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is the net output d.c voltage after application of

the in phase signals (V. ) from the p DSodo for t v/ith the

X U S G C

time constant T = RC calculated in ohms x farads, The time

constant thus determines the net gain of the filter» The signal

bandwidth of the operational amplifier with an RC filter in

the feedback loop is the same as the simple R.C. low pass filter

( F ig c 2o3b) i.e. where f = '1 (equation 16 ) 0 This upper 2tcRC

15 2

value is a result of defining the bandwidth, Af, as equal to

that sinusoidal frequency at which the circuits response is

1/ / 2 of its maximum value (A f and f are therefore the same upper

value)o However consider a white noise source generating a

noise voltage per unit bandwidth which gives an rms voltage at

the output of the filter and refer to equation 6,

It can be seen that to find the noise output of the RC filter,

the square of the noise voltage must be integrated over the 152.

range of frequencies of interest. The result is an equivalent

noise bandwidth o f :

f = 1 (2 2)

upper ^

This is significantly different from the signal bandwidth 1 .

2tcRC

appears in the equations for shot and Johnson noise- This

argument is true for v/hite noisee I? the noise is not white,

the relation between noise and bandwidth is different but in

general reducing A f reduces the noise at the output-

Not only is the bandwidth of the system determined by

the time constant but also the response time is affected- The

response time is defined as the time it takes for the output

signal to reach 99% of its final value- It maybe shown that

Tr = 4-6RC (23)

Combining equations (22 and (23):

I, = 1o15 A/ 1 (24-)

£ 7 “ ^ £ f

If the electrical bandwidth is reduced in an attempt to reduce

random noise the response time increases (equation 2h)0

Unfortunately not only does this extra time required cause

difficulties but also the trade of time for noise is not linear-

X

The noise only decreases as the (time) 2 a consequence of equivalent

noise bandwidth- (i-e- equations (3) to (3) where the

magnitude of the various noise sources are proportional to the

square root of the bandwidth)- To illustrate this point consider

that going from a time constant of 1 second to one of 10 0 seconds

narrows A f by a factor of 10 0, but this only decreases the noise

X

by (100) 2 i-e- 10- Thus it is necessary to wait 100 times

larger to improve this signal-to-noise ratio by a factor of 10-

Moreover the increase in response time will introduce errors

and inconveniences which effectively limit the extent by which

A f may be profitably reduced- These difficulties are outlined

below:

(1) Analysis time - the extra time necessary for the amplifier

to give a readout becomes inconvenient when carrying out multiple

readings such as statistical checks on a large number of samples

and standardso

(2) Sample consumption - A longer analysis time will mean

more sample solution consumed which may be a disadvantage for

some applicationso

(3) Drift Errors - Instrumental drifts resulting from source

spectral radiance drift, amplifier drift etc« have a greater

effect on analytical accuracy the longer it takes to complete

a measuremento

(A) Spectrum-scanning - For recording line spectra, the mono-

-1

7

chromator scan speed r(non sec ) should be approximately :

where S is the spectral bandpass of the monochromator0 In the

was used routinely i^hereas the optimum should have been C& o008 nm

accuracy is required..

The ideal lock-in amplifier is inherently linear, the

main result of this being that unwanted signals are a.c, and

consequently give random fluctuations about the d«,c„ level given

by the wanted signalo By contrast the noise passed by a tuned

amplifier into a conventional polarity sensitive rectifier gives

an aoCo output superimposed on a d«Co offset„ This d0c„ output

is an error which depends in magnitude upon the mean value of

the noise and is subject to changes which do not depend on the

signal level..

D Building of the lock-in amplifier

The basic principles of the lock-in amplifier circuit

‘have already been outlined in section 2o3°'\°Co The circuit

(23)

present work S was 0„25 nm and in fact a scan speed of 0„03 nm sec

— 1 A —1

sec (&if = 0*032 sec )„ However the Jarrell-Ash monochromator

- 1

3 3

was taken from the design by Caplan and Stern * This design

was specifically titled 'An Inexpensive Lock-In Amplifier' and

so it has proved to be* All the components were inexpensive

although it was necessary to build a tv/in power supply (£17)

to power the amplifier„ The total cost of the electronics

(including the preamplifier) was less than £10 0* The design

for the power supply was taken from the R.S* Components Ltd*

catalogue and R*S, voltage regulatorswere usedo

Two relatively minor modifications were made to the

lock-in amplifier circuitry., Firstly a modification to the input

amplifier. This amplifier as designed had too low an input

impedance to be compatible id.th the photomultiplier tube or the

preamplifier which was subsequently built <> Secondly a new output

amplifier (differential low-pass filter) was.built to be used as

supplementary to the design output amplifier* This new differential

low-pass filter was temperature stabilised to give minimum

drift with ambient temperature, thus permitting longer time

constants to be’ used at the output*

The main problem encountered during the building of the

lock-in amplifier was with high frequency oscillation caused by

instability of the integrated circuit operational amplifiers*

(This is a common problem with such amplifiers and there are

standard remedies based usually on trial and error with different

values of circuit components )* In this section the circuitry

in its final form is reproduced in sections as the description

of its features continues* Any differences between the Caplan

and Stern design and this circuitry are pointed out where

necessary* The preamplifier, described below, was not part of

the original design but was necessary to match the lock-in

amplifier to the photomultiplier tube*

*

The relevant part of the catalogue is given in appendix 3

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