• No results found

Clinkerization Overview

In document Cement Process Chemistry (Page 44-72)

Main Aim of this section is to produce Clinker from Raw meal in energy efficient manner

Kiln Operation can be in following mode

Wet Process : Kiln Feed Water 30 - 40%

Semi Dry/Wet process

Dry Process : Kiln Feed Water 2 - 3%

The choice of the process to be used depends upon a complex combination of different factors This includes:

The nature of the raw materials.

The thermal efficiency of the different processes and their variations

fuel and other energy prices

Clinkerization Overview

Three sections in Dry Process

Preheater :

Preheat the Kiln feed Using Waste Heat Gas

Calcination Using Waste heat gas & Coal in Calciner

Kiln :

Clinker Formation from Calcined Kiln feed using Coal fuel.

Cooler :

Heat Recovery from Hot Clinker

Cooling Clinker rapidly to form reactive clinker

Clinkerization Overview

Reactions - Heating

30 - 300

Evaporation of Water

400 - 900

Removal of structural water and OH group from clay minerals

Clacination

above 800

Formation of C2S , intermediate product , aluminate , ferrite

above 1250

Formation of liquid phase (aluminate & Ferrite melt)

Crystalization of Alite ,Belite I.e Completion of phase formation

Clinkerization Overview

Reactions - Cooling

1300 - 1240

Crystalization of liquid phase into mainly aluminate & ferrite

Clinkerization Overview

Clinkerization Overview

Liquid &

Phase

CaO + SiO2 -> CaO.SiO2

CaO.SiO2 + CaO -> (CaO)2.SiO2 (CaO)2.SiO2 + CaO -> (CaO)3.SiO2

(CaO)3.(Al2O3) --- C3A (CaO)4.(Al2O3).Fe2O3--- C4AF

Preheater

Different Type of Preheater System

4 , 5 , 6 stage ,One string - With or Without Calciner

4 , 5 stage ,Two String - Calciner String , Kiln String

4, 5 stage ,Two string - Both Calciner String

Typical : 5 stage , Two String - Calciner & Kiln String

More Stages gets added in Preheater String

More Heat Recovery from Waste Heat Gas

More Capital Cost

Less Temperature For Raw Mill Grinding

Preheater

Aim

Maximum Heat Recovery from waste heat gas

Maximum Calcination without melting raw meal

Operational Philosophy

Heat exchange between Waste Heat Gas & Raw Meal takes place through Direct Heat Exchange in Riser Duct

Separation of Raw Meal Solid from Gas is carried out in Cyclone at each stage.

Maximum Calcination is carried out in Pre-Calciner by burning Coal.

Preheater

Process

Gas enters from bottom cyclone

Raw meal enters from top cyclone

Gas is sucked by induced draft fan from kiln

Fan is placed at Preheater Outlet

From Last but One cyclone raw meal goes to Pre-Calciner where coal is fired

Tertiary air is sucked in Calciner from cooler

After Pre-Calciner Raw meal is carried to last cyclone by air & Separated raw meal from this cyclone goes to Kiln

Preheater

Major Operating Parameter

PHOutlet Temp : Heat Recovery

PHOutlet CO : ESP security, Oxygen Shortage

Calciner Outlet Temp : Completion of Calcination

Kiln inlet Material Temp : Material Fusion Temp

PHOutlet Draft / O2 : Excess Air , Leakage

Cyclone Cone Draft : Cyclone Jamming

Handles

PHOutlet Fan Damper /RPM : Air Quantity

Calciner Coal : Heat Quantity

Preheater

MV-CV Relation

Preheater

Abnormal Conditions & control

High PHOutlet CO

Cause:

– Less Oxygen for Coal Combustion – High Calciner Coal Feed rate

Control:

– Cut Calciner Coal

– Increase PHFan RPM or Damper

Preheater

Abnormal Conditions & control

High Kiln inlet material temp

Cause :

– High Calciner Coal Feed rate – Less Raw Meal Rate

– Secondary Burning of Coal in preheater

Control:

– Cut Calciner Coal

Preheater

Abnormal Conditions & control

High Calciner Outlet temp

Cause :

– High Calciner Coal Feed rate – Less Raw Meal Rate

Control:

