Distance from center: rPolymer volume fractionr
22. Say N to new fit to do a grid search
6.5. Sample and Lab Book Codes
Table 11: Lab book codes of the samples
Chapter Thesis code Lab book code
1. General Introduction Microgel JD-51 4.1. Reduced UV Light Scattering in
PDMS Microfluidic devices Silica NP JD-42 4.2. How hollow are
thermoresponsive, hollow nanogels?
CS-1/PP-1 CS-2/PP-2 CS-3/PP-3
JD-MKBT063 JD-MKBT064 JD-MKBT040 4.3. Core-shell-shell and hollow
double-shell microgels with
advanced temperature responsive-ness
CS CSS
JD-MKBT037CS JD-MKBT037CS-KN02 4.4. Polystyrene/PNIPAM Core-Shell
Particles and the Influence of the Core Dissolution on the Particle Structure
D-CS/D-HS H-CS/H-HS H-CS2/H-HS2
JD-103 JD-CvE-4 JD-50 4.5. Development of a Model System
for the Investigation of Hetero-geneous Crystallization of Soft Particles Near Flat and curved Walls
MG-1 MG-2 MG-3
JD-45 JD-70 JD-63
References
[1] R. Pelton: Temperature-sensitive aqueous microgels, Advances in colloid and interface science 2000, 85, 1-33.
[2] J. Thorne, G. Vine, M. Snowden: Microgel applications and commercial considerations, Colloid and Polymer Science 2011, 289, 625-646.
[3] M. Das, H. Das, E. Zhang, Kumacheva: MICROGELS: Old Materials with New Applications, Annual review of materials research 2006, 36, 117-142.
[4] S. Seiffert: Klein aber fein: sensitive Mikrogelkapseln, Angewandte Chemie 2013, 125, 11674-11680.
[5] V. C. Lopez, J. Lopez, M. J. Hadgraft, Snowden: The use of colloidal microgels as a (trans)dermal drug delivery system, International journal of pharmaceutics 2005, 292, 137-147.
[6] S. Nayak, H. Lee, J. Chmielewski, L. A. Lyon: Folate-Mediated Cell Targeting and Cytotoxicity Using Thermoresponsive Microgels, Journal of the American Chemical Society 2004, 126, 10258-10259.
[7] C. M. Nolan, C. D. Reyes, J. D. Debord, A. J. García, L. A. Lyon: Phase Transition Behavior, Protein Adsorption, and Cell Adhesion Resistance of Poly(ethylene glycol) Cross-Linked Microgel Particles, Biomacromolecules 2005, 6, 2032-2039.
[8] A. S. Hoffman: Hydrogels for biomedical applications, Advanced Drug Delivery Reviews 2012, 64, Supplement, 18-23.
[9] Y. Guan, Y. Zhang: PNIPAM microgels for biomedical applications: from dispersed particles to 3D assemblies, Soft Matter 2011, 7, 6375-6384.
[10] H. Kawaguchi, K. Fujimoto: Smart latexes for bioseparation, Bioseparation 1998, 7, 253-258.
[11] K. Molawi, A. Studer: Reversible switching of substrate activity of poly-N-isopropylacrylamide peptide conjugates, Chemical Communications 2007, 5173-5175.
[12] G. E. Morris, B. Vincent, M. J. Snowden, in Trends in Colloid and Interface Science XI, Vol. 105 (Eds.: J. B. Rosenholm, B. Lindman, P. Stenius), Steinkopff, 1997, pp. 16-22.
[13] M. Stieger, J. S. Pedersen, P. Lindner, W. Richtering: Are Thermoresponsive Microgels Model Systems for Concentrated Colloidal Suspensions? A Rheology and Small-Angle Neutron Scattering Study, Langmuir 2004, 20, 7283-7292.
[14] S. Nayak, L. A. Nayak, Lyon: Soft Nanotechnology with Soft Nanoparticles, Angewandte Chemie (International ed.) 2005, 44, 7686-7708.
[15] C. Wu, S. Zhou, S. C. F. Au-yeung, S. Jiang: Volume phase transition of spherical microgel particles, Die Angewandte Makromolekulare Chemie 1996, 240, 123-136.
[16] C. Erbil, A. Sezai Saraç: Description of the turbidity measurements near the phase transition temperature of poly(N-isopropyl acrylamide) copolymers: the effect of pH, concentration, hydrophilic and hydrophobic content on the turbidity, European Polymer Journal 2002, 38, 1305-1310.
[17] A. Guillermo, J. P. Cohen Addad, J. P. Bazile, D. Duracher, A. Elaissari, C. Pichot: NMR investigations into heterogeneous structures of thermosensitive microgel particles, Journal of Polymer Science Part B: Polymer Physics 2000, 38, 889-898.
References [18] B. Sierra-Martín, M. S. Romero-Cano, T. Cosgrove, B. Vincent, A. Fernández-Barbero: Solvent relaxation of swelling PNIPAM microgels by NMR, Colloids and Surfaces A: Physicochemical and Engineering Aspects 2005, 270–271, 296-300.
