Subject Index to Volume 35255-264

(1)

Page

Werner, H. 232

Wertz, D. W. 233 Wessel,

T.

J. 235 Whang, C. N. 153 White, C. W. 36 White,

H.

S. 234 White, J. M. 235 White, P. 140, 200 Whitesides, G. M. 236 Wiemhofer,

H.

D. 158 Wilczok,

U.

229

Wilde, M. 107

Wilkinson, G. 34 Williams, D. J. 45 Williams, R. S. 38 Winterbottom, J. M. 160 Wittmer, M. 164

Wokaun, A. 107

Wey,

J.

P.

155 White, A. H. 102

Puge Wolf, R. M. 155 Wolfson, S. K. 35 Woodhouse, J. 8. 101 Woollam, J. A. 152 Worley, S. D.

40, 108, 155 Wu, J. C. S. 42 w u ,

s.

c.

230

w u ,

w.

156

Xiao,

Q.

F. 32

Xing, X. 232

x u , c.-L. 42

Xu, D. 38

x u , Y. 102

Xue, Z. 38, 112 Yahikozawa, K. 157 Yakimenko,

L.

M. 35 Yamada, M. I l l

Yamaguchi, H. Yamaka, E. Yamamichi, S. Yamauchi, S. Yamazoe, N. Yang, S.-Z. Yao, S. J. Yaoita, M. Yasuda, K . 4 . Yates, J. T. Ye, S. Yeager, E. Yeo, J. K. Yermakov, A. Yoshida, Y. Young, P. A. Yum, E. K. Zaki, M. I. Zaks, I. A.

Puge I12 240 112 I65 38 234 35 I65 165 109. 140 102 232 238 23, 196 165 152 43

I40 102

Puge Zamashchikov, V. V. 161 Zanicchi, G. I54 Zassinovich, G. 44

Zeijlemaker, H. 46 Zeltser, A. M. I55

Zeper, W. B. 31. 112

Zhang, L. I53

Zhang, S. L. 33 Zhang, S.-W. I63 Zhang, W.-R. 234

Zhang, Z. 160

Zhorov, E. Yu. 44. 239 Zhou, X. C. 152

Zhou, Y.4. 42

Zhu, J. G. I12 Zhukova, T. B. 103 Zhvanetsky, 1. M. 40 Zimmerman,

T.

42 Zink, J. I. 38 Zubkowski, J. D. 37

SUBJECT INDEX TO VOLUME

35

a =abstract Page

Absorption, H, by Pd, a 154, 157 Acetalisation, by Rh(II1)triphos complexes, a 44

Acetals, activation, a 111

Acetone Oxime, carbonylation, a 163

Acetonine, synthesis, a 163

Acetophenone, a

44,

239

Acetylene, reactions, a 40, 159, 163, 236 Adsorption, by IrOJTi electrodes, a 157 CO, on I r / A l z 0 3 , a 42 on Pt electrode, effects, a 102

on Pt-Rh/A120,, a 159

on Pt( 100},reaction monitoring 188

on Rh catalysts, a 41

157

AIROF, a 113

111 cinnamyl, hydrogenation, a 40 C, , from syngas reaction, a 159 ethyl, chemisorption on Pt, Pd, Rh, Ru,

bonding study, a 38

flow rate sensor, a 106

from or-alkene hydroformylation, a 43

bonding study, a 38

electrwxidation, on Pt, a 35, 108, 157, 232

on RuO/C, a 36

extensive use in fuel cells, Grove Symp. 209 formation, from CO hydrogenation, a 237 synthesis from syngas, a 41 primary, aerobic oxidation, a 163 synthesis from CO+H,, a 42, 109 formation by hydroformylation, a 43, 239 45 dehydrogenation, a 159, 239

production 152, 161, 195

Alkenes, hydrogenation, homogeneous, a 161, 162 reactions, a 161, 163, 238, 239 hydroformylation, a 43, 239 Alkenyl Iodonium Salt, coupling with olefins, a 238 Alkylation, asymmetric Pd allylic, a 161

Alkylthiols, formation, a 152

H, by Pd/glassy C electrodes, a

Alcohols, allyl, cyclopentannulation, a 110 allylic, for enol production, a

methyl, chemisorption on Pt, Pd, Rh, Ru,

phthalic, electrooxidation, a 111

allylation, a 111

Aldehydes, activation, a 111

Alkanes, bridged.polycyclic, by RuO,, a

Alkylation-Alder Ene, cyclisation, a 110

Page

44, 111, 161, 162 Alkyl-Boron Compounds, polymerisation, a 43

Allenes, carbopalladation, a 44

Ally1 Benzene, hydroformylation, a 110 Allylation, primary alcohols, a I l l Alkynes, 1-Alkynes, reactions, a

Allylic Acetates, for or,P-unsaturated ketones, a 1 1 I

Allylsilanes, synthesis, a 162

Aluminium, grain boundary reaction with

Pd-Ag-Cu, a 153

Amines, carbonylation 70

Ammonia, carbonylation 70

in nitric acid production, a 236 oxidation, on knined gauze 58

photoproduction, from N 2 , by Pt/CdS system, a 104

reaction with CO, a 108

sensor 200

Amorphisation, on milling Pd-Si, a 154 platinum metals, solid state 83

Aniline, for diphenylurea, a 238

Anion, tandem capture-cyclisation, by Pd(O), a 161 110 Aromatisation, n-heptane, n-hexane, a 39, 40, 107

Aryl Halides, carbonylation 70

Aryl Iodides, coupling, a 237

43

Aryldithiocarbamats, a 237

Aryl-Aryl, exchange, a 238

Ascorbic Acid, oxidation, by Ru complexes, a 233 Barrier Layers, a 45, 46, 112, 113, 164, 240

Benzene, formation, a 160, 236

Benzonitrile, electrocatalytic hydrogenation, a 103 Bismuth, effect on lactose oxidation, a 40

Bonding, fusion, a 235

Book Reviews, Precious Metals Science

for HCN synthesis, a 160

Annulation, by Pd catalyst, a

reaction with vinyl-, cyclopropane/butane, a

and Technology 93

The Platinum Yearbook 1991 137

“Platinum 1991” 132

Bushveld Igneous Complex 132

Butane, n-, hydrogenolysis, isomerisation, on Pt, a 235 Butanediols, electrwxidation, a I l l

Cameras, IR 45, 64

Cancer, anti-tumour Pt complex, a 46 46 metal complex anti-cancer drugs, review, a

(2)

Page I I ? Capacitors, with Pt/Ta barrier layers. a

Carboannulation, vinylic cyclopropanes.

Carbon Oxides, CO, adsorption. on Ir/Al:O,. a 42

on Pi, Rh, Pi-Rh catalysts. a I59

on Rh(1). Rh(I)/TiO,, a 41

chemisorption. on Pt-Sn/Al,O *. a 107

on Pt/AI,O,. TiO,. a 235

CO-NO, Ce.

