Atomic percent Silicon
Appendix 6. Structural data for oxides listed in Table 21.
Appendices
Product System, Lattice parameters, (lit. values) / Â
space group a b c
TiOz (TiCU) Tet. I4i/amd 3.793 (3.785) 9.519(9.514) TiOz (TiCU) Tet. P4z/mnm 4.585 (4.593) 2.957 (2.959) ZrOz Mono. P2i/c 5.155 (5.142)
P= 98.07° (99.31°)
5.251 (5.206) 3.340 (3.313)
HfOz Mono. P2i/c 5.124 (5.12) p= 97.62° (98.0°)
5.201(5.18) 5.255 (5.25)
VzOa Hex. R-3c 4.948 (4.959) 13.941 (14.003)
VOz Tet. P4z/miun 4.534 (4.530) 2.881 (2.869)
LiNbOa Hex. R3c 5.155 (5.148) 13.851 (13.863)
LiTaOa Hex. R3c 5.159 (5.154) 13.727 (13.784)
CizOa Hex. R-3c 4.962 (4.958) 13.586 (13.587)
MoOz (MoCla) Mono. P2i/c 5.646 (5.607) p= 118.99° (120.94°)
4.872 (4.860) 5.656 (5.624)
MoOz (Mods) Mono. P2]/c 5.611 (5.607) P= 120.73° (120.94°)
4.872 (4.860) 5.622 (5.624)
WOz Mono. P2i/c 5.559 (5.556) P= 120.31° (120.42°) 4.889 (4.893) 5.656 (5.658) MnO Cub. Fm3m 4.440 (4.445) ReOz Orth. Pbcn 4.824 (4.809) 5.622 (5.643) 4.486 (4.601) Fea04 Cub. Fd3m 8.399 (8.394) RuOz Tet. P4z/mnm 4.502 (4.491) 3.111 (3.106) Ru Hex. P6a/mmc 2.703 (2.706) 4.282 (4.281) OsOz Tet. P4z/nmm 4.496 (4.500) 3.167 (3.184) Os Hex. P6a/mmc 2.723 (2.735) 4.310 (4.319) CoO Cub. Fm3m 3.929 (3.933) LiRhOz Cub. 4.274 (4.258) Rh Cub. Fm3m 8.409 (8.413) IrOz Tet. P4z/mmn 4.506 (4.498) 3.162 (3.154) NiO Cub. Fm3m 4.277 (4.195) PdO Tet. P4z/mmc 3.042 (3.043) 5.330 (5.336) Pta04 Cub. Pm3n 5.608 (5.585) CuzO Cub. Pn3m 4.267 (4.268)
ZnO Hex. P6a/mc 3.258 (3.250) 5.164 (5.207)
CdO Cub. Fm3m 4.670 (4.695)
References
References
1. R. T. Paine in Inorganometallic Chemistry, T. P. Fehlner (Ed.), Modern
Inorganic Chemistry series, J. P. Fackler Jr. (Ser. Ed.), Plenum, New York,
1992.
2. L. L. Hench and D. R. Ulrich (Eds ), Ultrastructure Processing o f Ceramics,
Glasses and Composites, Wiley, New York, 1984.
3. R. W. Rice in Design o f New Materials, D. L. Cocke and A. Clearfield (Eds), Plenum, New York, 1978.
4. D. Segal, Chemical Synthesis o f Advanced Ceramic Materials, Cambridge, Cambridge, 1989.
5. A. Bauger, J. C. Moutin and J. C. Niepce, J. Mater. Set, 1983, 18, 3041.
6. C. D. Chandler, Q. Powell, M. J. Hampden- Smith and T. T. Kodas, J. Mater. Chem., 1993, 3, 775.
7. L. E. Toth, Transition Metal Carbides and Nitrides, Plenum, New York, 1971.
8. N. N. Greenwood and A. Eamshaw, Chemistry o f the Elements, Pergamon, London, 1984.
9. D. M. P. Mingos and D. R Baghurst, Chem. Soc. Rev., 1991, 20, 1.
10. P. K. Bachmann, Adv. Mater., 1990, 2, 195.
11. R. N. Gedye, F. E. Smith and K. G. Westaway, Can. J. Chem., 1988, 66, 17.
12. S. L. McGill and J. W. Walkiewiez, J. Microwave Power Electromag. Energy Symp. Summ., 1987, 175.
13. K. Chatakondu, M. L. H. Green, D. M. P. Mingos and S. M. Reynolds, J.
Chem. Soc., Chem. Commun., 1989, 1515.
