5. CONCLUSION AND RECOMMENDATIONS
5.2 RECOMMENDATIONS
Further studies into the energy storage requirements as well as compositions required to successfully and economically use scrubbed biogas as an alternative to compressed natural gas (CNG), would expand on a biogas upgrading plants product line but lower capital costs, as the products produced from raw biogas can be increased. In South Africa, a large percentage of the population still rely on CNG and this is a market worth tapping into.
It is recommended that further studies into lowering the production cost by increasing capacities of the plant (and reroute this product gas to be utilised as a source of power in the
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plant) which can lower the energy requirements. Furthermore, preliminary results from the plant highlight that an excess of 400 MJ would lower the running costs substantially as the energy produced can be used to power the plant. This leaves it up to interpretation that the use of more energy-efficient equipment or eliminating the need of flash drums by utilising a multi- component distillation column with the above design, should be seen if it can be more feasible on a larger scale. In conclusion and for comparison, natural gas contains roughly 90% methane, has a calorific value of 39.50 MJ/m3 and biomethane with a methane content of more than 98%, has a calorific value of 36.00 MJ/m3, while the product gas produced by this process has a value of 36.42 MJ/m3. In order to achieve these higher calorific values, a study on utilising propane enrichment must be considered.
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REFERENCES
[1] CityPower, Tariffs & Charges 2014/2015, (2014).
http://www.eskom.co.za/CustomerCare/TariffsAndCharges/Documents/Tariff Book 2018-2018.pdf (accessed August 15, 2018).
[2] D. Balussou, A. Kleyböcker, R. McKenna, D. Möst, W. Fichtner, parte de_An
Economic Analysis of three operational co-digestion biogas plants in Germany, Waste and Biomass Valorization. 3 (2012) 23–41.
[3] Sasol, Supply Chain policy Sasol, 1 (2015) 2015. http://www.sasol.com (accessed November 6, 2017).
[4] Economic Development Department, The new growth path: Framework, (2011) 1–42. https://www.google.co.za/webhp?sourceid=chrome-instant&ion=1&espv=2&ie=UTF- 8# (accessed September 10, 2016).
[5] ATCO Gas, Material Safety Data Sheet - Natural Gas, (2014) 1–6. http://www.atcogas.com/Safety/Safety-Education-and-
Resources/Documents/Safety_Resources_MaterialSafetyDataSheet.pdf (accessed April 12, 2016).
[6] R. Goosen, Biogas and Green Transport Driving Economic Growth, (2013) 16. http://www.biogasassociation.co.za/downloads/NBC2013/NBC2013-3.pdf (accessed April 10, 2016).
[7] F. Bauer, T. Persson, C. Hulteberg, D. Tamm, Biogas upgrading–technology overview, comparison and perspectives for the future, Biofuels, Bioprod. Biorefining. 7 (2013) 499–511.
[8] J.D. Murphy, N.M. Power, An argument for using biomethane generated from grass as a biofuel in Ireland, Biomass and Bioenergy. 33 (2009) 504–512.
[9] D. Goulding, N. Power, Which is the preferable biogas utilisation technology for anaerobic digestion of agricultural crops in Ireland: Biogas to CHP or biomethane as a transport fuel?, Renew. Energy. 53 (2013) 121–131.
63
support, Energy Policy. 38 (2010) 4945–4954.
[11] H. Winkler, Renewable energy policy in South Africa: Policy options for renewable electricity, Energy Policy. 33 (2005) 27–38.
[12] L.E. Lottering, B. Mohammed, A.N. Matheri, E. Muzenda, Biogas to Biomethane Upgrade by a High-Temperature and Low-Pressure CO2 Removal Technique, in: 2nd Int. Conf. Energy, Environ. Clim. Chang. (ICEECC 2017), Mauritius, 2017: pp. 152– 160.
[13] L.E. Lottering, B. Mohammed, A.N. Matheri, E. Muzenda, Study on the Biomethane Potential (BMP) of Different Substrates, Johannesburg, South Africa, 2017.
