• No results found

CONCluDING REMARks

Ana Clarissa dos Santos Pires, Maria do Carmo Hespanhol da Silva, and

1.9 CONCluDING REMARks

Colloidal systems are present in many areas, including the food sector. In this chap-ter, the most important concepts and issues involving colloids from the point of view of food engineering and technology were presented.

We cited some examples within the chapter, aiming to clarify some aspects of colloids in a food system. We also presented some of the numerous studies, including issues and developments in the colloid world, applied to food research.

Foods are complex matrices, containing a lot of different ingredients. Many of these ingredients are in the colloidal state, making it of fundamental importance to understand colloid properties in order to obtain a deep knowledge of food systems.

In addition, as has been emphasized, one of the most important factors governing food shelf life is related to its colloidal stability.

Another important point is the increasing interest in fat replacement in food, as food researchers and technologists are asked to develop lighter and healthier products with the same quality and stability as their counterparts. This points out how relevant will be the knowledge of colloidal science and technology for food application.

Physical Chemistry of Colloidal Systems Applied to Food Engineering 23

ACkNOwlEDGMENTs

The authors wish to acknowledge the National Council of Technological and Scientific Development (CNPq) and the Foundation to Research Support of the Minas Gerais State (FAPEMIG) for their financial support.

REFERENCEs

Adamson, A.W. Physical Chemistry of Surfaces, 5th ed., John Wiley and Sons, Chichester, 1990, 777p.

Akartuna, I., Studart, A.R., Tervoort, E., Gonzenbach, U.T., Gauckler, L.J. (2008). Stabilization of oil-in-water emulsions by colloidal particles modified with short amphiphiles.

Langmuir, 24 (14), 7161–7168.

Birdi, K.S. Introduction to surface and colloid chemistry. In: Birdi, K.S. (ed) Handbook of Surface and Colloid Chemistry, 2nd ed., CRC Press, Boca Raton, FL, 2003a, pp. 11–14.

Birdi, K.S. Surface tension and interfacial tension of liquids. In: Birdi, K.S. (ed) Handbook of Surface and Colloid Chemistry, 2nd ed., CRC Press, Boca Raton, FL, 2003b, pp. 76–125.

Chuah, A.M., Kuroiwa, T., Kobayashi, I., Nakajima, M. (2009). Effect of chitosan on the sta-bility and properties of modified lecithin stabilized oil-in-water monodisperse emulsion prepared by microchannel emulsification. Food Hydrocolloids, 23 (3), 600–610.

Colafemmina, G., Fiorentino, D., Ceglie, A., Carretti, E., Fratini, E., Dei, L., Baglioni, P., Palazzo, G. (2007). Structure of SDS micelles with propylene carbonate as cosol-vent: a PGSE−NMR and SAXS study. Journal of Physical Chemistry B, 111 (25), 7184–7193.

Cruz-Silva, R., Arizmendi, L., Del-Angel, M., Romero-Garcia, J. (2007). pH- and thermosen-sitive polyaniline colloidal particles prepared by enzymatic polymerization. Langmuir, 23 (1), 8–12.

Das, S.K., Bhowal, J., Das, A.R., Guha, A.K. (2006). Adsorption behavior of rhodamine B on Rhizopus oryzae biomass. Langmuir, 22 (17), 7265–7272.

Eastman, J. Colloid stability. In: Cosgrove, T. (ed) Colloid Science: Principles, Methods and Applications, Blackwell, Ames, IA, 2005, pp. 36–49.

Eastoe, J. Surfactant aggregation and adsorption at interfaces. In: Cosgrove, T. (ed) Colloid Science: Principles, Methods and Applications, Blackwell, Ames, IA, 2005, pp. 50–76.

Ferreira, M., Caetano, W., Iltri, R., Tabak, M., Oliveira Junior, O.N. (2005). Técnicas de caracterização para investigar interações no nível molecular em filmes de Langmuir e Langmuir-Blodgett (LB). Química Nova, 28, 502–510.

Ghoush, M.A., Samhouri, M., Al-Holy, M., Herald, T. (2008). Formulation and fuzzy model-ing of emulsion stability and viscosity of a gum–protein emulsifier in a model mayon-naise system. Journal of Food Engineering, 84 (2), 348–357.

Holmberg, K., Jönsson, B., Kronberg, B., Lindman, B. Surfactants and Polymers in Aqueous Solution, John Wiley and Sons, Chichester, 2002, 545p.

Jang, W., Nikolov, A., Wasan, D.T., Chen, K., Campbell, B. (2005). Effect of protein on the texture of food emulsions under steady flow. Industrial and Engineering Chemistry Research, 44 (14), 4855–4862.

Karadag, D., Turan, M., Akgul, E., Tok, S., Faki, A. (2007). Adsorption equilibrium and kinetics of Reactive Black 5 and Reactive Red 239 in aqueous solution onto surfactant-modified zeolite. Journal of Chemical and Engineering Data, 52 (5), 1615–1620.

24 Engineering Aspects of Milk and Dairy Products

LaRue, I., Adam, M., Zhulina, E.B., Rubinstein, M., Pitsikalis, M., Hadjichristidis, N., Ivanov, D.A., Gearba, R.I., Anokhin, D.V., Sheiko, S.S. (2008). Effect of the soluble block size on spherical diblock copolymer micelles. Macromolecules, 41 (17), 6555–6563.