References
14. D. R. Baghurst, A. M. Chippindale and D. M. P. Mingos, Nature, 1988, 332, 311.
15. D. R. Baghurst and D. M. P. Mingos, J. Chem. Soc., Chem. Commun., 1988, 829.
16. A. G. Whittacker and D. M. P. Mingos, J. Chem. Soc., Dalton Trans., 1992, 2751.
17. C. C. Landry and A. R. Barron, Science, 1993, 260, 1653.
18. R. Dagani, Chem. Eng. News, 1988, 66, 7.
19. M. Ebelman, Chimie. Phys., 1846, 16, 129.
20. M. Ebelman, C. R. Acad. Sci., 1847, 25, 85.
21. L. L. Hench and J. K. West, Chem. Rev., 1990, 90, 33.
22. L. L. Hench and D. R. Ulrich (Eds.), Science o f Ceramic Chemical
Processing, Wiley, New York, 1984.
23. S. H. Wang, C. Campbell and L. L. Hench, in Ultrastructure Processing o f
Advanced Ceramics, J. D. Mackensie and D. R. Ulrich (Eds.), Wiley, New
York, 1988.
24. B. E. Yoldas, Bull. Am. Ceram. Soc., 1975, 54, 286.
25. C. J. Brinker and G. W. Scherer, Sol- Gel Science: The Physics and
Chemistry o f Sol- Gel Processing, Academic Press Ltd, London, 1990.
26. E. Matijevic, M. Bundnick and L. J. Meites, J. Colloid Interface Sci., 1977, 61, 302.
27. E. Matijevic, in Science o f Ceramic Chemical Processing, L. L. Hench and D. R. Ulrich (Eds ), Wiley, New York, 1986.
28. E. Matijevic in Ultrastructure Processing o f Advanced Ceramics,
References
29. A. Szweda, A. Hendry and K. H. Jack, Proc. Brit. Ceram. Soc., 1981, 31, 107.
30. A. H. Cowley, R. A. Jones, C. M. Nunn and D. L. Westmoreland, Chem. Mater., 1990, 2, 221.
31. Q. Li, C. M. Sorensen, K. J. Klabunde and G. C Hadjipanayis, Aerosol Sci. Tech., 1993, 19, 453.
32. S. Lee, O. A. Shlyaktin, M. 0. Mun, M. K. Bae and S. I. Lee, Superconductor Sci. Tech., 1995, 8, 60.
33. E. Uzunova, D. Klissurski and S. Kassabov, J. Mater. Chem., 1994, 4, 153.
34. G. A. M. Hussein, Thermochim. Acta, 1994, 244, 139.
35. H. W. Wang, D. A. Hall and F. R. Sale, J. Therm. Anal, 1994, 41, 605.
36. E. Matijevic, Ann. Rev. Mater. Sci., 1985, 15, 483.
37. T. Trindade, J. D. Pedrosa de Jesus and P. O’Brien, J. Mater. Chem., 1994, 4, 1611.
38. S. M. Stczynski, J. G. Brennan and M. L. Steigerwald, Inorg. Chem., 1989, 28, 4431.
39. T. A. Guiton, C. I. Czkaj, M. S. Rau, G. L. Geoffroy and C. G. Pantano,
Mater. Res. Soc. Symp. Proc., 1988, 121, 503.
