In accordance with Annex II of Regulation (EC) nº1907/2006 (point 3), the product contains:
Components:
Peroxide/s Chemical description:
Mixture:
3.2
Non-applicable
Concentration Chemical name/Classification
Identification
25 - <50 % Acute Tox. 4: H302; Eye Dam. 1: H318; Org. Perox. D: H242; Skin Corr. 1B: H314
-Danger Regulation 1272/2008
Self-classified 2-Butanone, peroxide
25 - <50 % Aquatic Chronic 3: H412
Regulation 1272/2008
Self-classified 1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
10 - <25 % Eye Irrit. 2: H319 - Warning
Regulation 1272/2008
ATP CLP00 4-hydroxy-4-methylpentan-2-one
To obtain more information on the risk of the substances consult sections 8, 11, 12, 15 and 16.
SECTION 4: FIRST AID MEASURES
Non-applicable
Indication of any immediate medical attention and special treatment needed:
4.3
Acute and delayed effects are indicated in sections 2 and 11.
Most important symptoms and effects, both acute and delayed:
4.2
Request immediate medical assistance, showing the SDS of this product. Do not induce vomiting, because its expulsion from the stomach can be hazardous to the mucus of the main digestive tract, and its inhalation, to the respiratory system. Rinse out the mouth and throat, as they may have been affected during ingestion. In the case of loss of consciousness do not administrate anything orally unless supervised by a doctor. Keep the person affected at rest.
By ingestion/aspiration:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes.
If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, as this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the product.
By eye contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will increase the risk of infection.
By skin contact:
This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse or persist.
By inhalation:
Request medical assistance immediately, showing the SDS of this product.
Description of first aid measures:
4.1
SECTION 5: FIREFIGHTING MEASURES
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and, consequently, can present a serious health risk.
Special hazards arising from the substance or mixture:
5.2
Product is non-flammable under normal conditions of storage, manipulation and use. In the case of inflammation as a result of improper manipulation, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an extinguishing agent.
Extinguishing media:
5.1
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-1338-23-4 215-661-2 Non-applicable 01-2119514691-43-XXXX CAS:EC:
Index:
REACH:
6846-50-0 229-934-9 Non-applicable 01-2119451093-47-XXXX CAS:
EC:Index:
REACH:
123-42-2 204-626-7 603-016-00-1 01-2119473975-21-XXXX CAS:
EC:
Index:
REACH:
SECTION 5: FIREFIGHTING MEASURES (continued)
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other emergencies. Destroy any source of ignition. In case of fire, refrigerate the storage containers and tanks for products susceptible to inflammation, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an aqueous medium.
Additional provisions:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and individual respiratory equipment.
Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance with Directive 89/654/EC.
Advice for firefighters:
5.3
SECTION 6: ACCIDENTAL RELEASE MEASURES
See sections 8 and 13.
Reference to other sections:
6.4
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible absorbents. For any concern related to disposal consult section 13.
It is recommended:
Methods and material for containment and cleaning up:
6.3
Avoid at all cost any type of spillage into an aqueous medium. Contain the product absorbed appropriately in hermetically sealed containers. Notify the relevant authority in case of exposure to the general public or the environment.
Environmental precautions:
6.2
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have protection.
Personal precautions, protective equipment and emergency procedures:
6.1
SECTION 7: HANDLING AND STORAGE
24 Months Maximum time:
50 ºC Maximum Temp.:
5 ºC Minimum Temp.:
Technical measures for storage
A.-Conditions for safe storage, including any incompatibilities:
7.2
Due to the danger of this product for the environment it is recommended to use it within an area containing contamination control barriers in case of spillage, as well as having absorbent material in close proximity.
Technical recommendations to prevent environmental risks
D.-Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
Technical recommendations to prevent ergonomic and toxicological risks
C.-Product is non-flammable under normal conditions of storage, manipulation and use. It is recommended to transfer at slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on conditions and materials that should be avoided.