Liu, J., Liu, D., Yokoyama, Y., Yusa, S., Nakashima, K. (2009). Physicochemical properties of micelles of poly(styrene-b-[3-(methacryloylamino)propyl]trimethylammonium chlo-ride-b-ethylene oxide) in aqueous solutions. Langmuir, 25 (2), 739–743.

López-León, T., Santander-Ortega, M.J., Ortega-Vinuesa, J.L., Bastos-González, D. (2008).

Hofmeister effects in colloidal systems: influence of the surface nature. Journal of Physical Chemistry C, 112 (41), 16060–16069.

Meyer, M., Le Ru, E.C., Etchegoin, P.G. (2006). Self-limiting aggregation leads to long-lived metastable clusters in colloidal solutions. Journal of Physical Chemistry B, 110 (12), 6040–6047.

Mirhosseini, H., Tan, C.P., Aghlara, A., Hamid, N.S.A., Yusof, S., Chern, B.H. (2008a).

Influence of pectin and CMC on physical stability, turbidity loss rate, cloudiness and flavor release of orange beverage emulsion during storage. Carbohydrate Polymers, 73 (1), 83–91.

Mirhosseini, H., Tan, C.P., Hamid, N.S.A., Yusof, S. (2008b). Effect of Arabic gum, xanthan gum and orange oil contents on x-potential, conductivity, stability, size index and pH of orange beverage emulsion. Colloids and Surface A: Physicochemical and Engineering Aspects, 315 (1–3), 47–56.

Miyano, K., Maeda, T. (1986). Photoluminescence, absorption and Raman spectra of a poly-diacetylene monolayer. Physical Review B, 33 (6), 4386−4388.

Myers, D. Surfaces, Interfaces and Colloids: Principles and Applications, 2nd ed., John Wiley and Sons, Chichester, 1999, 519p.

Nikolov, V., Lin, J., Merzlyakov, M., Hristova, K., Searson, P.C. (2007). Electrical measure-ments of bilayer membranes formed by Langmuir−Blodgett deposition on single-crystal silicon. Langmuir, 23 (26), 13040–13045.

Norde, W. Colloids and Interfaces in Life Sciences. Marcel Dekker, New York, 2003, 430p.

Phan The, D., Debeaufort, F., Voilley, A., Luu, D. (2009) Influence of hydrocolloid nature on the structure and functional properties of emulsified edible films. Food Hydrocolloids, 23 (3), 691–699.

Prpich, A.M., Biswas, M.E., Chen, P. (2008). Adsorption kinetics of aqueous n-alcohols: a new kinetic equation for surfactant transfer. Journal of Physical Chemistry C, 112 (7), 2522–2528.

Riley, J. Charge in colloidal systems. In: Cosgrove, T. (ed) Colloid Science: Principles, Methods and Applications, Blackwell, Ames, IA, 2005, pp. 14–49.

Semenova, M.G., Belyakova, L.E., Polikarpov, Y.N., Antipova, A.S., Dickinson, E. (2009).

Light scattering study of sodium caseinate þ dextran sulfate in aqueous solution: rela-tionship to emulsion stability. Food Hydrocolloids, 23 (3), 629–639.

Seto, K., Hosoi, Y., Furukawa, Y. (2007). Raman spectra of Langmuir–Blodgett and Langmuir–

Schaefer films of polydiacetylene prepared from 10,12-pentacosadiynoic acid. Chemical Physics Letters, 444 (4-6), 328–332.

Shah, D.O., Moudgil, B.M. Highlights of research on molecular interactions at interfaces from the University of Florida. In: Mittal, K.L., Shah, D.O. Adsorption and Aggregation of Surfactants in Solution. Marcel Dekker, New York, 2002, pp. 1–48.

Shaker, R.R., Jumah, R.Y., Abu-Jdayil, B. (2000). Rheological properties of plain yogurt dur-ing coagulation process: impact of fat content and preheat treatment of milk. Journal of Food Engineering, 44 (3), 175–180.

Sherman, P. (2007). Colloidal stability of ice cream mix. Journal of Texture Studies, 1 (1), 43–51.

Physical Chemistry of Colloidal Systems Applied to Food Engineering 25

Somasundaran, P., Markovic, B., Yu, X., Krishnakumar, S. Colloid systems and interfaces—

stability of dispersions through polymer and surfactant adsorption. In: Birdi, K.S. (ed) Handbook of Surface and Colloid Chemistry, 2nd ed., CRC Press, Boca Raton, FL, 2003, pp. 393–439.

Vicent, B. Introduction to colloidal dispersions. In: Cosgrove, T. (ed) Colloid Science:

Principles, Methods and Applications, Blackwell, Ames, IA, 2005, pp. 1–13.

Voets, I.K., Moll, P.M., Agil, A., Jérôme, C., Detrembleur, C., Waard, P., Keizer, A., Stuart, M.A.C. (2008). Temperature responsive complex coacervate core micelles with a PEO and PNIPAAm corona. Journal of Physical Chemical B, 112 (35), 10833–10840.

Yam, Q., Gao, L., Sharma, V., Chiang, Y.M., Wong, C.C. (2008). Particle and substrate charge effects on colloidal self-assembly in a sessile drop. Langmuir, 24 (20), 11518–11522.

Zhang, H., Liu, Y., Zhang, J., Wang, C., Li, M., Yang, B. (2008). Influence of interparticle electrostatic repulsion in the initial stage of aqueous semiconductor nanocrystal growth.

Journal of Physical Chemical C, 112 (6), 1885–1889.

27