40. M. L. Steigerwald, Chem. Mater., 1989,1, 52.
41. J G Brennan, T. Siegrist, S. M. Stuczynski and M. L. Steigerwald, J. Am. Chem. Soc., 1989, 111, 9240.
42. D. V. Baxter, M. H. Chisholm, V. F. Distasi, G. J. Gama, A. L. Hector and I. P. Parkin, Chem. Mater., submitted for publication.
References
43. R. M. Laine and A. S. Hirschon in Transformation o f Organometallics into
Common and Exotic Materials: Design and Activation, R. M. Laine (Ed.),
M. NijhofF, Dordrecht, 1988.
44. G. L. Brown and L. Maya, J. Am. Ceram. Soc., 1988, 71, 78.
45. S. Yajima, K. Okamura, J. Hayashi and M. Omori, J. Am. Ceram. Soc., 1976, 59, 324.
46. K. Okamura, Composites, 1987,18, 107.
47. S. Yajima, T. Iwai, T, Yamamura, K. Okamura and Y. Hasegawa, J. Mater. Sci., 1981, 16, 1349.
48. K. Okamura, M. Sato, Y. Hasegawa and T. Amano, Chem. Lett, 1984, 2059.
49. S. T. Oyama, Catal. Today, 1992, 15, 179.
50. L. Leclercq, K. Imura, S. Yoshida, T. Barbee and M. Boudart, Preparation o f Catalysts II, B. Delmon, P. Grange, P. A. Jacobs and G. Poncelet (Eds ), Elsevier, Amsterdam, 1979.
51. S. Iwana, K. Hayakawa and T. Arizumi, J. Crystal Growth, 1982, 56, 265;
ibid., 1984, 66, 189.
52. P. Ronsheim, A. Mazza and A. N. Christensen, Plasma Chem. Plasma Process., 1981, 1, 135.
53. A. Brenner and R. L. Burwell Jr., J. Am. Chem. Soc., 1975, 97, 2566.
54. D. E. Willis, J. Catal, 1983, 84, 344.
55. M. J. Ledoux, C. Pham- Huu, S. Marin, M. Weibel and J. Guille, C R. Acad. Sci. Paris, t. 310, Serie II, 707, 1990.
56. J. S. Lee, S. T. Oyama and M. Boudart, J. Catal, 1987,106, 125.
References
58. L. L. Wang, Z. A. Munir and Y M. Maximov, J. Mater. Sci., 1993, 28, 3693.
59. D. Belitkus, J. Metals, January 1972, 30.
60. A. G. Mershanov and I. P. Borovinskaya, Comb. Sci. Tech., 1975,10, 195.
61. L. M. Sheppard, Adv. Mater. Proc., 1986, 2, 25.
62. H. C. Yi and J. J. Moore, J. Mater. Sci., 1990, 25, 1159.
63. B. Manley, J. B. Holt and Z. A. Munir, Mater. Sci. Res., 1984,16, 303.
64. O. R. Bermann and J. Barrington, J. Amer. Ceram. Soc., 1966, 49, 502.
65. M. Ouabdesselam and Z. A. Munir, J. Mater. Sci., 1987, 22, 1799.
66. K. Hirao, Y. Miyamoto and M. Koizumi, Materials (Jpn.), 1987, 36 (400), 12.
67. M. Ohyanagi, M. Koizumi, K. Tanihata, Y. Miyamoto, O. Yamada, I. Matsubara and Y. Yamashita, J. Mater. Sci. Lett., 1993, 12, 500.
68. K. Sato, K. Terase and H. Kijimuta, U. S. Patent, 4,399,115 (1983).
69. R. R. Chianelli and M. B. Dines, Inorg. Chem., 1978,17, 2758.
70. A. D. F. Toy in Comprehensive Inorganic Chemistry, J. C. Bailar,
H. J. Emeléus, R. Nyholm and A. F, Trotman- Dickenson (Eds ), Vol. 2, Pergamon, Oxford, 1973.
71. S. Hilpert and A. Wille, Z. Phys. Chem., 1932, 18B, 291.
72. D. E. Corridge, Phosphorus and an Outline o f it's Chemistry, Biochemistry
and Technology, Elsevier, Oxford, 1978.