Technical recommendations for the prevention of fires and explosions
B.-Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the container. Maintain order and cleanliness where dangerous products are used.
Precautions for safe manipulation
A.-Precautions for safe handling:
7.1
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this product.
Specific end use(s):
7.3
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5 General conditions for storage
B. CONTINUED ON NEXT PAGE B.
-SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Substances whose occupational exposure limits have to be monitored in the work environment Control parameters:
8.1
DNEL (Workers):
There are no occupational exposure limits for the substances contained in the product
Local
DNEL (General population):
Local
1-isopropyl-2,2-dimethyltrimethylene diisobutyrate Oral
11,8 mg/m³ Sediment (Marine water)
Non-applicable Oral
0,019 mg/kg Sediment (Fresh water)
0,056 mg/L Sediment (Marine water)
83300000 g/kg Oral
1,15 mg/kg Sediment (Fresh water)
Non-applicable CAS: 6846-50-0 Soil
0,014 mg/L Fresh water
3 mg/L 1-isopropyl-2,2-dimethyltrimethylene diisobutyrate STP
0,91 mg/kg Sediment (Marine water)
Non-applicable Oral
9,06 mg/kg Sediment (Fresh water)
1 mg/L CAS: 123-42-2 Soil
2 mg/L
B.-As a preventative measure it is recommended to use basic Personal Protection Equipment, with the corresponding <<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more information see subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk prevention services as it is not known whether the company has additional measures at its disposal.
General security and hygiene measures in the work place
A.-Exposure controls:
8.2
The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded.
Specific protection for the hands
C. CONTINUED ON NEXT PAGE C.
-SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)
Remarks CEN Standard
Labelling PPE
Pictogram
The Breakthrough Time indicated by the manufacturer must exceed the period during which
the product is being used. Do not use protective creams after the product has come into contact
with skin.
EN 374-1:2003 EN 374-3:2003/AC:2006
EN 420:2003+A1:2009 NON-disposable chemical
protective gloves Mandatory hand
protection
Ocular and facial protection
D.-As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with total reliability and has therefore to be checked prior to the application
Remarks CEN Standard
Labelling PPE
Pictogram
Clean daily and disinfect periodically according to the manufacturer´s instructions. Use if there is a
risk of splashing.
EN 166:2001 EN 167:2001 EN 168:2001 EN ISO 4007:2012 Face mask
Mandatory face protection
Bodily protection
E.-Remarks CEN Standard
Labelling PPE
Pictogram
For professional use only. Clean periodically according to the manufacturer´s instructions.
EN 13034:2005+A1:2009 EN 168:2001 EN ISO 13982-1:2004/A1:2010 EN ISO 6529:2001 EN ISO 6530:2005
EN 464:1994 Disposable clothing for
protection against chemical risks
Mandatory complete body protection
Replace boots at any sign of deterioration.
EN ISO 20345:2011 EN 13832-1:2006 Safety footwear for
protection against chemical Mandatory foot risk
protection
Additional emergency measures
F.-Standards Emergency measure
Standards Emergency measure
DIN 12 899 ISO 3864-1:2002 Eyewash stations
ANSI Z358-1 ISO 3864-1:2002 Emergency shower
116,2 g/mol Average molecular weight:
6 Average carbon number:
103,16 kg/m³ (103,16 g/L) V.O.C. density at 20 ºC:
10 % weight V.O.C. (Supply):
With regard to Directive 2010/75/EU, this product has the following characteristics:
Volatile organic compounds:
In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental spillage of both the product and its container. For additional information see subsection 7.1.D
Environmental exposure controls:
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Colourless Colour:
Fluid Appearance:
Liquid Physical state at 20 ºC:
Appearance:
For complete information see the product datasheet.
Information on basic physical and chemical properties:
9.1
*Not relevant due to the nature of the product, not providing information property of its hazards.