[14] S. Strauch, J. Krassowski, A. Singhal, Biomethane Guide for Decision Makers: Policy guide on biogas injection into the natural gas grid, Green Gas Grids. (2013) 1–38. [15] W. Gis, I. Samson-bręk, Review of technology for cleaning biogas to natural gas
quality, Automot. Ind. Inst. PIMOT. (2012) 33–39.
[16] J. Hao, P.A. Rice, S.A. Stern, Upgrading low-quality natural gas with H2S- and CO2- selective polymer membranes. Part II. Process design, economics, and sensitivity study of membrane stages with recycle streams, J. Memb. Sci. 320 (2008) 108–122.
[17] C. Gallagher, J.D. Murphy, Is it better to produce biomethane via thermochemical or biological routes? An energy balance perspective, Biofuels, Bioprod. Biorefining. 7 (2013) 273–281.
[18] I. Angelidaki, M.M. Alves, D. Bolzonella, L. Borzacconi, J.L. Campos, A.J. Guwy, S. Kalyuzhnyi, P. Jenicek, J.B. Van Lier, Defining the biomethane potential (BMP) of solid organic wastes and energy crops: a proposed protocol for batch assays, (2009). [19] M. Mel, M.A.H. Sharuzaman, R.H. Setyobudi, Removal of CO2 from biogas plant
using chemical absorption column, AIP Conf. Proc. 1755 (2016).
[20] Q. Sun, H. Li, J. Yan, L. Liu, Z. Yu, X. Yu, Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation, Renew. Sustain. Energy Rev. 51 (2015) 521–532.
64
Energy. 31 (2015) 571–582.
[22] R. Spalding-Fecher, D.K. Matibe, Electricity and externalities in South Africa, Energy Policy. 31 (2003) 721–734.
[23] K. Menyah, Y. Wolde-Rufael, Energy consumption, pollutant emissions and economic growth in South Africa, Energy Econ. 32 (2010) 1374–1382.
[24] E. Vine, An international survey of the energy service company ESCO industry, 2005. [25] X. Ou, X. Yan, X. Zhang, Using coal for transportation in China: Life cycle GHG of
coal-based fuel and electric vehicle, and policy implications, Int. J. Greenh. Gas Control. 4 (2010) 878–887.
[26] Greater London Authority, 50 years on: The struggle for air quality in London since the great smog of December 1952, Greater London Authority, 2002.
[27] O. Crankshaw, A. Gilbert, A. Morris, Backyard Soweto, Int. J. Urban Reg. Res. 24 (2000) 841–857.
[28] T. Wang, J. Chang, P. Lv, Synthesis gas production via biomass catalytic gasification with addition of biogas, Energy and Fuels. 19 (2005) 637–644.
[29] G. Esposito, L. Frunzo, A. Panico, F. Pirozzi, Enhanced bio-methane production from co-digestion of different organic wastes, Environ. Technol. (United Kingdom). 33 (2012) 2733–2740.
[30] M. Scholz, T. Melin, M. Wessling, Transforming biogas into biomethane using membrane technology, Renew. Sustain. Energy Rev. 17 (2013) 199–212.
[31] M.A. Dareioti, S.N. Dokianakis, K. Stamatelatou, C. Zafiri, M. Kornaros, Biogas production from anaerobic co-digestion of agroindustrial wastewaters under mesophilic conditions in a two-stage process, Desalination. 248 (2009) 891–906. [32] K. Hagos, J. Zong, D. Li, C. Liu, X. Lu, Anaerobic co-digestion process for biogas
production: Progress, challenges and perspectives, Renew. Sustain. Energy Rev. 76 (2017) 1485–1496.
[33] K. Chłopek, C. Frommen, A. Léon, O. Zabara, M. Fichtner, Synthesis and properties of magnesium tetrahydroborate, Mg(BH4)2, J. Mater. Chem. 17 (2007) 3496.
65
[34] C. Yangin Gomec, M.E. Ersahin, R.K. Dereli, O. Arikan, I. Ozturk, Biomethane production as an alternative bioenergy source from codigesters treating municipal sludge and organic fraction of municipal solid wastes, J. Biomed. Biotechnol. (2011) 953065.