K

effects on Rh/AI,O,. a 41

cycling, for Pd/AI,O, restructuring. a 40

detection in presence of NO. SO:. a 235

effect on ethene hydrogenation. a I07 32

electrooxidation, see Electrodes

for aromatic nitro compound reduction. a 162

for diphenylurea. a 238

hydrogenation, on Rh catalysts. a 109, 160. 237

on Ru clusterslinorganic oxides. (1 42

interaction with 0, on Ir/Al,O,. a 42

on,Rh!Al,O,, displacement by P H I . a 109

oxidation, on Pt/SnO, , a I07

on PdCI,-CuCI,/AI,O,,C. a 109

poisoning on Pd/SiO,. characterisation. a 41

reaction with NH

,

a I08

Ru

carbonyl complexes 70 43. I l l Carboxylic a-Amino Acids, synthesis. a 161

Catalysis, biphasic, a I62

by Ru carbonyls 70

heterogeneous, a 39-42, 106-1 10. 159-160, 235-237

homogeneous, a 42-45, 1 1 0 - 1 12. 161-163, 237-239

Catalysts, EUROPT-I, for CH, conversion I95

for diesel engines 178. 187

Iridium, wire, for HCN synthesis, a I60

Iridium Complex, stabilised by 0 donor

I r / A l l O , , C O + O , adsorption, interactions. a 42

Irlsupport, precursor stoichiometry. a I07

Osmium Complex, OsHCI(CO)(PIPr, 1,.

hydrosilylations, a I62

IH, 0 s

,

(CO),l/poly-naphthalene, olefin

isomerisation, a I l l

Palladium Complexes, Pd acetate

+

di-imine ligands, vinylations, a 43

PdCl l(dppf). polymerisations, a 43

by cluster compounds 10

three-way. SAE conference 94

ligand, hydrosilylation, a 44

PdCl 2(PhCN),. aryldithiocarbonimidate PdCl ,(Ph, P), styrene

PdCl,/Ph, PC,H,SO ,Na, heptene Pd(0). tandem cyclisation-anion capture, a Pd(O)L,+vinylic/arylic halides,

carbopalladations, a 44

Pd(I1). Alder ene reaction, a

Pd(1I) acetate, carbo-, heteroannulation, a Pd(II), alkyne-cyclopalladations, a I l l Pd(l1) +onium salts

+

triphenylphosphine,

for diphenylurea, a 238

Pd(OAc), , @-vinylation, a 161

C-C coupling. a 238

rearrangement, a 237

hydrocarboxylation, a 161

hydrocarboxylation. a 238 161

I10 alkylation of ally1 substrate, a

110

43

Catalysts fcontcl.) Puge

Pd(OAc),.

H ?

+CCI, reaction. (1 43

reactions, a 237

triflate reactions. ( I 238

Pd(OAc),. Pd(PPh,),. PdCI,. coupling Pd(OAc),(PPh,), + C u iodide. vinyl Pd(OAc), + ( +)DIOP. asymmetric

alkylati Pd(0:CC PI

ons. (I 161

I26

' . H . ) ? . mild CH, oxidation

i(PFu ,)[CI,. cyclohexenone annulation. a 238

,-p-CH < ) I , aryl-aryl Pd(PPh ) : (C H.

exchange. (I 238

Pd,(dba),.CHCI *. coupling reactions. ti 161

(DIAN)Pd(olefin). hydrogenations. a 161

IPd(pyridine. phosphine)l(BF, ),.

dimerisations, a I10

I(dppp)Pd(solvent),I[Xl

,.

carbonylations. LI 161

Palladium, industrial uses. review. ( I 44

poisoning by metal ions, a I08

Pd, Pd-Pt, Pd-RhlC, SiO,, TiO,, propylcne

oxidation. a I60

109

PdCI?, PdCI,-CuCI,/AI,O,, CO oxidation. ( I

PdCll +Keggin-type heteropoly anions, reductive PdCl, /CuCI? IHOAc, propylene oxidation. LI 43

P d ( l l l ) , sulphided. C ? H , cyclisation. (1 236

I

ox

Pd-BilC, lactose oxidation. ( I 40

PdlAIPO,, styrene hydrogenation. ( I I 59

I

ox

CO-NH, reaction. u I08

surface restructuring o n CO cycling. ti 40 Pd/Al,O,:SiO, +Na. Fe, Mn oxides,

preparation. structure. properties. u I08

P d l a - A l , O , , C , H , hydrogenation. ( I 236

PdlC, reaction of pyrimidine nucleosides

+

vinyl/allylic triflates. ( I I60

PdlF-polymer Nation, olefin conversion. u 106

PdlHY, pretreatment. Cr promoter effects. LI 109

PdlHY, /NaHY, /Nay. methylcyclopentane

conversions. n I60

P d l L a , O , , in high pressure IR cell.

hydrogenation. ( I 40

PdlMgO. phenol hydrogenation. LI 236

PdlNaY, lCaY zeolites, HC conversions. LI 160

PdlPTFEINafion, cyclohexene hydrogenation. ( I 106

Pd/rare earth oxide, support effects. ( I I09

PdlSAPO-I I , I -hexene conversion. II 40

PdlSiO,, characterisation. MCP

hydrogenolysis. a 41

carbonylation. a 43

PdS/AI:O,, hexene-l hydrogenation. a I59 Pd(Pt)/AI:O,, S poisoning. ( I

PdlA1,O $, CH, oxidationiconibustion. ( I

promoted, MeOH synthesis. ( I 41

Pdlsupport, H combustion. ( I I60

Pdly-Al,O,, C , H l - C , H , hydrogenation. ( I 40

Platinum Complexes, bis(divinyltetraiiicthyl- disi1oxane)Pt. colloid formation. ( I I10

Pt blues. H: evolution. ( I 43

PtX,(CO)(C,H, "). synthesis. t i 237

IPt(C , H 4 ) ( ( +)-DIOP)+PtCl ,((+ I-DIOP)I. hydrciformy lat ion. ( I 41

Pt(ll)-NaI-HCIO,-HIO. vinyl halogenidc

reduction. ( I 161

PI-H. +Ph ,Si(C =CCMc ):

.

ring .rysteiiis. with phosphinito ligandb. hydrofmnylation. (143

cis-IPtC12(PPh ,O,I/SnCI,. oletin

Platinum, diolefin(dialkyl)Pt(lI) hydrogenation. ~1236 236 Pt, Pd, Rh, Ir, acetylene hydrogenation.