73. P. R. Bonneau, R. K. Shibao and R. B. Kaner, Inorg. Chem., 1990, 29, 2511.
74. P. R. Bonneau, R. F. Jarvis Jr. and R. B. Kaner, Nature, 1991, 349, 510.
References
75. J. B. Wiley, P. R. Bonneau, R. E. Treece, R F. Jarvis Jr., E. G. Gillan, L. Rao and R. B. Kaner, A. C. S. Symp. Ser., 1992, 499, 369 (Chap. 26).
76. P. R. Bonneau, R. F. Jarvis Jr. and R. B. Kaner, Inorg. Chem., 1992, 31, 2127.
77. J. B. Wiley and R. B. Kaner, Science, 1992, 255, 1093.
78. R. E. Treece, G. S. Macala and R. B. Kaner, Chem. Mater., 1992, 4, 9.
79. I. P. Parkin and A. T. Rowley, Adv. Mater., 1994, 6, 780.
80. I. P. Parkin and A. T. Rowley, J. Mater. Chem., 1995, 5, 909.
81. PDF-2 database. International Centre for Diffraction Data, Swarthmore, PA
19081, USA, 1990.
82. K. Jones in Comprehensive Inorganic Chemistry, J. C. Bailar, H. J. Emeléus, R. Nyholm and A. F, Trotman- Dickenson (Eds ), Vol. 2, Pergamon, Oxford,
1973.
83. B. R. Brown 'mMellor ’s Comprehensive Treatise on Inorganic and Theoretical Chemistry, Vol. 8, Suppl. 1, Nitrogen, Part I, Section III, Longman, London, 1964.
84. J. Flahaut and P. Lamelle, Progress in the Science and Technology o f the
Rare Earths, Vol. 13, Pergamon Press, UK, 1968.
85. C. K. Jorgenson, Oxidation Numbers and Oxidation States, Spriger- Verlag, New York, 1969.
86. A. F. Wells, Structural Inorganic Chemistry, 5th Ed., Oxford, London, 1984.
87. Handbook o f Chemistry and Physics, CRC Press, 55th Ed., 1974.
88. A. MünsXQT, Angew. Chem., 1957, 69, 281.
89. H. H. Hausner and M. G. Bowman (Eds), Fundamentals o f Refractory
References
90. H. A. Johansen, in Survey o f Progress in Chemistry 8, A. Scott (Ed.), Academic Press, New York, 1977, p.57.
91. E. G. Kendall, in Ceramics fo r Advanced Technologies, J. E. Hove and W. C. Riley (Eds ), Wiley, New York, 1965.
92. E. A. Almond in Transformation o f Organometallics into Common and Exotic
Materials: Design and Activation, R. M. Laine (Ed.), M. NijhofF, Dordrecht,
1988.
93. S. R. Kurtz and R. G. Gordon, Thin Solid Films, 1986,140, 277.
94. A. R. Williams, Mût/. Res. Soc. Symp. Proc., 1983, 19, 17.
95. M. Boudart, S. T. Oyama and L. Leclecq, Proc. 7th Int. Cong. Catal, Tokyo, 1980, T. Seiyama and K. Tanabe (Eds ), Vol. 1, p. 587, Kodansha, 1980.
96. S. T. Oyama, J. Catal, 1992, 133, 358.
97. C. B. Murchison and D. A. Murdick, Hydrocarbon Processing, 1981, 60, 159.
98. G. S. Ranhotra, A. T. Bell and J. A. Reimer, J. Catal, 1987, 108, 40.
99. D. J. Sajkowski and S. T. Oyama, Symposium on The Chemistry o f W/Mo
Catalysts, 199th A. C. S. National Meeting, Petroleum Chemistry Division,
Boston, Massachusetts, April 22- 27, 1990.