[19] S.-Y. Lin, K.-S. Chen, R.-C. Liang: Thermal micro ATR/FT-IR spectroscopic system for quantitative study of the molecular structure of poly(N-isopropylacrylamide) in water, Polymer 1999, 40, 2619-2624.
[20] R. H. Pelton, P. Chibante: Preparation of aqueous latices with N-isopropylacrylamide, Colloids and Surfaces 1986, 20, 247-256.
[21] O. S. Gerhard Lagaly, Ralf Zimehl in Dispersionen und Emulsionen, 1997.
[22] S. Abrol, D. H. Solomon: Studies on microgels: 4. The effect of solvent on the synthesis of t-butylstyrene-divinylbenzene microgels by anionic polymerization, Polymer 1999, 40, 6583-6589.
[23] M. Frank, W. Burchard: Microgels by intramolecular crosslinking of poly(allylamine) single chains, Die Makromolekulare Chemie, Rapid Communications 1991, 12, 645-652.
[24] D. Kuckling, C. D. Vo, H. J. P. Adler, A. Völkel, H. Cölfen: Preparation and Characterization of Photo-Cross-Linked Thermosensitive PNIPAAm Nanogels, Macromolecules 2006, 39, 1585-1591.
[25] S. Neyret, B. Vincent: The properties of polyampholyte microgel particles prepared by microemulsion polymerization, Polymer 1997, 38, 6129-6134.
[26] M. Andersson, S. L. Maunu: Structural studies of poly(N-isopropylacrylamide) microgels: Effect of SDS surfactant concentration in the microgel synthesis, Journal of Polymer Science Part B:
Polymer Physics 2006, 44, 3305-3314.
[27] X. Wu, R. H. Pelton, A. E. Hamielec, D. R. Woods, W. McPhee: The kinetics of poly(N-isopropylacrylamide) microgel latex formation, Colloid and Polymer Science 1994, 272, 467-477.
[28] M. Stieger, W. Richtering, J. S. Pedersen, P. Lindner: Small-angle neutron scattering study of structural changes in temperature sensitive microgel colloids, The Journal of Chemical Physics 2004, 120, 6197-6206.
[29] H. Macková, D. Macková, Horák: Effects of the reaction parameters on the properties of thermosensitive poly(N-isopropylacrylamide) microspheres prepared by precipitation and dispersion polymerization, Journal of polymer science. Part A, Polymer chemistry 2006, 44, 968-982.
[30] Z. Meng, M. Smith, L. A. Lyon: Temperature-programmed synthesis of micron-sized multi-responsive microgels, Colloid and Polymer Science 2009, 287, 277-285.
[31] S. Meyer, W. Richtering: Influence of Polymerization Conditions on the Structure of Temperature-Sensitive Poly(N-isopropylacrylamide) Microgels, Macromolecules 2005, 38, 1517-1519.
[32] Y. Hertle, T. Hellweg: Thermoresponsive copolymer microgels, Journal of Materials Chemistry B 2013, 1, 5874-5885.
[33] M. J. Snowden, B. Z. Chowdhry, B. Vincent, G. E. Morris: Colloidal copolymer microgels of N-isopropylacrylamide and acrylic acid: pH, ionic strength and temperature effects, Journal of the Chemical Society, Faraday Transactions 1996, 92, 5013-5016.
[34] J. Kleinen, W. Richtering: Defined Complexes of Negatively Charged Multisensitive Poly(N-isopropylacrylamide-co-methacrylic acid) Microgels and Poly(diallydimethylammonium chloride), Macromolecules 2008, 41, 1785-1790.
[35] B. Brugger, J. Vermant, W. Richtering: Interfacial layers of stimuli-responsive poly-(N-isopropylacrylamide-co-methacrylicacid) (PNIPAM-co-MAA) microgels characterized by interfacial rheology and compression isotherms, Physical Chemistry Chemical Physics 2010, 12, 14573-14578.
[36] S. Schmidt, T. Liu, S. Rütten, K.-H. Phan, M. Möller, W. Richtering: Influence of Microgel Architecture and Oil Polarity on Stabilization of Emulsions by Stimuli-Sensitive Core–Shell Poly(N-isopropylacrylamide-co-methacrylic acid) Microgels: Mickering versus Pickering Behavior?, Langmuir 2011, 27, 9801-9806.
[37] L. Zha, J. Hu, C. Wang, S. Fu, A. Elaissari, Y. Zhang: Preparation and characterization of poly (N-isopropylacrylamide-co-dimethylaminoethyl methacrylate) microgel latexes, Colloid and Polymer Science 2002, 280, 1-6.
[38] V. T. Pinkrah, M. J. Snowden, J. C. Mitchell, J. Seidel, B. Z. Chowdhry, G. R. Fern:
Physicochemical Properties of Poly(N-isopropylacrylamide-co-4-vinylpyridine) Cationic Polyelectrolyte Colloidal Microgels, Langmuir 2003, 19, 585-590.