C effects. ( I IS9

Pt black, for Pt complex hydrogenation 236

Pt clusterslchelate resin-Na, Mg, Al

complexes, preparation. ( I 40 Pt oxideslTiO,, CdS, aqueous phntncatalytic

alkenyl silanes. LI 42

hydroformylation. ( I I10

in nitric acid production. t i

(3)

Catalysts (conrd.) Page Pt planes, olefin hydrogenation, a 159 Pt(lll), CH,I, CO coadsorption, a 235 Pt-Ce/SiO,, microstructure, reactivity, a I08 Pt-COX, 0 electroreduction, a 103 Pt-IrlAl,O

,,

n-heptane aromatisation, a 107 Pt-IrlAl,O,,

-no,,

/TiO,, support effects, a 236 Pt-Ir/support, precursor stoichiometry, a 107 Pt-Ni-Nb-Sn-Pt, HCHO electrooxidation, a 157 Pt-Re/Al,O1, &hydrogenation, preparation, a 107 Pt-SnlAl, 0

,,

chemisorption, XPS, a 107 n-heptane aromatisation, a 107 IPtCI,(SnCI,),lz -/y-Al,O,, alkane

dehydrogenation, a 159

Pt/,

Pt-Rh/Al,O,, CO adsorption, a 159 Pt/AI,O

,,

cinchona-modified, ligand-

Pt-Au colloids, H, photoevolution 22 Pt-GalAl,O,, n-hexane conversion, a 39

Pt-Re-S/AI,O,CI, reforming reactions, a 39

accelerated catalysis, a 39

ethene hydrogenation, CO effects, a I07

S

poisoning, SMSI, a 235

Pt/AI,O, pillared clay, hydrocracking,

isomerisations, a 159

R/AI,O,-CI, deactivation on coking, a 235

R / C , H oxidation, a 232

Pt/F-polymer Nation, olefin conversion, a 106 Pt/H-mordenite, n-heptane hydroconversion, a 107 PtlKL, n-hexane aromatisation, a 40 Pthylon, Sn-Ptlnylon, liquid-phase

hydrogenation, a 40

Pt/Pr,O,

,, alcohol production, from syngas,

a 159 PtlPTFEINafion, cyclohexene hydrogenation, a 106 106 Pt/SnO,/SiO,, CO low temperature oxidation, a107 Ptlsupport, precursor stoichiometry. a 107 Pt/TiO,, H photoevolution from H,O-MeOH. a 2 3 3

S

isoning, SMSI, a 235

PtlTiK-ZrO,, n-hexane reforming, a 236 PtlZrO,, polycrystalline, MeOH oxidation, a 108 Rhodium, chiral cationic water soluble

Pt/Rh, low-level moisture generation, a

resistance to HIS, a 39

complexes/cation exchange resins, a Rh colloids, hydrosilylation, a

hydrogenation, a wire, HCN synthesis, a

BINAP-Rh(I), photocatalytic asymmetric CP*(P(OMe) j)Rh(C I H,)(H)+*

Rh chiral phosphine ligands, asymmetric Rh chiraU3-al kyl phenanthrol ine , Rh phosphine chelate complexes,

Rh/RC@-C,H,SO,Na),, alkene Rhodium Complexes, asymmetric

hydrosilylation, a reduction, a dimerisations, a hydrogenolysis, a hydrogenation, a

42 238 239 160

239 37 162 162

44

reductions, a I62

RhCI(CO)(PR ,),, pentane

dehydrogenation. a 158

RhPh, PPy, styrene hydroformylation, a 239 Rh(I1) carboxamides, preparation,

cyclopropanation, a 111

Rh(I1)perfluorobutyrate. hydrosilylation, a 162

Rh(PMe,),CI(CO). alkane

dehydrogenation, a 239

238 Rh( +)/DIOP, alkene hydroboration, a

Rh-phosphine, hydroformylation, a

44

Rh-tris(o-rert-butyl-pmethylpheny1)phosphite.

Rh,(CO),, +amine. nitroanisole, tricyclohexylphosphine Rh(H)CI

,

hydroformylation, a 239

nitrotoluene reduction, a 239 chloroarene h drogenolysis, a 162 [RhCI ,(triphos){ acetalisations, a 44

Catalysts (contd.) Page

[Rh(COD)Cll (S)-phephos, asymmetric IRh(C0D)Cll

,

+TMS-CN, acetyl reaction, al I 1 IRh(CO),CIl

,

+phosphanorbornadiene,

hydroformylations, a 162

IRh(diphosphine)(solvent),

1

+, enol

Rh(0) colloidal particles, hydrogenation, a 162 Rho), Rh(I)/TiO,, CO adsorption, I-hexene

hydrogenation, a 41

Rh-Ag/TiO,, MCP hydrogenolysis, a 41 Rh-Ce/SiO,, microstructure, reactivity, a 108 Rh-Co-CulTiO,, HI +CO reaction, a 42 Rh-Co/Al

,

0,

,

MgO, SO,, propylene

hydroformylation, a 237

Rh-MnlSiO

,

CO hydrogenation, a I09 Rh/AI,O,, CO adsorption, a 159 109 ethene hydrogenation, CO effects, a 107

in solar reactor, a 31

interaction with N,, a 155

protection from oxidative degradation, a 109 RhlAI,O, +Ce, K, NO-CO reaction, a 41 Rh/AI,O,-K,CO,, exchange functionalisation 140 Rhly-Al,O,, ZrO,, ZnO, MgO,

c haracterisation

,

a 237

Rh/MgO, for H/CO reaction, a 231 Rh/Nb,O,, C O , hydrogenation, a 41

Rh/SiO,, NCO formation,

a

41

Rh/TiO,, CO, hydrogenation, a 41 IHRh(CO)(PPh

,)I

/membrane,

hydrosilylation, a 44

production, a 1 1 1

CO displacement by PH

,

, a

hydroformylations, a 109

Rh, (CO) /TiO,

,

CO hydrogenation, a 160 Ruthenium, chiral, synthesis, a 111 RuO,, C-H bond activation in alkanes, a

Ru clusterslinorganic oxides, preparation Ruthenium Complexes, K[Ru(EDTA-H)C112H,O,

from Ru ,(CO),, , a 42

45

NH

,

photoproduction, a 104

RuCl(OAc)(PPh ,)

,

triple system, RuCI,(PPh,), +NaOH, ketone RuClJ.3H,0, naphthalene RuHI(tppts)

,

, propionaldehyde Ru(acac)

,,

for naphthalene

electrooxidation, a 233

Ru(cod)(cot), codimerisation, a 163 Ru(NH,),CI,, for naphthalene

Ru,(CO), carboxylates, hydrogenation, a 163 Ru ,(CO) I

,

+tricyclohexylphosphine,

alkene hydroformylation, a 239

decarbonylation, a 163

IRuBr,(Me,SO),l, PPh, oxidation, a 163 [Ru,(CO),(Me,CNO) ,(Me,CNOH),l,

aerobic oxidation, a 163

hydrogenation, a 239

hydrogenation, a 112

RuX,L,, ether oxygenation, a 45

carbonylation, a

[(bpy)(trpy)RuOl +, diol oxidations, a [(Ph. PI .NlIH, Ru, 020) I ,1. for .~

,.