[35] M. Åhman, Biomethane in the transport sector-An appraisal of the forgotten option, Energy Policy. 38 (2010) 208–217.
[36] M. Frondel, N. Ritter, C.. C.M. Schmidt, C. Vance, Economic impacts from the promotion of renewable energy technologies: The German experience, Energy Policy. 38 (2010) 4048–4056.
[37] M. Poeschl, S. Ward, P. Owende, Environmental impacts of biogas deployment - Part I: Life Cycle Inventory for evaluation of production process emissions to air, J. Clean. Prod. 24 (2012) 168–183.
[38] M. Harasimowicz, P. Orluk, G. Zakrzewska-Trznadel, A.G. Chmielewski, Application of polyimide membranes for biogas purification and enrichment, J. Hazard. Mater. 144 (2007) 698–702.
[39] S. Rasi, Biogas Composition and Upgrading to Biomethane Saija Rasi Biogas Composition and Upgrading to Biomethane, University of Jyväskylä, 2009.
[40] H.S. Salave, Design, Development and Experimental Investigation on Various Biogas Upgrading Techniques, IOSR J. Mech. Civ. Eng. 17 (2017) 55–60.
[41] Eze, Agbo, Maximizing the potentials of biogas through upgrading, Am. J. Sci. Ind. Res. 1 (2010) 604–609.
[42] S. Rasi, A. Veijanen, J. Rintala, Trace compounds of biogas from different biogas production plants, Energy. 32 (2007) 1375–1380.
[43] M. Marsh, C.E. Officer, K. Krich, D. Augenstein, J. Benemann, B. Rutledge, D. Salour, Biomethane from Dairy Waste A Sourcebook for the Production and Use of Renewable Natural Gas in California, 2005.
[44] S.S. Kapdi, V.K. Vijay, S.K. Rajesh, R. Prasad, Biogas scrubbing, compression and storage: Perspective and prospectus in Indian context, Renew. Energy. 30 (2005) 1195–1202.
66
[45] W.M. Budzianowski, Sustainable biogas energy in Poland: Prospects and challenges, Renew. Sustain. Energy Rev. 16 (2012) 342–349.
[46] F. Osorio, J.C. Torres, Biogas purification from anaerobic digestion in a wastewater treatment plant for biofuel production, Renew. Energy. 34 (2009) 2164–2171. [47] W.M. Budzianowski, Benefits of biogas upgrading to biomethane by high‐pressure
reactive solvent scrubbing, Biofuels, Bioprod. Biorefining. 6 (2012) 12–20.
[48] M. Persson, O. Jonsson, A. Wellinger, Biogas Upgrading To Vehicle Fuel Standards and Grid, IEA Bioenergy. (2007) 1–32.
[49] Z. ul Z. Asam, T.G. Poulsen, A.S. Nizami, R. Rafique, G. Kiely, J.D. Murphy, How can we improve biomethane production per unit of feedstock in biogas plants?, Appl. Energy. 88 (2011) 2013–2018.
[50] F. Sealing, C. Production, A. Separation, I.S. Data, C.S. Preview, Improving Bulk Solids Handling The Smart Way to, (2017) 8–10.
[51] J.D. Browne, E. Allen, J.D. Murphy, Evaluation of the biomethane potential from multiple waste streams for a proposed community scale anaerobic digester, Environ. Technol. 34 (2013) 2027–2038.
[52] M. Ravina, G. Genon, Global and local emissions of a biogas plant considering the production of biomethane as an alternative end-use solution, J. Clean. Prod. 102 (2015) 115–126.
[53] C. Herbes, L. Braun, D. Rube, Pricing of biomethane products targeted at private households in Germany-product attributes and providers’ pricing strategies, Energies. 9 (2016).
[54] E. Allen, J.D. Browne, J.D. Murphy, Evaluation of the biomethane yield from anaerobic co-digestion of nitrogenous substrates, Environ. Technol. (United Kingdom). 34 (2013) 2059–2068.