100. M. L. Cohen, Phys. Rev. B, 1985, 32, 7988.
101. K. Naito and N. Kagegashira, Adv. Nucl Sci Tech., 1976, 9, 99.
102. I. P. Parkin and J. D. Woolins, Phosphorus, Sulfur and Silicon, 1990, 47, 141.
103. P. Eckerlin and P. H. Kandler, Structure Data o f Elements and Intermetallic
Phases, Vol. 6, and W. Pies and A. Weiss, Crystal Structure Data o f
Inorganic Compounds, Vol. 7, in Landolt- Bornstein Numerical Data and
Functional Relationships in Science and Technology, New Series, K. -H.
Hellwege and A. M. Hellwege (Eds ), Springer- Verlag, Berlin, 1971.
References
104. H. P. Klug and L. E. Alexander, X- ray Diffraction Procedure fo r
Polycrystalline and Amorphous Materials, 2nd Ed., Wiley, New York, 1974.
105. K. Nakamoto, Infrared and Raman Spectra o f Inorganic and Coordination
Compounds, 3rd Ed., Wiley, Chichester, 1978.
106. R. L. LaDuca and P. T. Wolczanski, Inorg. Chem., 1992, 31, 1311.
107. D. V. Baxter, M. H. Chisholm, G. J. Gama, A. L. Hector and I. P. Parkin,
Chem. Vap. Deposition, 1995, 1, 49.
108. O. Kubaschewski, C. B. Acock and P. J. Spencer, Materials
Thermochemistry, 6th Ed., Pergamon, Oxford, 1993.
109. Equations solved using Mathematica program. Version 1.0, T. Gray, Wolfram Research Inc., Champaign, II 61820.
110. 1983 Complete Temperature Measurement Handbook, Table VI, Omega Engineering Inc., Stanford, CT 06907.
11 Oa. Practical Surface Analysis. Volume I- Auger and X-ray Photoelectron
Spectroscopy, D. Briggs and M. P. Seah (Eds.), 2nd Ed., Wiley, Chichester,
1990.
111. E. G. Gillan andR. B. Kaner, Inorg. Chem., 1994, 33, 5693.
112. Optimised Boron Analysis with the Kevex Microanalysis System,
Microanalysis Tech. Bull. No. 11, Kevex Corporation, 1105 Chest Drive, Foster City, CA 94404.
113. D. A. Vennos, M. E. Badding and F. J. DiSalvo, Inorg. Chem., 1990, 29, 4059.
114. D. A. Vennos and F. J. DiSalvo, J. Sol. State Chem., 1992, 98, 318.
References
116. A. Wilson in Mellor ’s Comprehensive Treatise on Inorganic and Theoretical
Chemistry, Vol.
Vni,
Suppl. Ill, Phosphorus, Section YU, Longman, London,1971.
117. J. D. Smith in Comprehensive Inorganic Chemistry, J. C. Bailar,
H. J. Emeléus, R. Nyholm and A. F, Trotman- Dickenson (Eds.), Vol. 2, Pergamon, Oxford, 1973.
118. A. T. Rowley and I. P. Parkin, J. Mater. Chem., 1993, 3, 689.
119. J. C. Fitzmaurice, I. P. Parkin and A. T. Rowley, J. Mater. Chem., 1994, 4, 285.
120. R. E. Treece, G. S. Macala, L, Rao, D. Franke, H. Eckert and R. B. Kaner,
Inorg. Chem., 1993, 32, 2745.
121. R. E. Treece, J. A. Conklin and R. B. Kaner, Inorg. Chem., 1994, 33, 5701.
122. N. N. Greenwood and E. A. Eamshaw, The Chemistry o f the Elements,
Pergamon, London, 1990.
123. D. E. C. Corbridge, Topics in Phosphorus Chemistry, 1966, 3, 57.
124. J. H. Krieger, Agr. Chemicals, 1952, 7, 46 and 135.
125. R. E. Treece, E. G. Gillan and R. B. Kaner, Comment Inorg. Chem., 1995,16, 313.
126. R. V. Parish, NMR, NQR, EPR andMossbauer Spectroscopy in Inorganic
Chemistry, Ellis Horwood, Chichester, 1990.