[39] J. Xu, A. Barros Timmons, R. Pelton: N-Vinylformamide as a route to amine-containing latexes and microgels, Colloid and Polymer Science 2004, 282, 256-263.
[40] Q. Wang, Y. Zhao, H. Xu, X. Yang, Y. Yang: Thermosensitive phase transition kinetics of poly(N-isopropylacryl amide-co-acrylamide) microgel aqueous dispersions, Journal of Applied Polymer Science 2009, 113, 321-326.
[41] I. Berndt, W. Richtering: Doubly Temperature Sensitive Core−Shell Microgels, Macromolecules 2003, 36, 8780-8785.
[42] I. Berndt, J. S. Pedersen, W. Richtering: Temperature-Sensitive Core–Shell Microgel Particles with Dense Shell, Angewandte Chemie 2006, 118, 1769-1773.
[43] M. Bradley, B. Vincent, G. Burnett: Uptake and release of surfactants from polyampholyte microgel particles, Colloid and Polymer Science 2009, 287, 345-350.
[44] M. Keerl, J. S. Pedersen, W. Richtering: Temperature Sensitive Copolymer Microgels with Nanophase Separated Structure, Journal of the American Chemical Society 2009, 131, 3093-3097.
[45] T. Hellweg, C. D. Dewhurst, W. Eimer, K. Kratz: PNIPAM-co-polystyrene Core-Shell Microgels:
Structure, Swelling Behavior, and Crystallization, Langmuir 2004, 20, 4330-4335.
[46] R. Contreras-Cáceres, A. Sánchez-Iglesias, M. Karg, I. Pastoriza-Santos, J. Pérez-Juste, J.
Pacifico, T. Hellweg, A. Fernández-Barbero, L. M. Liz-Marzán: Encapsulation and Growth of Gold Nanoparticles in Thermoresponsive Microgels, Advanced Materials 2008, 20, 1666-1670.
[47] I. Gorelikov, L. M. Field, E. Kumacheva: Hybrid Microgels Photoresponsive in the Near-Infrared Spectral Range, Journal of the American Chemical Society 2004, 126, 15938-15939.
[48] M. Karg, I. Pastoriza-Santos, J. Pérez-Juste, T. Hellweg, L. M. Liz-Marzán: Nanorod-Coated PNIPAM Microgels: Thermoresponsive Optical Properties, Small 2007, 3, 1222-1229.
[49] J. Ge, T. Huynh, Y. Hu, Y. Yin: Hierarchical Magnetite/Silica Nanoassemblies as Magnetically Recoverable Catalyst–Supports, Nano Letters 2008, 8, 931-934.
References [50] J. E. Wong, A. Krishnakumar Gaharwar, D. Müller-Schulte, D. Bahadur, W. Richtering:
Layer-by-layer assembly of a magnetic nanoparticle shell on a thermoresponsive microgel core, Journal of Magnetism and Magnetic Materials 2007, 311, 219-223.
[51] Y. Mei, Y. Lu, F. Polzer, M. Ballauff, M. Drechsler: Catalytic Activity of Palladium Nanoparticles Encapsulated in Spherical Polyelectrolyte Brushes and Core−Shell Microgels, Chemistry of Materials 2007, 19, 1062-1069.
[52] M. Karg: New smart poly (NIPAM) microgels and nanoparticle microgel hybrids: Properties and advances in characterisation, Current opinion in colloid & interface science 2009, 14, 438.
[53] I. Berndt, J. S. Pedersen, W. Richtering: Structure of Multiresponsive “Intelligent” Core−Shell Microgels, Journal of the American Chemical Society 2005, 127, 9372-9373.
[54] K. P. Lok, C. K. Ober: Particle size control in dispersion polymerization of polystyrene, Canadian Journal of Chemistry 1985, 63, 209-216.
[55] W. Stöber, A. Fink, E. Bohn: Controlled growth of monodisperse silica spheres in the micron size range, Journal of Colloid and Interface Science 1968, 26, 62-69.
[56] M. Karg, I. Pastoriza-Santos, L. M. Liz-Marzán, T. Hellweg: A Versatile Approach for the Preparation of Thermosensitive PNIPAM Core-Shell Microgels with Nanoparticle Cores, ChemPhysChem 2006, 7, 2298-2301.
[57] I. Berndt, J. S. Pedersen, P. Lindner, W. Richtering: Influence of Shell Thickness and Cross-Link Density on the Structure of Temperature-Sensitive Isopropylacrylamid Poly-N-Isopropylmethacrylamide Core Shell Microgels Investigated by Small-Angle Neutron Scattering, Langmuir 2005, 22, 459-468.
[58] M. Karg, S. Wellert, S. Prevost, R. Schweins, C. Dewhurst, L. M. Liz-Marzán, T. Hellweg: Well defined hybrid PNIPAM core-shell microgels: size variation of the silica nanoparticle core, Colloid and Polymer Science 2010, 289, 699-709.