[55] E. Ryckebosch, M. Drouillon, H. Vervaeren, Techniques for transformation of biogas to biomethane, Biomass and Bioenergy. 35 (2011) 1633–1645.
67
Perspective: Jatropha cultivation in southern India: Assessing farmers’ experiences, Biofuels, Bioprod. Biorefining. 6 (2012) 246–256.
[57] S. Pokharel, Promotional issues on alternative energy technologies in Nepal.energy Policy 31:307-318, Energy Policy. 31 (2003) 307–318.
[58] R.P.J.M. Raven, K.H. Gregersen, Biogas plants in Denmark: successes and setbacks, Renew. Sustain. Energy Rev. 11 (2007) 116–132.
[59] S. Rasi, J. Läntelä, J. Rintala, Trace compounds affecting biogas energy utilisation - A review, Energy Convers. Manag. 52 (2011) 3369–3375.
[60] M.T. Varnero, K. Galleguillos, D. Guerrero, J. Suárez, Producción de biogás y enmiendas orgánicas a partir del residuo olivícola (alperujo), Inf. Tecnol. 25 (2014) 73–78.
[61] H.M. Lapp, D.D. Schulte, A.B. Sparling, L.C. Buchanan, Methane production from animal wastes. I. Fundamental considerations, Can. Agric. Eng. 17 (1975) 97–102. [62] L. Deng, M.B.M. Hägg, Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane, Int. J. Greenh. Gas Control. 4(4) (2010) 638–646.
[63] A.M.I. Yousef, Y.A. Eldrainy, W.M. El-maghlany, A. Attia, Upgrading biogas by a low-temperature CO2 removal technique, Alexandria Eng. J. 55 (2016) 1143–1150. [64] A. Petersson, A. Wellinger, Biogas upgrading technologies–developments and
innovations, IEA Bioenergy. 20 (2009) 20.
[65] A. Makaruk, M. Miltner, M. Harasek, Membrane biogas upgrading processes for the production of natural gas substitute, Sep. Purif. Technol. 74 (2010) 83–92.
[66] G.D. Zupančič, M. Roš, Heat and energy requirements in thermophilic anaerobic sludge digestion, Renew. Energy. 28 (2003) 2255–2267.
[67] W.R. Peters, M., K. Timmerhaus, Plant Design and Economics for Chemical Engineers, McGraw-Hill New York, 2003.
[68] J.F. Coetzee, M.F. James, Anaesthetic gas analysers: Potential for confusion and errors if you live and work at moderate altitude, South. African J. Anaesth. Analg. 16 (2010)
68
6–8.
[69] A.S.M. America, Operation and Maintenance Manual, East. (2000) 1–41.
[70] F. Cucchiella, I. D’Adamo, Technical and economic analysis of biomethane: A focus on the role of subsidies, Energy Convers. Manag. 119 (2016) 338–351.
[71] K.K. S, M.H. Ibrahim, S. Quaik, S.A. Ismail, Composting: A Traditional Practice of Waste Treatment, Prospect. Org. Waste Manag. Significance Earthworms. 23 (2016) 45–68.
[72] R.K. Sinnott, G. Towler, Chemical engineering design., Butterworth-Heinemamn, 2009.
[73] P.R.H. and G. Don, W, Chemical Engineering Handbook, McGraw-Hill, 1999.
[74] J. Warnatz, U. Maas, R.W. Dibble, Combustion: Physical and Chemical Fundamentals, Modeling and Simulation, Experiments, Pollutant formation, Springer, 1996.
[75] J. Ariunbaatar, A. Panico, G. Esposito, F. Pirozzi, P.N.L. Lens, Pretreatment methods to enhance anaerobic digestion of organic solid waste, Appl. Energy. 123 (2014) 143– 156.
[76] X. Chen, W. Yan, K. Sheng, M. Sanati, Comparison of high-solids to liquid anaerobic co-digestion of food waste and green waste, Bioresour. Technol. 154 (2014) 215–221. [77] S. Xie, Evaluation of Biogas Production From Anaerobic Digestion of Pig Manure and
Grass Silage, (2012).