. . ~ ~ -

_.

cvclohex-Zen- 1 -one. ‘u

Ru-CoiCeO,, H-CO reaction, a Ru-Ge, Pb, Sb, Si, Sn/AI,O,, dispersed, Ru/C, quinoline hydrogenation, a Ru/SiO,, C,H, hydroformylation, a Ru/zeolite-A, preparation, size effect, a Ru

,

(CO) I

,

+

bpy/Mg silicate, water gas

x-Allylruthenium, for ketone synthesis, a Catecholborane, for alkene hydroboration, a Ceramics, support for Pd-Ag membrane, for

properties, a

shift reaction, a

H permeation, a

163 1 1 1

45 160

110 110 237 42 110 111 238 154

(4)

Chloroarenes, hydrogenolysis, a

Chloroform, formation, a

Chloronitrobenzenes, reduction, a

Chloroperbenzoic Acid, reaction with [Ru(PPh, ),CI

,Ir

a

Cholesterol, sensor, a

CHP Systems, Grove Symp. Chromium, catalyst promoter, a

for corrosion protection, a

grain boundary reaction with Pd-Ag-Cu, a

Cinnamaldehyde, hydrogenation, a

Cisplatin, a

Clusters, complexes, a

Coal, conversion, a

Coatings, 110,-Ta,O,ibase metal electrodes, a

polymetallic activation

Pd, by electroless deposition, a

Pd modified aluminide Pt, by electroless deposition, a

Pt thin films, ion beam deposited, a

Rh, in reed switches, a

Cobalt, a

Codimerisation. acetvlenes +alkenes. a on Mo-W-Cr alloys

Page

Cerium, additions to Rh/A1201, NO-CO reaction. a 41 Chemical Reaction Fronts on Pt{ 100) I88 Chemical Vapour Deposition, a 38. 152 Chemisorption, CO, H, 0 107. 235 38 Chenevix, Richard, palladium discovery 141 I62 43 CO, MeOH, EtOH, on electrodes, a

162 45 I65 209 109 I63 153 40 46 156 10 I12 157 105 133 82 105 112 165 153 163

Cokine. in cataivsts. 'a 235

22, 34, 36, 110, 238, 239 Colloi&, Pt, Pt-hu,'Rh, Ru, Ag, a

Composites, superconducting 2

Conductors, molecular, IPd(tmp)l I IReO,], a

Conferences, 12th Natl. Fuel Cell Seminar, 1990 2nd Grove Fuel Cell Symp., London, 1991 2nd Intl. Symp. Metal-H Systems, Banff, Intl. Symp. Polymetallic Activation, Palma, Magneto-Optic Recording International SAE Intl. Congress and Exposition, Detroit,

156 17 209

Sept. 1990 24, 195

Sept. 1990 10

Symposium, Tokyo, 1991 I34

Feb.-Mar. 1991 94

Corrosion, in contracts, a 165 104 protection, in Mo-W-Cr-Pd alloys 133 resistance, Cr+PGM additives in acids, a 163 F ion on IrOlTiO ceramic electrode, a 35

Fe40Cr3Ru steel, a 34

of Ir-Ni electrodes, for OER, a I06 platinised porous Ti electrodes, a 35 2, 23, 156 164

34 Pt complex oxides, formed in crucibles, a 156 Rh-Cu single, solidification, a 155

Ruse,, a 155

single, Ir, plastic deformation 196 single, Pt,

Rh,

Pd, surfaces, in H I S O , , a 228

Y,,Ru,,, Er,Ru,, a 34

n-Si, Pt doped, a 228

Cyclic Voltammetry, for Ru-Ti alloys, a 103 Cyclisation, reactions, a 36, 161, 238 Cyclohexane, reactions 27, 39, 160

Cyclohexanone, a 36, 236

Cyclohexenone, annulation, a 238 Cyclohexylamine, carbonylation 70 1 1 1 42 photo-, CdS in PtlCdS dispersions, a

Crucibles, Ir, Pt

Crystallisation, heavy metal fluoride glass, a

Crystals, Pd-Ni-P, a I 02

Pt basal single electrodes, a

Cyclohexene, reactions 74, 106, 110

Cyclopentene, hydroformylation, a 110 Cyclopropanation, catalysts for , a

Cyclo-Z-en-l-one, reactions, a 45 Cyclopropane, reaction, on RuNaAESI, a

Page

Decarbonylation, [Ir,(CO)

,,I

isomcrs. a 237 Decomposition, formamide. a 108

hydrazine. a 155

NO, on Pt{ 100) I88

Dehydroaminoacid, derivatives. hydrogenation,

asymmetric, a 42

Dehydrogenation, alkanes, a 159. 239 cyclic C , , C , hydrocarbons, a 107

pentane, a 158

46 I06

ammonia 200

cholesterol, a I65

CO, in presence of NO, SO,, a 235

CO, a 38, 106

H 85, 106, 234, 235, 240 H, 0, PdlSnO, model sensor, a 106 164

IR, a 45. 64. 208

laser power, a 158

luminescent, using

Ru

complexes, a 105 0, CH,, H , , 0,. by PdlSnO,, PtlTiO,, a 158

0,. a 38, 106, 158

strain gauges 65

titration monitor, by Ir oxide device I37 Deuterium, enriched by T in giant Pd cluster, a 230 in self assembly of catalysts, a 236 Deuterium Exchange, in styrene, a 161 Dienes, reactions, a 40, 44, 107, 159, 237

synthesis, a 161, 163

Diesel Engines, emission control 94, 178, 187 Royal Commission on exhaust control I87 Diffusion, H, in Pd-Ag, a-Pd, PdSiH alloys, a

103, 153, 230 Ir dimers, Ir adatoms, on Ir(l lo), a 155

membranes 33. 138

,

I P t . in 0,. a

163 46 I l l

233 239 238 45 155 105

I I3 I65 I65 234 165 240 165 46 I12 46 234 23 1 33 32 209 37 I02 Electrochemistry, a 34-36, IOj-lOk, I5%158, 232-233 Electrochrornism, AIROFs, a 1 I3 Electrodeposition, Pd-Ni films 208 Electrodeposition, a 38, 105, 106, 234 Electrodes, anodes, DSA, a 95, 105

Pt, urea oxidation, a 35

(5)

Electrodes (contd.) Page

+

(Bi 0 1 ) u . I (Er,O

,

h .