[59] L. S. Zha, Y. Zhang, W. L. Yang, S. K. Fu: Monodisperse temperature-sensitive microcontainers, Advanced Materials 2002, 14, 1090-1092.
[60] F. Zhang, C. Wang: Preparation of thermoresponsive core-shell polymeric microspheres and hollow PNIPAM microgels, Colloid and polymer science 2008, 286, 889-895.
[61] Z. H. Chen, C. Kim, X.-b. Zeng, S. H. Hwang, J. Jang, G. Ungar: Characterizing Size and Porosity of Hollow Nanoparticles: SAXS, SANS, TEM, DLS, and Adsorption Isotherms Compared, Langmuir 2012, 28, 15350-15361.
[62] C. J. McDonald, M. J. Devon: Hollow latex particles: synthesis and applications, Advances in Colloid and Interface Science 2002, 99, 181-213.
[63] H. Masoud, A. Alexeev: Controlled Release of Nanoparticles and Macromolecules from Responsive Microgel Capsules, ACS Nano 2011, 6, 212-219.
[64] Z. Xing, C. Wang, J. Yan, L. Zhang, L. Li, L. Zha: Dual stimuli responsive hollow nanogels with IPN structure for temperature controlling drug loading and pH triggering drug release, Soft Matter 2011, 7, 7992-7997.
[65] C. E. Mora-Huertas, H. Fessi, A. Elaissari: Polymer-based nanocapsules for drug delivery, International Journal of Pharmaceutics 2010, 385, 113-142.
[66] H. M. Chen, R.-S. Liu, M.-Y. Lo, S.-C. Chang, L.-D. Tsai, Y.-M. Peng, J.-F. Lee: Hollow Platinum Spheres with Nano-Channels: Synthesis and Enhanced Catalysis for Oxygen Reduction, The Journal of Physical Chemistry C 2008, 112, 7522-7526.
[67] C. H. Choi, J. H. Jung, D. W. Kim, Y. M. Chung, C. S. Lee: Novel one-pot route to monodisperse thermosensitive hollow microcapsules in a microfluidic system, Lab on a chip 2008, 8, 1544-1551.
[68] F. Caruso, R. A. Caruso, H. Möhwald: Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating, Science 1998, 282, 1111-1114.
[69] K. Glinel, G. B. Sukhorukov, H. Möhwald, V. Khrenov, K. Tauer: Thermosensitive Hollow Capsules Based on Thermoresponsive Polyelectrolytes, Macromolecular Chemistry and Physics 2003, 204, 1784-1790.
[70] K. Zhang, L. Zheng, X. Zhang, X. Chen, B. Yang: Silica-PMMA core-shell and hollow nanospheres, Colloids and Surfaces A: Physicochemical and Engineering Aspects 2006, 277, 145-150.
[71] X. Xu: Synthesis and utilization of monodisperse hollow polymeric particles in photonic crystals, Journal of the American Chemical Society 2004, 126, 7940.
[72] D. Zhu, F. Wang, C. Gao, Z. Xu: Construction of PS/PNIPAM core-shell particles and hollow spheres by using hydrophobic interaction and thermosensitive phase separation, Frontiers of Chemical Engineering in China 2008, 2, 253-256.
[73] E. Bourgeat-Lami: Encapsulation of inorganic particles by dispersion polymerization in polar media 1. Silica nanoparticles encapsulated by polystyrene, Journal of colloid and interface science 1998, 197, 293.
[74] F. Zhang, G. Hou, S. Dai, R. Lu, C. Wang: Preparation of thermosensitive PNIPAM microcontainers and a versatile method to fabricate PNIPAM shell on particles with silica surface, Colloid and Polymer Science 2012, 290, 1341-1346.
[75] R. Grunder, G. Urban, M. Ballauff: Small-angle x-ray analysis of latex particles with core-shell morphology, Colloid and Polymer Science 1993, 271, 563-572.
[76] J. Wald, S. Wiese, T. Eckert, W. Jahnen-Dechent, W. Richtering, A. Heiss: Formation and stability kinetics of calcium phosphate-fetuin-A colloidal particles probed by time-resolved dynamic light scattering, Soft Matter 2011, 7, 2869-2874.
[77] R. P. May, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter (Ed.: T. Z. P. Lindner), Elsevier Science B. V. , 2002, pp. 441-462.
[78] H. D. T. Mertens, D. I. Svergun: Structural characterization of proteins and complexes using small-angle X-ray solution scattering, Journal of Structural Biology 2010, 172, 128-141.
[79] P. N. Pusey, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter (Ed.: T. Z. P. Lindner), Elsevier Science B. V. , 2002, pp. 3-21.
[80] P. Schurtenberger, (Ed.: T. Z. P. Lindner), Elsevier Science B. V. , 2002, pp. 145-170.
[81] A. Einstein: Über die von der molekularkinetischen Theorie der Wärme geforderte Bewegung von in ruhenden Flüssigkeiten suspendierten Teilchen, Annalen der physik 1905, 322, 549-560.
[82] P. N. Pusey, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter (Ed.: T. Z. P. Lindner), Elsevier Science B. V. , 2002, pp. 203-220.