127. K. S. Irani and K. A. Gingerich, J. Phys. Chem. Solids, 1963, 24, 1153.
128. Values of Tad were calculated as described in section 2.3 using published data.^®* Heat capacity data for HfP were estimated by the methods of Kelly and Kellogg with Ünal’s revised data tables (assumes a predominantly ionic compound).
129. F. Hulliger, Struct. Bonding, 1968, 4, 83.
References
130. Magnetic Properties, J. S. Kouvel, Intermetallic Compounds,
J. H. Westbrook (Ed.), Wiley, 1967.
131. W. B. Pearson, A Handbook o f Lattice Spacings and Structures o f Metals and
Alloys- 2, G. V. Raynor (Ed), International Series o f Monographs in Metal
Physics and Physical Metallurgy, Pergamon, Oxford, 1967.
132. H. Fjellvâg and A. Kjekshus, Acta Chem. Scand, 1986, A40, 17.
133. M. Okada, R. A. Guidotti and J. D. Corbett, Inorg. Chem., 1968, 7,2118.
133a. Inorganic Chemistry, D. F. Shriver, P. W. Atkins and C. H. Langford, Oxford University Press, Oxford, 1992.
134. E. G. Rochow in Comprehensive Inorganic Chemistry, J. C. Bailar, H. J. Emeléus, R. Nyholm and A. F, Trotman- Dickenson (Eds ), Vol. 2, Pergamon, Oxford, 1973.
135. For more recent discussions on silicide bonding: J. H. Weaver, A. Franciosi and V. L. Moruzzi, Phys. Rev. B, 1984, 1984, 29, 3293; G. Rossi, Surf. Sci. Rep., 1987, 7, 1; C. Calandra, O. Bisi and G. Ottaviani, Surf. Sci. Rep., 1985, 4, 271.
136. L. Topor and O. J. Kleppa, Trans. A, 1986, 17, 1217.
137. A. Franciosi, J. H. Weaver and D. G. O’Neill, Phys. Rev. B, 1983, 28, 4889.
138. M. S. Chandrasekharaiah, J. L. Margrave and P. A. G. O’Hare, J. Phys.
Chem. Ref. Data, 1993, 22, 1459.
139. M. E. Schlesinger, Chem. Rev., 1990, 90, 607.
140. F. M. d’Heurle, J. Mater. Res., 1988, 3, 167.
140a. Gas Phase Ion and Neutral Thermochemistry, S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levin and W. G. Mallard, J. Phys. Chem. Ref. Data, 1988, 17, suppl. 1.
References
142. G. Combe, A. L. Hector, A. V. Komarov, M. Lavender and I. P. Parkin, manuscripts in preparation.
143. A. V. Komarov and I. P. Parkin, Polyhedron, in press; A. V. Komarov and I. P. Parkin, J. Mater. Sci. Lett., in press.
144. A. M. Prokhorov and Y. S. Kuz’minov, Physics and Chemistry o f Crystalline
Lithium Niobate, lOP Publishing Ltd, Bristol, 1990.
145. S. A. Weiss, Manganese, the Other Uses, Metal Bulletin Books, London, 1977.
146. N. N. Greenwood, Inorganic Crystals, Lattice Defects and Nonstoichiometry,
Chap. 6, Butterworths, London, 1968.
147. W. Beesk, P. G. Jones, H. Rumpel, E. Schwarzmann and G. M. Sheldrick, J.
Chem. Soc., Chem. Commun., 1981, 664.
148. D. Cahen, J. A. Ibers and M. H. Mueller, Inorg. Chem., 1974, 13, 10 and references therein.
Publications
Publications
The following papers have been published during the course o f this work:
1) “Rapid synthesis of TiN, HfN and ZrN from solid state precursors.” J. C. Fitzmaurice, A. Hector and I. P. Parkin. Polyhedron, 1993, 12, 1295. 2) “Convenient, low energy, solid- liquid metathesis reactions: synthesis of TiN,
TiOz, VN, VO2 and TixVyN (x+y=l).” A. Hector and I. P. Parkin. J. Chem.