– Cut Calciner Coal

Preheater

Abnormal Conditions & control

Low Cyclone cone draft

Cause :

– Less Air

– Coating in cyclone

– Brick lining failure , Flap damper Malfunction

Control:

– Cut Raw Meal Feed Rate

Kiln

Aim

Maintain Clinker Quality

Minimize Heat Consumption

Operational Philosophy

Heat is generated by Coal combustion

High residence time i.e. 20 min

High Temp 1500oC

Maximum Contact area of Hot air & Material by circulatory motion (4 rpm)

Kiln

Process

Kiln is cylindrical rotating furnace (60 m length) &

installed slightly slant (3-4degree) to carry the material to lower end when rotating.

At Lower end is the burner where coal is fired through using primary air for conveying.

Cooler Secondary air is sucked into Kiln which is at high temp ( Due to heat recuperation from hot clinker ).

Secondary Air from Cooler & Primary Air gets heated by combustion of coal.

This air travels opposite to material flow & Heat Exchange between air & material takes place

Kiln

Major Operating Parameter

Kiln Torque : Clinker Quality

Burning Zone Temp. : Good Heat Content

Clinker Lt..wt. & Free Lime : Clinker Quality

Kiln Hood Draft : Safety & Maintenance

Kiln inlet CO or O2 : Oxygen Availability

Handles

Kiln Feed

Kiln RPM

Kiln Coal

Kiln

Clinker Quality

Clinker Phase Requirement

C3 S (Alite) - 40 to 60% :Rapid Contribution to strength C2 S (Belite) - 20 to 30% : Slow Contribution to strength C3 A - 5 to 12% : Rapid Contribution to strength C4 AF - 5 to 12% : V. Slow Contribution to strnth

Indirect/Direct Measurement of Good Clinker

Litre Weight (density) - Represent phase%

Free Lime (CaO) - Should be minimized

Kiln

Clinker Quality

Affecting Parameters

Degree of Kiln feed mixing

Kiln Feed Granulometry

Burnability of kiln feed

Degree of heating

Retention time

Clinker Cooling Rate

Kiln

MV-CV Relation

Kiln

Abnormal Conditions & control

High Kiln inlet CO

Cause :

– Less Air

– More Kiln Coal

Control:

– Cut Kiln Coal

– Increase PH fan RPM / Open Damper

Kiln

Abnormal Conditions & control

LOW kiln Torque/ Dusty Kiln

Cause :

– Less Heat Content in Kiln – High Kiln filling

Control:

– Reduce Kiln RPM & Increase Kiln Coal – Decrease Kiln Feed

Kiln

Abnormal Conditions & there control

Red Spot

Cause :

– Coating Deformation – Brick dislodging

Control:

– Reduce Kiln RPM – Stop Kiln

Cooler

Aim

Recuperate Maximum Heat from Clinker

Maintain Clinker Quality

Minimize Clinker Temperature

Operational Philosophy

Maximum Heat Recuperation in first few compartments is achieved by keeping high bed height of Clinker

Lower Clinker temperature is achieved in last few compartments by Low Clinker bed height & High Air volume

Cooler

Process

Types Of Cooler

Reciprocating Grate Cooler

– Perforated Grates moving one over other creating forward motion for clinker.

– Air with high velocity flows vertically up 90 degree to Clinker flow.

IKN Cooler

– Grates Doesn’t move. Forward motion for clinker is created by Horizontal Air Jet with very high velocity.

– Air with very high velocity flows parallel to Clinker flow & then moves vertically up.

Cooler

Major Operating Parameter

Under-Grate Pressure : Clinker Bed

Grate Drive Amps : Clinker Bed

Clinker Temperature : Clinker property , Safety

Secondary Air Temp. : Recuperation

Hood Draft : Safety

Cooler Vent Temperature : Heat Loss

Handles

Air Volume / Fan Damper / Fan RPM

Grate Drive Speed

Vent fan Damper / RPM

Cooler

MV-CV Relation

Cooler

Abnormal Conditions & control

Grate Drive Amps High

Cause :

– High Clinker Bed Height – Lumps

Control:

– Increase Grate Speed

In document Cement Process Chemistry (Page 44-72)

Related documents