References [83] O. Glatter, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter
(Ed.: T. Z. P. Lindner), Elsevier Science B. V. , 2002, pp. 3-21.
[84] O. Spalla, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter, 2002, pp. 49-72.
[85] J. S. Pedersen, in Neutrons, X-rays and Light: Scattering Methods Applied to Soft Condensed Matter (Ed.: T. Z. P. Lindner), 2002, pp. 391-422.
[86] T. Nisisako, T. Torii, T. Takahashi, Y. Takizawa: Synthesis of Monodisperse Bicolored Janus Particles with Electrical Anisotropy Using a Microfluidic Co-Flow System, Advanced Materials 2006, 18, 1152-1156.
[87] R. F. Shepherd, J. C. Conrad, S. K. Rhodes, D. R. Link, M. Marquez, D. A. Weitz, J. A. Lewis:
Microfluidic Assembly of Homogeneous and Janus Colloid-Filled Hydrogel Granules, Langmuir 2006, 22, 8618-8622.
[88] Z. Nie, W. Li, M. Seo, S. Xu, E. Kumacheva: Janus and Ternary Particles Generated by Microfluidic Synthesis: Design, Synthesis, and Self-Assembly, Journal of the American Chemical Society 2006, 128, 9408-9412.
[89] C.-H. Chen, R. K. Shah, A. R. Abate, D. A. Weitz: Janus Particles Templated from Double Emulsion Droplets Generated Using Microfluidics, Langmuir 2009, 25, 4320-4323.
[90] C.-H. Chen, A. R. Abate, D. Lee, E. M. Terentjev, D. A. Weitz: Microfluidic Assembly of Magnetic Hydrogel Particles with Uniformly Anisotropic Structure, Advanced Materials 2009, 21, 3201-3204.
[91] A. S. Utada, E. Lorenceau, D. R. Link, P. D. Kaplan, H. A. Stone, D. A. Weitz: Monodisperse Double Emulsions Generated from a Microcapillary Device, Science 2005, 308, 537-541.
[92] M. Seo, C. Paquet, Z. Nie, S. Xu, E. Kumacheva: Microfluidic consecutive flow-focusing droplet generators, Soft Matter 2007, 3, 986-992.
[93] R. K. Shah, J.-W. Kim, J. J. Agresti, D. A. Weitz, L.-Y. Chu: Fabrication of monodisperse thermosensitive microgels and gel capsules in microfluidic devices, Soft Matter 2008, 4, 2303-2309.
[94] S. Seiffert, J. Thiele, A. R. Abate, D. A. Weitz: Smart Microgel Capsules from Macromolecular Precursors, Journal of the American Chemical Society 2010, 132, 6606-6609.
[95] M. Seo, Z. Nie, S. Xu, M. Mok, P. C. Lewis, R. Graham, E. Kumacheva: Continuous Microfluidic Reactors for Polymer Particles, Langmuir 2005, 21, 11614-11622.
[96] S. Q. Xu, Z. H. Nie, M. Seo, P. Lewis, E. Kumacheva, H. A. Stone, P. Garstecki, D. B. Weibel, I.
Gitlin, G. M. Whitesides: Generation of monodisperse particles by using microfluidics: Control over size, shape, and composition, Angew. Chem.-Int. Edit. 2005, 44, 724-728.
[97] Z. Nie, S. Xu, M. Seo, P. C. Lewis, E. Kumacheva: Polymer Particles with Various Shapes and Morphologies Produced in Continuous Microfluidic Reactors, Journal of the American Chemical Society 2005, 127, 8058-8063.
[98] S.-Y. Teh, R. Lin, L.-H. Hung, A. P. Lee: Droplet microfluidics, Lab on a Chip 2008, 8, 198-220.
[99] E. Tumarkin, E. Kumacheva: Microfluidic generation of microgels from synthetic and natural polymers, Chemical Society Reviews 2009, 38, 2161-2168.
[100] J. C. McDonald, D. C. Duffy, J. R. Anderson, D. T. Chiu, H. K. Wu, O. J. A. Schueller, G. M.
Whitesides: Fabrication of microfluidic systems in poly(dimethylsiloxane), Electrophoresis 2000, 21, 27-40.
[101] A. Van Blaaderen, A. Vrij: Synthesis and characterization of colloidal dispersions of fluorescent, monodisperse silica spheres, Langmuir 1992, 8, 2921-2931.
[102] Z. Diwu, Y. Lu, C. Zhang, D. H. Klaubert, R. P. Haugland: Fluorescent Molecular Probes II. The Synthesis, Spectral Properties and Use of Fluorescent Solvatochromic Dapoxyl Dyes, Photochemistry and Photobiology 1997, 66, 424-431.
[103] S. Seiffert, D. A. Weitz: Controlled fabrication of polymer microgels by polymer-analogous gelation in droplet microfluidics, Soft Matter 2010, 6, 3184-3190.