[78] H.M. El-Mashad, R. Zhang, Biogas production from co-digestion of dairy manure and food waste, Bioresour. Technol. 101 (2010) 4021–4028.
[79] F. Fantozzi, C. Buratti, Bioresource Technology Biogas production from different substrates in an experimental Continuously Stirred Tank Reactor anaerobic digester, Bioresour. Technol. 100 (2009) 5783–5789.
[80] V. Vijay, A case for biogas energy application for rural industries in India, Renew. Energy. 9 (1996) 993–996.
69
into scalability of biosurfactant combined microwave disintegration of sludge at alkali pH for achieving profitable bioenergy recovery and net profit, Bioresour. Technol. 267 (2018) 281–290.
[82] K. Dhamodharan, V. Kumar, A.S. Kalamdhad, Effect of different livestock dungs as inoculum on food waste anaerobic digestion and its kinetics, Bioresour. Technol. 180 (2015) 237–241.
[83] T. Conant, A. Karim, A. Datye, Coating of steam reforming catalysts in non-porous multi-channeled microreactors, Bioresour. Technol. 99 (2008) 882–888.
[84] G.S. Kangle, K. M.; Kore, S. V.; Kore, V. S.; Kulkarni, Recent Trends in Anaerobic Codigestion : A Review, Univers. J. Environ. Res. Technol. 2 (2012) 210–219. [85] Bioprocess Control, Ampts II. Operation and Maintenance Manual, Network. (2014).
www.bioprocesscontrol.com (accessed April 10, 2016).
[86] J. Zhu, C. Wan, Y. Li, Enhanced solid-state anaerobic digestion of corn stover by alkaline pretreatment, Bioresour. Technol. 101 (2010) 7523–7528.
[87] I. Kelly, Equipment Design and Cost Estimation for Small Modular Biomass Systems , Synthesis Gas Cleanup , and Oxygen Separation Equipment Task 2 : Gas Cleanup Design and Cost Equipment Design and Cost Estimation for Small Modular Biomass Systems , Synthesis Gas Cl, (2006) 50. https://www.nrel.gov/docs/fy06osti/39944.pdf (accessed April 10, 2017).
[88] P. Kasikamphaiboon, J. Chungsiriporn, C. Bunyakan, W. Wiyaratn, Simultaneous removal of CO2 and H2S using MEA solution in a packed column absorber for biogas upgrading, Songklanakarin J. Sci. Technol. 35 (2013) 683–691.
[89] F.Y. Jou, F.D. Otto, A.E. Mather, Solubility of mixtures of hydrogen sulfide and carbon dioxide in aqueous solutions of triethanolamine, J. Chem. Eng. Data. 41 (1996) 1181–1183.
[90] D. Weisser, On the economics of electricity consumption in small island developing states: A role for renewable energy technologies?, Energy Policy. 32 (2004) 127–140. [91] AGAMA BIOGAS, AGAMA Prefab Digester – Basic Information Brochure – June
70
http://www.greenconnexion.co.za/Agama_Biogas_Digester.pdf (accessed November 6, 2017).
[92] R. Baxter, N. Hastings, A. Law, E.J.. Glass, Puxin Biogas Plant, Anim. Genet. 39 (2008) 561–563.
[93] T. Wallace, A. Bradshaw, Technologies and strategies for people with communication problems following brain injury or stroke, Taylor & Francis, 2011.
[94] C.-Z. Li, Fundamentals of Renewable Energy Processes, Process Saf. Environ. Prot. 84 (2006) 476.
[95] M. Poschl, S. Ward, P. Owende, M. Pöschl, S. Ward, P. Owende, M. Poschl, S. Ward, P. Owende, Evaluation of energy efficiency of various biogas production and
utilization pathways, Appl. Energy. 87 (2010) 3305–3321.
[96] A. Evans, V. Strezov, T.J. Evans, Assessment of sustainability indicators for
71