,,

a 233

Pd thin film disc, H insertion, a 157 Pt, PtlNafionlPE, in 0 sensor, a 38, 158 F ion-IrO/TiO ceramic, effluent treatment, a 35 for OER, preparation, a 106 gas diffusion, Pt, uranous nitrate production, a 164 Ir oxide, in titration monitor 137

IrO,-Ta,O,lTa, /Ti, a 157

IrOJTi, adsorption properties, a 157 Ir-PtlNafion, 117/Pt-Ir, in HCI electrolysis, a 35 Ir,Ti I -xOz/Ti, preparation, activity, stability, a 36

Pd, implantated by K, Li, a 103 Pd, Pt-Pd, for ethylene glycol oxidation, a 103 TiO,/SiO,/Pt, response to gases, a 36 ultramicro, TiO,/SiO,/Pt, gas response, a 36 platinised porous Ti, corrosion resistance. a 35 platinised

PI,

in cholesterol oxidase sensor, a 165 polymer/polymer/Pt, preparation, a 35 Pt, adsorbed CO effect, a 102 basal single crystal, a 34 CO electrooxidation, a 232 for glucose oxidation, a 232 in cell with Ru naphthalene oxidation, a 233

in 0 sensor, a 158

in phenol oxidation, waste water control, a 232 102 Pt, Pd, Rh, Ru, chemisorption of CO,

MeOH, EtOH, bonding study, a 38 Pt, Pt/C+metal oxides, MeOH oxidation, a 35, 232

Pt

black, Pt/WO,, for H detection, a 38 Pt disk fabrication, a 234

Pt gauze, rrans-[PtHCl(PEt,),l oxidation, a

35 Pt, Pd, Rh, Ru/poly(pyrrole-viologen)/glassy

103 Pt rotating disc, for 0 , reduction, a 232 Pt(bpy)(CN),/Pt, spectrochemical properties, a 233 Pt-SPE membrane, in fuel cell, a 163 PtlC, for H oxidation, support porosity, a 232

in PEM, a 240

PtlSnO,, FWWO,, in CO sensor, a 38 RuOlC, MeOH oxidation, 0 evolution, a 36 RuO, +TiO,, SnO, activated, a 104 RuO,/C, for alcohol detection, a 106 Ru Ti, -xOz/Ti, catalytic activity, a 36 [Rb(L),CI,I+BF,-, hydrogenations, H,

evolution, a 36

105 Electroless Plating, for Pd thin films, a 38 35 Emission Control, 1991 SAE conference reports 94

diesel exhaust 178, 187

fuel cell benefits, Grove Symp. 209 Energy, more efficient sources, Grove Symp. 209 Enones, conjugated, electrocatalytic hydrogenation, a 103 Enthalpy, of formation, RuGe, RhGe, PdGe, a 154 Environment, fuel cell benefits to 17, 209 Enynes, 1,6-, cycloisomerisation, a 110

Esters, a 45, 161

Etching, Pt foils, in 0 plasma, a 38 Pt-InP photoelectrodes, a 104 Ethane, hydrogenolysis, catalyst activity a 236

Ethene, hydrogenation, a 107

Ethers, luminescence, oxygenation, a 45, 104 Ethyl 2-Formylpropanoate, synthesis, a 162 Ethyl Acrylate, hydroformylation, a 162 Ethyl Chloride, formation, a 43 Ethyl Pyruvate, hydrogenation, a 39 Ethylanthraquinone, 2, hydrogenation, for Pd

catalyst studies, a 108

Ethylbenzene, from styrene, a 236 Ethylene, from vinylhalogenides, a 161

40. 109, 162, 236 cathodes, high temperature,

photo, Pt-InP, etched, a 104

porous in Pt/CaF,/Pt cell, a

C felt, for hydrogenations, a

Electroless Deposition, Pt, Pd, Ni, a Electrolysis, HCI, by SPE electrodes, a

Enols, catalytic production, a I l l

reactions, a

Page 103. 163 107 178. 187 Ethylene Glycol, reactions, a

Ethyne, effect on ethene hydrogenation, a E.E.C., diesel exhaust control

research support 10

Faraday, Michael, history 222

Fischer-Tropsch, catalysts, a I 6 0 Films, anodic Ir oxide films, charge storage, a

Fission, PGM waste reprocessing, a Formaldehvde. a

I13 I I2

PI,

focused ion beam deposition, a

“ ,

Formamide, decomposition, a Formic Acid, electrooxidation, a Fuel Cells, a

12th Natl. Fuel Cell Seminar 2nd Grove Fuel Cell Symp., London, history

MeOH, a phosphoric acid, a

Sept. 1991

Fuel Oil, for syngas production, temperature Functionalisation, measurement, a of Rh catalysts, by K Gadolinium Oxide, reaction with Pd+H, a Gauzes, knitted, for NH, oxidation Geology, British Columbia

Pt deposits in USSR Glass, formation, Pd-Ni-P, a

Zr-Ba-La-Al-Na fluorides, Pt nucleation, a

164

33 PdlUNi,,P,,, internal friction, a 229

Pt-AI, thin films 83

232 I88 Glasses, Pdu.835Slo.165, structure changes, a

Glucose, oxidation, on Pt electrode, a Graphite, oxidation, on Pt( 100)

202 157. 163 108 I57 45, 240 17 21. 209 201 I63 45 I I3 140 154 58 16 96 I02

Heptane, n-, reactions, a 39, 107 Heptene, -1, hydrocarboxylation, a 238 Heteroannulation, vinylic cyclopropanes,

cyclobutanes, a 43

Heterocyclisation, C , H , , a 236

Hexane, isomers, a 160

Hexane, n-, reactions, a 39, 40, 41, 236 Hexene, 1-, reactions, a 40.41.42.70, I l l , 159 Hexene, n-, EtlSiH addition, a 110

History, Michael Faraday 222

“Palladium: or, New Silver” 141 Hydrazine, decomposition, a 155 Hydroboration, of alkenes, a 238 Hydrocarbons, adsorption with H2S, H I . on Pt. a 152

conversions, a I60

diesel engine emissions, catalysts for 178. I87 I12 synthesis from CO+H,, a 42 Hydrocarboxylation, reactions, a 161, 238 Hydrochlorination, olefins, a 231 Hydroconversion, n-heptane, n-nonane, a 107. 109

Hydrocracking, a 39. 159

Hydrocyanic Acid, synthesis, a 160 Hydroformylation, alkenes, a 43. 239

ethyl acrylate, a I62

ethylene, C 3 H 6 . on Rh catalyst, a I 09

oct-I-ene, u 239

olefins, a 110. 162

propylene, a 237

styrene, I-hexene, a 42. 239 154 34 catalytic recombination with 0, for

moisture generator, a I06

chemisorption, a 107, 157, 235 coadsorption with H,S, HC, on Pt, a I52 low MW, production from coal, a

Hydrochloric Acid, electrolysis, a 35

Hydrodechlorination, CCI,. a 43

polybutadiene, a 44

Hydrogen, absorption, by Pd-Al-La-Ni alloy. u

adsorption states on Pt electrodes, a

(6)

Hydrogen (contd.) Page codeposited with Pd plating, a 106

detection with CO sensor, a 38

diffusion, in Pd, Pd alloys, a 33, 103, 153, 230

electrooxidation, on h / C , a 232

embrittlement of steel, Pt implanted, a 228

evolution, by Rhnr complex polymers, a 36

from H,O-MeOH, a 233

on silicides, a 35

43

in Pd 24. 33

from H , O photoreduction, by Pt blues, a

~~

in uranous nitrate production, a insertion into Pd disc cathodes, a metal svstems

164

157 195

oxidation, on Pd/support, a 160 permeation, through Pd, Pd-Ag membrane

32, 138, 154

photoevolution 22, 104

photospillover, in ZnO/Pd system, a reaction with NO, on Rh, a Schottky device response to, a see also Synthesis

Gas

sensors

use in fuel cells, Grove Symp.