Soc., Chem. Commun., 1993, 1095.
3) “Low temperature solid state routes to transition metal oxides via metathesis reactions involving lithium oxide.” A. Hector and I. P. Parkin. Polyhedron,
1993, 12, 1855.
4) “Low temperature routes to early transition metal nitrides.” J. C. Fitzmaurice, A. L. Hector and I. P. Parkin. J. Chem. Soc., Dalton Trans., 1993, 2435. 5) “A convenient, rapid, low energy route to crystalline TiN, VN and TixVyN
(x+y=l).” I. P. Parkin and A. L. Hector. J. Mater. Sci. Lett., 1993, 12, 1856. 6) “Rapid, low energy synthesis of lanthanide nitrides.” J. C. Fitzmaurice,
A. Hector, A. T. Rowley and I. P. Parkin. Polyhedron, 1994,13, 235.
7) “Low energy initiated routes to crystalline metal phosphides and arsenides.” J. C. Fitzmaurice, A. Hector and I. P. Parkin. J. Mater. Sci. Lett., 1994, 13, 1. 8) “Solid state metathesis preparations of group VIII metal oxide powders.”
A. L. Hector and I. P. Parkin. J. Mater. Sci. Lett., 1994, 13, 219.
9) “Self- propagating routes to transition metal phosphides.” A. L. Hector and I. P. Parkin. J. Mater. Chem., 1994, 4, 279.
10) “Room temperature initiated routes to titanium and vanadium pnictides.” A. L. Hector and I. P. Parkin. Inorg. Chem., 1994, 33, 1727.
11) “Metal pnictide synthesis; Self- propagating reactions involving sodium arsenide, antimonide and bismuthide.” A. L. Hector and I. P. Parkin. Z.
Naturforsch. B, 1994, 49b, 477.
12) “Solid state routes to crystalline group IIB chalcogenides. Applications of metathesis reactions.” J. C. Fitzmaurice, A. Hector and I. P. Parkin. Main
Group Met. Chem., 1994, 17,537.
13) “A synthesis of bismuth (III) phosphide: the first binary phosphide of bismuth.” C. J. Carmalt, A. H. Cowley, A. L. Hector, N. C. Norman and I. P. Parkin. J. Chem. Soc., Chem. Commun., 1994, 1987.
Publications
14) “Synthesis of metal silicide powders by thermolysis of metal chlorides with magnesium silicide.” J. C. Fitzmaurice, A. L. Hector, I. P. Parkin and A. T. Rowley. Phosphorus, Sulfur and Silicon, 1995, 101, 47.
15) “Sodium azide as a reagent for solid state metathesis preparations of refractory metal nitrides.” A. L. Hector and I. P. Parkin. Polyhedron, 1995, 14, 913. 16) “Low pressure chemical vapour deposition of metallic films of iron,
manganese, cobalt, copper, germanium and tin employing Bis(trimethyl) silylamide complexes M(N(SiMe3)2)n ” D. V. Baxter, M. H. Chisholm, G. J. Gama, A. L. Hector and I. P. Parkin. Chem. Vap. Deposition, 1995, 1, 49.
17) “Magnesium and calcium nitrides as nitrogen sources in metathetical reactions to produce metal nitrides.” A. L. Hector, I. P. Parkin and A. T. Rowley.
Chem. Mater., 1995, 7, 1728.
18) “Room temperature synthesis in liquid ammonia of zinc, cadmium and mercury sulfides.” A. L. Hector, G. Henshaw, I. P. Parkin and G. A. Shaw. Main
Group Chem., in press.
19) “Molecular routes to metal carbides, nitrides and oxides; Studies of the ammonolysis of metal dialkylamides and silylamides.” D. V. Baxter, M. H. Chisholm, V. F. Distasi, G. J. Gama, A. L. Hector and I. P. Parkin.
Chem. Mater., submitted for publication.