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-SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)
Non-applicable * Refraction index:
Non-applicable * Surface tension at 20 ºC:
Other information:
9.2
Non-applicable * Upper flammability limit:
Non-applicable * Lower flammability limit:
423 ºC Autoignition temperature:
Non-applicable * Flammability (solid, gas):
61 ºC Flash Point:
Flammability:
Non-applicable * Oxidising properties:
Non-applicable * Explosive properties:
Non-applicable * Melting point/freezing point:
Non-applicable * Decomposition temperature:
Non-applicable * Solubility properties:
Non-applicable * Solubility in water at 20 ºC:
Non-applicable * Partition coefficient n-octanol/water 20 ºC:
Non-applicable * Vapour density at 20 ºC:
Non-applicable * pH:
Non-applicable * Concentration:
Non-applicable * Kinematic viscosity at 40 ºC:
15,57 cSt Kinematic viscosity at 20 ºC:
16,06 cP Dynamic viscosity at 20 ºC:
1,032 Relative density at 20 ºC:
1032 kg/m³ Density at 20 ºC:
Product description:
Non-applicable * Evaporation rate at 20 ºC:
316 Pa (0 kPa) Vapour pressure at 50 ºC:
52 Pa Vapour pressure at 20 ºC:
250 ºC Boiling point at atmospheric pressure:
Volatility:
Non-applicable * Odour threshold:
Characteristic Odour:
*Not relevant due to the nature of the product, not providing information property of its hazards.
SECTION 10: STABILITY AND REACTIVITY
Not applicable Avoid direct impact
Precaution Not applicable
Not applicable
Humidity Sunlight
Increase in temperature Contact with air
Shock and friction
Applicable for handling and storage at room temperature:
Conditions to avoid:
10.4
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
Possibility of hazardous reactions:
10.3
Chemically stable under the conditions of storage, handling and use.
Chemical stability:
10.2
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.
Reactivity:
10.1
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-SECTION 10: STABILITY AND REACTIVITY (continued)
See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions, complex mixtures of chemical substances can be released: carbon dioxide (CO2), carbon monoxide and other organic
compounds.
Hazardous decomposition products:
10.6
Avoid alkalines, heavy metals, reducing agents, peroxide
accelerating agents Precaution
Precaution Not applicable
Avoid direct impact
Others Combustible materials
Combustive materials Water
Acids
Incompatible materials:
10.5
SECTION 11: TOXICOLOGICAL INFORMATION
Non-applicable Other information:
Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Aspiration hazard:
H-- Specific target organ toxicity (STOT)H--repeated exposure: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Specific target organ toxicity (STOT)-repeated exposure:
G-Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Specific target organ toxicity (STOT) - single exposure:
F-- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous with sensitising effects. For more information see section 3.
- Cutaneous: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
Sensitizing effects:
E-- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for the effects mentioned. For more information see section 3.
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for this effect. For more information see section 3.
CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):
D-- Contact with the skin: Above all, skin contact may occur as fabrics of all thicknesses can be destroyed, resulting in burns.
For more information on the secondary effects see section 2.
- Contact with the eyes: Produces serious eye damage after contact.
Contact with the skin and the eyes (acute effect):
C-- Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified as dangerous for inhalation. For more information see section 3.
- Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory tract
Inhalation (acute effect):
B-- Acute toxicity : The consumption of a considerable dose can cause irritation in the throat, abdominal pain, nausea and vomiting.
- Corrosivity/Irritability: Corrosive product, its consumption causes burns destroying the full thickness of fabrics. For more information on the secondary effects of contact with the skin see section 2.
Ingestion (acute effect):
A.-In case of exposure that is repetitive, prolonged or at concentrations higher than recommended by the occupational exposure limits, it may result in adverse effects on health depending on the means of exposure:
Dangerous health implications:
The experimental information related to the toxicological properties of the product itself is not available Information on toxicological effects:
11.1
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