Magnesium, Nickel and Cadmium

Synthesis and Characterisation of Glimeperide Complexes of Copper, Magnesium, Nickel and Cadmium

... For determining the ligand-metal ratio, molar solutions were prepared of metal salts and ligand in 1:2 ratio and conductometric titrations were carried out by using monovariation method which indicates that all the four ... See full document

7

Show all 10000 documents...