I05

155

240

85, 106, 158, 234, 235

209

Hydrogen Peroxide, photoproduction, a 233

Hydrogen Sulphide, effects with

Pt,

a 39, 152

acetylene, a 159

alkenes, a 161, 162, 239

asymmetric, dehydroaminoacid

derivatives, a 42

buta-l.3-diene. isoprene, a 159

cinnamyl alcohol, cinnamaldehyde, a 40

CO, in a continuous flow microreactor, a 160

on basic axides, a 237

on Ru clusterslinorganic oxides, a 42

CO, CO,, on Pd/La,O,, a 40

conjugated enones, styrene, benmnitrile, a 103

CO,, on Rh catalysts, a 41

cyclohexanone, a 36

C , H , , C,H,, C,Hb, a 236

C 2 H I - C 2 H I , a 40

diene, olefin, a 40

dimethyl oxalate, a I63

diolefin(dialkyl)Pt(II) complexes, a 236

ethene, a 107

ethylanthraquinone, 2-. for Pd catalyst studies, a 108

hexene- 1, a 41, 159

phenol, a 236

110

styrenes, a 159

transfer, ketones, aliphatic, aromatic, a 239

Hydrogenolysis, asymmetric, Na epoxysuccinate. a 162

biphasic, a I62

chloroarenes, a 162

ethane, for catalyst activity, a 236

methylcyclopentane, on Rh-AglTiO,, a 41

methylcyclopropane, a 41

n-butane. a 235

Hydrolysis, cis-PtCI,(NH,),, a 38

Hydrosilylation, alkynes, a 44, 162

asymmetric, acetophenone, a 44, 239

phenylacetylene, a 162

Pt colloid formation, a 110 Rh colloid catalysis, a 238

Imines, a 111. 161

Imino Acids, photocatalytic cyclisation, a 36

Impedance, Pt/SiO,, ultrathin films, a 32

Hydrogenation, acetophenone, a 44

unsaturated carboxylic acid, a 1 1 1

on Rh-Mn/SiO,, a 109

cyclohexene, a 106

ethyl pyruvate, a 39

propionaldehyde, a 112

quinolines, on Ru/C, Raney Ni, a

of cyclohex-2-en-l-one, a 45

Indans, production, a 43

Page Indium, grain boundary reaction with Pd-Ag-Cu, a 153

Integrated Circuits, a 112, 113

Interconnects, Al-Pd-Si metallisation, a 1 I3 33

Ion Plating, for h-GaAs Schottky contacts, a 234

IR, imaging, sensors, a 45, 164, 208

IR

cell, for high pressure spectroscopy, a 155

Iridium, crystal cleavage 23

diffusion on Ir(I 10) surfaces, a 155

plastic deformation 196

radioactive, reprocessing 202

thin films, a 38

Iridium Alloys, Ir-Al quasicrystals 21

Ir-Ni, for OER electrodes, a 106 Ir-Ta, amorphous, diffusion barriers, a 46

Iridium Complexes, polymetallic activation 10 [Ir6(CO),bl, isomer synthesis in NaY zeolite, a 237

1 I3

coatings for DSA electrodes 95, 105

in titration monitor I37

IrO,.nHIO clusters, redox states in H 2 0

photoreactions, a 105

64 Isocyanate, formation, a 41, 108

Isomerisation, direction of 28 39. 110, 111, 159, 235

Isomers, in

Pt,

Pd complexes 28

Isoprene, hydrogenation, a 159

Johnson, Percival Norton, palladium discovery 14 1 Johnson Matthey, Prince of Wales Award

for Innovation 20 1

“Platinum 1991’’ 132

Joining, PtSi fusion bonding, a 235

Ketones, a 1 1 1 . 161, 239

Lactose, oxidation, a 40

Langmuir-Blodgett Films, a 102, 233, 234

Lasers, a 107, 158

Lead Alloys, Pb-Cu-Sn-Se-Pd, microstructural Luminescence, in Pt(bpy)(NH,),

’

+-anthraceno-

Indolines, production, a 43

Ion Beam Mixing, Pd-Ni, low temperature, a

Iridium Oxide, AIROFs, a

Iridium Silicide, in IR imagers

reactions, a

stability, a 33

crown ether, a 104

in Ru(I1)polypyridine complexes, a 105 quenching, Ru(bpy)

,

’

+ , a 37. 158

Ru(bpy),CI,. a 233

Magnetism, Ce-Ru-SiGe. a 102

diamagnetic transition in Pt I D complex, a 153

effect on Ru multilayer films, a 23 1 FeRuGaSi thin films. a 155

Fe(Pd,Pt, --x),l a 101

in Fe-Pd alloys, a 33

in PdlCo multilayers, a 31, 101. 234

in

Pt

complex oxides formed in crucibles, a 156

in Pt/Co, a 31, 112, 152

in U-Pt/Pd/Rh-In alloys, a 32

in IPd(tmp)I,[ReO,l, a 156

of Pt resistance thermometer, a 113

Pt-Fe-Nb system, a 152

PtlFe multilayers, a 152

Pt,Mn-Pt,Fe, paramagnetic susceptibility, a 228

PtlMn,.,Fe,.,, a 229

Magneto-Optics, conference report 134

in Co/Pt, Co/Pd multilayers 31, 112

thin, ultrathin Pt/Co, a 152

Medical, a 46, 165

anti-tumour complexes, a 46

dental alloys, a 46

Membrane Reators 27, 164

33

F-polymer Nafion, PTFE/Nafon, supports, a 106 Manganese, catalyst promoter, a 109

(7)

Membranes (conrd.) Page Pd, H permeation through, CO, CO, effects, a 32 Pd-Ag, for H permeation 138, 153, 154 Pd/ZnO, H photospillover. a 105 see also Thin F i l m

Mercaptans, formation, a 152

Merensky Reef I32

Metallisation, systems, a 165, 240 Metallisations, Au-Sn/Pt, Al-Pd-Si, a 112, 113

Methane, formation, a 237

gas detector, a 158

reactions, a 108, 126, 160, 195

Methanol, fuel cells 163, 209

see Alcohols, methyl

Methyl Acrylate, dimerisation, a 162 Methyl Formats, decomposition into syngas, a 163 Methyl Trifluoroacetate, from CH, 126 Methylcyclohexane, selective dehydrogenation, a 107 Methylcyclopentane, reactions, a 41, 107, 160, 235 Methylcyclopropane, hydrogenolysis, a