[104] S. Mura, J. Nicolas, P. Couvreur: Stimuli-responsive nanocarriers for drug delivery, Nature Materials 2013, 12, 991-1003.
[105] E. Amstad, S.-H. Kim, D. A. Weitz: Photo- and Thermoresponsive Polymersomes for Triggered Release, Angewandte Chemie International Edition 2012, 51, 12499-12503.
[106] Y. Wang, V. Bansal, A. N. Zelikin, F. Caruso: Templated Synthesis of Single-Component Polymer Capsules and Their Application in Drug Delivery, Nano Letters 2008, 8, 1741-1745.
[107] S. S. Datta, A. Abbaspourrad, E. Amstad, J. Fan, S. H. Kim, M. Romanowsky, H. C. Shum, B. Sun, A. S. Utada, M. Windbergs: 25th Anniversary Article: Double Emulsion Templated Solid Microcapsules: Mechanics And Controlled Release, Advanced Materials 2014, 26, 2205-2218.
[108] M. Windbergs, Y. Zhao, J. Heyman, D. A. Weitz: Biodegradable Core–Shell Carriers for Simultaneous Encapsulation of Synergistic Actives, Journal of the American Chemical Society 2013, 135, 7933-7937.
[109] M. A. Cohen Stuart, W. T. S. Huck, J. Genzer, M. Muller, C. Ober, M. Stamm, G. B. Sukhorukov, I. Szleifer, V. V. Tsukruk, M. Urban, F. Winnik, S. Zauscher, I. Luzinov, S. Minko: Emerging applications of stimuli-responsive polymer materials, Nature Materials 2010, 9, 101-113.
[110] E. V. Skorb, H. Möhwald: 25th Anniversary Article: Dynamic Interfaces for Responsive Encapsulation Systems, Advanced Materials 2013, 25, 5029-5043.
[111] C. S. Karamitros, A. M. Yashchenok, H. Möhwald, A. G. Skirtach, M. Konrad: Preserving Catalytic Activity and Enhancing Biochemical Stability of the Therapeutic Enzyme Asparaginase by Biocompatible Multilayered Polyelectrolyte Microcapsules, Biomacromolecules 2013, 14, 4398-4406.
[112] F. Caruso, D. Trau, H. Möhwald, R. Renneberg: Enzyme Encapsulation in Layer-by-Layer Engineered Polymer Multilayer Capsules, Langmuir 2000, 16, 1485-1488.
[113] K. C. Clarke, A. M. Douglas, A. C. Brown, T. H. Barker, L. A. Lyon: Colloid-matrix assemblies in regenerative medicine, Current Opinion in Colloid & Interface Science 2013, 18, 393-405.
[114] A. V. Kabanov, S. V. Vinogradov: Nanogels as pharmaceutical carriers: finite networks of infinite capabilities, Angewandte Chemie International Edition 2009, 48, 5418-5429.
[115] S. Seiffert: Small but Smart: Sensitive Microgel Capsules, Angewandte Chemie International Edition 2013, 52, 11462-11468.
[116] L.-Y. Chu, A. S. Utada, R. K. Shah, J.-W. Kim, D. A. Weitz: Controllable Monodisperse Multiple Emulsions, Angewandte Chemie International Edition 2007, 46, 8970-8974.
References [117] D. Qin, Y. Xia, G. M. Whitesides: Soft lithography for micro- and nanoscale patterning, Nature
Protocols 2010, 5, 491-502.
[118] A. P. R. Johnston, C. Cortez, A. S. Angelatos, F. Caruso: Layer-by-layer engineered capsules and their applications, Current Opinion in Colloid & Interface Science 2006, 11, 203-209.
[119] J. J. Richardson, H. Ejima, S. L. Lörcher, K. Liang, P. Senn, J. Cui, F. Caruso: Preparation of Nano- and Microcapsules by Electrophoretic Polymer Assembly, Angewandte Chemie International Edition 2013, 52, 6455-6458.
[120] B. G. De Geest, N. N. Sanders, G. B. Sukhorukov, J. Demeester, S. C. De Smedt: Release mechanisms for polyelectrolyte capsules, Chemical Society Reviews 2007, 36, 636-649.
[121] S. Y. Yang, D. Lee, R. E. Cohen, M. F. Rubner: Bioinert Solution-Cross-Linked Hydrogen-Bonded Multilayers on Colloidal Particles, Langmuir 2004, 20, 5978-5981.
[122] A. N. Zelikin, J. F. Quinn, F. Caruso: Disulfide Cross-Linked Polymer Capsules: En Route to Biodeconstructible Systems, Biomacromolecules 2006, 7, 27-30.
[123] H. Lee, R. Mensire, R. E. Cohen, M. F. Rubner: Strategies for Hydrogen Bonding Based Layer-by-Layer Assembly of Poly(vinyl alcohol) with Weak Polyacids, Macromolecules 2011, 45, 347-355.
[124] C. M. Nolan, L. T. Gelbaum, L. A. Lyon: 1H NMR Investigation of Thermally Triggered Insulin Release from Poly(N-isopropylacrylamide) Microgels, Biomacromolecules 2006, 7, 2918-2922.
[125] S. Nayak, D. Gan, M. J. Serpe, L. A. Lyon: Hollow Thermoresponsive Microgels, Small 2005, 1, 416-421.
[126] V. Lapeyre, N. Renaudie, J.-F. Dechezelles, H. Saadaoui, S. Ravaine, V. Ravaine: Multiresponsive Hybrid Microgels and Hollow Capsules with a Layered Structure, Langmuir 2009, 25, 4659-4667.
[127] J. D. Debord, L. A. Lyon: Synthesis and characterization of pH-responsive copolymer microgels with tunable volume phase transition temperatures, Langmuir 2003, 19, 7662-7664.
[128] J. Dubbert, K. Nothdurft, M. Karg, W. Richtering: Core-shell-shell and hollow double-shell microgels with advanced temperature responsiveness, Macromolecular Rapid Communications, 2014 DOI: 10.1002/marc.201400495.
[129] D. Putnam: Polymers for gene delivery across length scales, Nature materials 2006, 5, 439-451.
[130] T. Serizawa, K. Wakita, T. Kaneko, M. Akashi: Thermoresponsive properties of porous poly(N-isopropylacrylamide) hydrogels prepared in the presence of nanosized silica particles and subsequent acid treatment, Journal of Polymer Science Part A: Polymer Chemistry 2002, 40, 4228-4235.
[131] http://www.ncnr.nist.gov/resources/activation/, 28.07.2014
[132] N. Dingenouts, S. Seelenmeyer, I. Deike, S. Rosenfeldt, M. Ballauff, P. Lindner, T. Narayanan:
Analysis of thermosensitive core-shell colloids by small-angle neutron scattering including contrast variation, Physical Chemistry Chemical Physics 2001, 3, 1169-1174.
[133] W.-F. Dong, J. K. Ferri, T. Adalsteinsson, M. Schönhoff, G. B. Sukhorukov, H. Möhwald:
Influence of Shell Structure on Stability, Integrity, and Mesh Size of Polyelectrolyte Capsules:
Mechanism and Strategy for Improved Preparation, Chemistry of Materials 2005, 17, 2603-2611.
[134] C.-J. Cheng, L.-Y. Chu, P.-W. Ren, J. Zhang, L. Hu: Preparation of monodisperse thermo-sensitive poly(N-isopropylacrylamide) hollow microcapsules, Journal of Colloid and Interface Science 2007, 313, 383-388.
[135] Y. Zhang, M. Jiang, J. Zhao, X. Ren, D. Chen, G. Zhang: A Novel Route to Thermosensitive Polymeric Core–Shell Aggregates and Hollow Spheres in Aqueous Media, Advanced Functional Materials 2005, 15, 695-699.
[136] J. Qian, F. Wu: Synthesis of Thermosensitive Hollow Spheres via a One-Pot Process, Chemistry of Materials 2007, 19, 5839-5841.
[137] S. Wu, J. Dzubiella, J. Kaiser, M. Drechsler, X. Guo, M. Ballauff, Y. Lu: Thermosensitive Au-PNIPA Yolk–Shell Nanoparticles with Tunable Selectivity for Catalysis, Angewandte Chemie International Edition 2012, 51, 2229-2233.
[138] H. Senff, W. Richtering: Influence of cross-link density on rheological properties of temperature-sensitive microgel suspensions, Colloid and Polymer Science 1999, 278, 830-840.
[139] J. Deng, Y. Yu, S. Dun, W. Yang: Hollow Polymer Particles with Nanoscale Pores and Reactive Groups on Their Rigid Shells: Preparation and Application as Nanoreactors, J. Phys. Chem. B 2010, 114, 2593-2601.
[140] S.-H. Kim, J.-G. Park, T. M. Choi, V. N. Manoharan, D. A. Weitz: Osmotic-pressure-controlled concentration of colloidal particles in thin-shelled capsules, Nature Communications 2014, 5.
[141] F. Chu, F. Polzer, N. Severin, Y. Lu, A. Ott, J. Rabe, M. Ballauff: Thermosensitive hollow Janus dumbbells, Colloid and Polymer Science 2014, 292, 1785-1793.
[142] C. Scherzinger, O. Holderer, D. Richter, W. Richtering: Polymer dynamics in responsive microgels: influence of cononsolvency and microgel architecture, Physical Chemistry Chemical Physics 2012, 14, 2762-2768.
[143] D. Suzuki, T. Yamagata, M. Murai: Multilayered Composite Microgels Synthesized by Surfactant-Free Seeded Polymerization, Langmuir 2013, 29, 10579-10585.
[144] X. Hu, Z. Tong, L. A. Lyon: Multicompartment Core/Shell Microgels, Journal of the American Chemical Society 2010, 132, 11470-11472.
[145] K. Zhang, J. Ma, B. Zhang, S. Zhao, Y. Li, Y. Xu, W. Yu, J. Wang: Synthesis of thermoresponsive silica nanoparticle/PNIPAM hybrids by aqueous surface-initiated atom transfer radical polymerization, Materials Letters 2007, 61, 949-952.