Methylnaphthalene, 2, oxidation, a Methylstyrene, a-, hydrogenation, a

Methyl-2-Oxobutanoic Acid, 3-, photocatalytic asymmetric reduction, a

MicroscoDv,

_ _

scannine electron. with RuO. in

-

imaging, a

Mineralogy, in Canada

Mirrors, Rh/C multilayer X-ray, a Moisture, generator, a

Molybdenum, Pd catalyst promoter, a Morphology, back scattering electron detector, a

Ptlgraphite thin film, a Pt/SiO,, 25A, a Naphtha, reforming, a Naphthalenes, oxidation, a NEMCA, for MeOH oxidation, a Neohexene, Et ,SiH addition, a Nicholson, William, palladium discovery Nickel, high temperature reactions with Sic, a Nitric Acid! process gas filtration, a

production, on knitted gauze Nitroanilines, reduction, a Nitroanisole, p-, reduction, a Nitroanthraauinone. 1-. reactions. a

41 233 236 37 39 16 39 106 43 39 152 32 39 233 108 110 141 153 236 58 162 239 162 Nitrohemen;, reactions ' 43, 70, 162, 238

Nitrogen, reactions, a 104, 155 Nitrogen Oxides, NO, dissociation, reaction

155 NO-CO, Ce, K effects on Rh/AI,O,, a 41 188

Nitrotoluene, reduction, a 239

Noril'sk-Talnakh, Pt deposits 96 160 with H on Rh, a

self poisoning on Pt{

IOO}

Nonane, n-, hydroconversion, a 109 Nuclear Fuel, FGM reprocessing 202 Nucleosides, C-5 alkyl, production, a

Octane, n-, hydrocracking, isomerisation, a 159 Oct-lene, hydroformylation, a 239

Olefins, couplings, a 161, 238

40, 110, 111, 159, 162, 237 Optical Switch, in Langmuir-Blodgett film, a 234 Organofluorophosphines, complexes, preparation,

properties 86

Osmium, polycrystalline, thermionic emission, a 230 Osmium Complexes, 0 s organofluorophosphines 86 OsH,(PMe,Ph), , concurrent photodissociation, a 37

OsO,, oxidant 31

0s-ammines, a 23 1

Os,h(CO) I i(PPh,)z 9 a 156

Pt ,Os, (CO)

,,

(COD), Pt I Os, (CO), ,(COD), , a 156 [OsCI(NO)(PiPr,), 1, synthesis, a 232 reactions, a

Osmium Alloys, Al-0s quasicrystals 21

0 s polyhydrides, paramagnetic, a 37

polymetallic activation 10

Oxidants, (Ph,)IRuO,(OAc)CI,l, a 45

Page Oxidation, 2-methylnaphthalene, naphthalene, a 233 alcohols, primary, aerobic, a I63 ammonia, on knitted gauze 58 CO, on Pt{lOO] crystals, reaction monitoring 188

CO, a 107, 109

electro-, CO, on Pt electrode, a 232 I l l

ethylene glycol, a I03

glucose, a 232

H. a 232

alkanes, bridged polycyclic, a 45

diols by Ru complex, a

HCHO, a I57

HCOOH, MeOH, a 157

MeOH, on Pt, a 35, 36, 108, 232 Pd, electrodissolution, a I57 phenol, water pollution control, a 232 Fe,,Cr,Ru steel, corrosion resistance, a 34 graphite, on Pt( 100) 188

H, a 160

internal, in Pd-4OAg-IRE alloys, a 33

lactose, on Bi-PdC, a 40

methane, by Pd 108, 126

photo, H 2 0 , ascorbic acid, a 105, 233 43. 160 resistance, in Pd coated Mo-W-Cr-Pd alloys 133

74

propylene, propylene glycol, a

PtlNi crystals, a 101

_ . 163

35

Rh, high temperature, a triphenylphosphine, a urea. a

[Ru('PPh,), CI ,I, a trans-[PtHCI(PEt,),l, a

Oxygen, catalytic evolution, from MeOH, a catalytic recombination with H, for

moisture generator, a chemisorption, on Pt-Sn/Al

,

0

,

, a evolution, by IrO,-Ta,O,lTa electrodes, a

electrodes for, a from HCIO,, a from H,SO,, a

interaction with CO, on Ir/AI,O,, a interaction with Pt/CeO, sensors, a reduction electrocatalysts, a

reduction in H,SO, +phenanthroline, on

sensor, a Pt rotating disc, a Oxygenation, aliphatic ethers, a Oxyhexatriene, cyclisation, a

Palladium, addition, to stainless steel, a

to Au-Cu dental alloys, a or-Pd, H permeation in, a amomhous intemhase with InP. a cluster, Pd,,,Phkn,,(OAc),,,,

a

clusters, on mica, scanning force microscopy compounds, cyclopalladated, reaction with study, a 229

~.

45 35 36 I06 107 157 106 104 95 42 158 103 232 38, 158 45 238 I63 46 I03 153 230

. .

alkynes, a I l l

Fe(Pd,Pt,

-2,.

magnetism, a 101 EuPd,Si,, valence change under pressure, a 229 PdGe, enthalpy of formation, a 154 IPd(tmp)l

,

IReO,

I ,

a 156 electrodes, see Electrodes

electrodissolution, a 157

electroless deposition, a 105 glasses, Pd,,Ni,,P,,, internal friction, a 229

history, discovery, a 141

in contacts, a 113, 165

in detectors, sensors, see Detectors

in membrane reactor, a 164 in Schottky contacts, a 240 ion beam mixing in Ni, a 33

membrane reactors 27

membranes, a 32, 105

modified aluminide coatings 82 nanocrystalline, mechanical behaviour, a I54

(8)

Palladium (conrd. ) Page NilPdNiIAu. composite for contacts, a 234 228 Pd(l1l). sulphided. for C,H, cyclisation. a 236 Pd-AI thin film. phase formatrion. a 153 Pd-H systems, Intl. Symp. 24. 195 Pd/AI diffusion couple, a 32

PdlCo 31. 101. 134, 234

PdlSnO,. for gas sensor. a 106. 158 Pd.C, _”. thin films. electrical orowrties. a 101 P d ( l l I ) . crystal surface in H,SO,. a

p l a h g . k i t h H codeposition, a’ radioactive, reprocessing rod, electrochemical charging. a

thin films, a 38.

ultrafine particles. for H absorption.

‘

adsorption, a characteristics. a

Palladium Alloys, assessed for contact Pd solid solution. electrical resistivity. a Pd-Ag, H permeation 138. 153. Pd-Ag-Cu. grain boundary reactions. a Pd-40Ag-lRE. internal oxidation. a Pd-Ag-Y(Gd), diffusion characteristics. a Pd-Al-La-Ni, H absorption, a

Pd-Au. lattice expansion, a Pd-Au-Cu, dental, tarnishing tests. a Pd-Cr, in strain gauges

Pd-C-Mg, a

Pd-Er, preparation. metallography. a Pd-Fe, sputter deposited, a Pd-H systems, Intl. Symp.