[146] W. Xu, I. Choi, F. A. Plamper, C. V. Synatschke, A. H. E. Müller, V. V. Tsukruk: Nondestructive Light-Initiated Tuning of Layer-by-Layer Microcapsule Permeability, ACS Nano 2012, 7, 598-613.
[147] Y. Wang, Y. Yan, J. Cui, L. Hosta-Rigau, J. K. Heath, E. C. Nice, F. Caruso: Encapsulation of Water-Insoluble Drugs in Polymer Capsules Prepared Using Mesoporous Silica Templates for Intracellular Drug Delivery, Advanced Materials 2010, 22, 4293-4297.
[148] A. S. Hoffman: The origins and evolution of “controlled” drug delivery systems, Journal of Controlled Release 2008, 132, 153-163.
[149] M. Karg, S. Wellert, I. Pastoriza-Santos, A. Lapp, L. Liz-Marzn, T. Hellweg: Thermoresponsive core-shell microgels with silica nanoparticle cores: size, structure, and volume phase transition of the polymer shell, Physical chemistry chemical physics 2008, 10, 6708-6716.
References [150] W. Burchard, W. Richtering: Dynamic light scattering from polymer solutions, Progress in
Colloid & Polymer Science 1989, 80, 151-163.
[151] C. Scherzinger, P. Lindner, M. Keerl, W. Richtering: Cononsolvency of Poly(N,N-diethylacrylamide) (PDEAAM) and Poly(N-isopropylacrylamide) (PNIPAM) Based Microgels in Water/Methanol Mixtures: Copolymer vs Core−Shell Microgel, Macromolecules 2010, 43, 6829-6833.
[152] C. D. Jones, J. G. McGrath, L. A. Lyon: Characterization of Cyanine Dye-Labeled Poly(N-isopropylacrylamide) Core/Shell Microgels Using Fluorescence Resonance Energy Transfer, The Journal of Physical Chemistry B 2004, 108, 12652-12657.
[153] B. Z. C. Nighat Kausar, Martin J. Snowden, in Smart Polymers: Applications in Biotechnology and Biomedicine, Vol. 2 (Ed.: B. M. Igor Galaev), 2008, pp. 137-175.
[154] M. J. Murray, M. J. Snowden: The preparation, characterisation and applications of colloidal microgels, Advances in Colloid and Interface Science 1995, 54, 73-91.
[155] A. Pich, W. Richtering, in Chemical Design of Responsive Microgels, Vol. 234 (Eds.: A. Pich, W.
Richtering), Springer Berlin Heidelberg, 2011, pp. 1-37.
[156] G. R. Deen, T. Alsted, W. Richtering, J. S. Pedersen: Synthesis and characterization of nanogels of poly(N-isopropylacrylamide) by a combination of light and small-angle X-ray scattering, Physical Chemistry Chemical Physics 2011, 13, 3108-3114.
[157] C. H. Hofmann, F. A. Plamper, C. Scherzinger, S. Hietala, W. Richtering: Cononsolvency Revisited: Solvent Entrapment by N-Isopropylacrylamide and N,N-Diethylacrylamide Microgels in Different Water/Methanol Mixtures, Macromolecules 2012, 46, 523-532.
[158] A. Pich, S. Bhattacharya, Y. Lu, V. Boyko, H.-J. P. Adler: Temperature-Sensitive Hybrid Microgels with Magnetic Properties, Langmuir 2004, 20, 10706-10711.
[159] W. Richtering, A. Pich: The special behaviours of responsive core-shell nanogels, Soft Matter 2012, 8, 11423-11430.
[160] T. Trongsatitkul, B. M. Budhlall: Microgels or microcapsules? Role of morphology on the release kinetics of thermoresponsive PNIPAm-co-PEGMa hydrogels, Polymer Chemistry 2013, 4, 1502-1516.
[161] Q. Sun, Y. Deng: In Situ Synthesis of Temperature-Sensitive Hollow Microspheres via Interfacial Polymerization, Journal of the American Chemical Society 2005, 127, 8274-8275.
[162] M. Horecha, V. Senkovskyy, M. Stamm, A. Kiriy: One-Pot Synthesis of Thermoresponsive PNIPAM Hydrogel Microcapsules Designed to Function in Apolar Media, Macromolecules 2009, 42, 5811-5817.
[163] P. Podsiadlo, S. G. Kwon, B. Koo, B. Lee, V. B. Prakapenka, P. Dera, K. K. Zhuravlev, G. Krylova, E. V. Shevchenko: How Hollow Are Hollow Nanoparticles?, Journal of the American Chemical
[163] P. Podsiadlo, S. G. Kwon, B. Koo, B. Lee, V. B. Prakapenka, P. Dera, K. K. Zhuravlev, G. Krylova, E. V. Shevchenko: How Hollow Are Hollow Nanoparticles?, Journal of the American Chemical