Pd-Ha. preparation. metallography. a Pd-Ma-W-Cr, oxidation resistance Pd-Ni, H insertion into thin films, a

I06 202 233 54. 229 157 165 33 54, 230 153 33 33 154 I54 46 65 229 I54 33 24 I54 I33

I57

. _ I

plating bath 208

Pd-Ni-P, crystal nucleation, glass formation. a 102 Pd-Pb-Cu-Sn-Se. microstructural stability. a 33 Pd-Pt-U, magnetic transport properties, a 32 Pd-rare earth oxides, coupled reduction. a 154

Pd-Si, a 154. 229. 230

Pd-Si-H, H diffusion, electromigration. a 230 Pd-Te, system constitution, a 33

Pd-Zr, amorphisation 83

Palladium Complexes, H

,

PdCl 6 , effect on Ag

imaging colloids, a 36

isomers 28

ortho-palladated imines, mesogens. a 23 I Pd organofluorophosphines 86 PdLCI,, PdC-H),, Pd(L-2H). a 23 1

Pd(I1)-Sn, a 103

[Pd(3,3’-bipyridazine),llC10,

I , .

a I02 lPd,X,(PPrn,),l+ 1,4-benzodiazepines. a 231 [Pd, As (PPh,,

1,

[Pd,Sb,(PPh, )

I,

a 156 Palladium Silicides, alloy glasses, structure changes, a33

for H evolution, a 35

mechanical alloying, a Pd,Si, in ULSI, a

see also Palladium Alloys, Pd-Si Patents 47-56. 114-124, 166-176, Pentane, dehydrogenation, a

Pentene, 1-, hydrofonnylation, a Permeability, see also Diffusion

Permeation, H, through Pd 32. Phase Changes, at Pd/InP interface, a

Phase Diagrams, CeRu,(Ge-Si) a at PtlGaAs, Si/Pt/GaAs interfaces. a in AI-Pd thin films, a

Fe(Pd,Pt

,

-J

,

, a Pd-Te, a

RuO, -Bi,O ,-CuO, a Phenol, a

Phenylacetylene, hydrosilylation, a Phenylcarbamate,

N-,

formation, a Phenylpropanal, 2-, from styrene, a Phosphine, displacing Co on Rh catalyst, a

154 240

24 1-249 158 I10 138, 154 153 153 153 I02 101 33 I55 232. 236 I62 43 42 I09

Page Phosphonic a-Amino Acids, synthesis. a 161 Photocatalysis, a 36-37. 43. 104-105. 158. 233-234 Photodissociation, OsH

,

(PMe ! Ph)

,

.

a 37 Photolysis, Ru(II) diirnine. u I05 Plating, electroless, Pt. Pd. Ni. a I05 Pd. with H codeposition. a I06 Platinum, addition to YBaCuO superconductor. a 229 compounds. Fe(Pd,Pt, magnetism. a 101 228 Pt I Mn-Pt

,

Fe. oaramaenetic. a

Pt,Mn,. ,Fe,,.

,‘.

magnetism in. a 229

CVD. a I52

deposits. in USSR 96

doped heavy metal fluoride glass. a I64 electrodes. see Electrodes

n-Si crystals. a 228

electroless deposition. (7 I05

equilibrium shape. surface energy. ( I

hydrous oxide films. u I02 101

etching foils. ( I 38

high temperature reactions with Sic. o 153 implanted in steel. reduced rmhrittlenient. a 228 in electrical contacts. a 46 in high temperature superconductivity 7

ion beam deposition. a I I 2 mullilaycrcd thin films. preparation. structure. ( I 228

Pt( 100). Pt( I I I ) . for adsorption. a 152 P t ( l l l ) . reactions. a 228. 235 Pt-GaAs. in Schottky contacts. ( I 234

Pt-H bond cleavage. a 35

Pt/CdS dispersions. photocorrosion. a I04 in Schottky N H , sensor 200

Pt/CdS.Ag,S/RuO,. for NH production. a 104 PtICo. in magnetooptic

devices 31. 112. 134. 152, 228 PtiFe thin film multilayers. anisotropy. LI I52

PtIGaAs. SiIPtIGaAs. intermixed phase. t i 153

Pt/mica disks. fabrication. II 234

PtINi. oxidation prevention. ( I 101

Ptlpyrolytic graphite. thin film morphology. a 152 PtITa. Pt/Ti. barriers. II I I 2

Pt/TiO,. gas sensor. a 158 Pt{ 100). chemical reaction fronts I88 radioactive. reprocessing ’02 thick films. laser power detection. II 158

thin films. a 38. 101

ultrafine particles. for electrooxidations. I I 157

ultrathin films, / S i 0 2 . properties. a 32 underlayers. in YBaCuO superconductors. II ?40

“Platinum 1991”

Platinum Alloys, in PAFC fuel cells. ( I

Pt-AI. amorphisation quasicrystals

Pt-ColC, for 0 electroreduction. II

PI-Fe-Nb. magnetic. thermal properties. I I

Pt-Pd. solid solution. for ethylene glycol Pt-Rh. gauze. for NH3 oxidation Pt-Rh. Pt-Rh-Au. volatilisation. (I

Pt-U-In. magnetic, transport properties. ( I

Pt-Y-B. properties. a

C O D P I ( C D , ) ~ . Pt surface alkyls. a isomers

o-vinyl Pt(IV), a polymetallic activation

Pt blues, for H i photoevolution. a Pt organofluorophosphines

PtCl ,,[bis(aminomethyl)dimethylsilanel.

Pt(bpy)(CN)

,

IPt electrodes. spectroscopic Pt(bpy)(NH,),,,+: luminescence. a Pt(I1)-diaminobioun. synthesis.

oxidation. a

Platinum Complexes, anti-cancer, (I

OS3,Pt(CO), I (PPh ?)!.

anticancer, a properties. a

characteristisation, u

132 45 83 ? I I03 1.52 I03 58 32 32 32 46 236 2R I56 161 10 43 86 46 233 104

(9)

Platinum Complexes (conrd.) Page

Pt-Sn bimetallic, a 34

Pt,0s6(CO)Iz(COD). Pt50s,(CO),, (COD), , a 156

R,Ba,CuPtO, , R,Ba ,Cu,PtO,, , Ba,CuPt,O,, a I56

IPtI,(L’)IIBF,l. a 23 I

[Pt(en), lIPt(en) I I , I(CI0, ),

.

magnetism in, a 153

lPt(L’)l[BF,I, a 23 1

IPt(3,3‘-bipyridazin),1~Cl0,1,, a I02

IPt 2 (p-C=CHPh)(C rCPh)(PEt j ) , IBF, ,

photochemical atom-transfer, a 104 cis-PtCI,(NH3),, hydrolysis products, a 38

cis-[PtCl

,

(PPh

,

1,

a 23 1 trans-IPtHCI(PEt I

I ,

electrochemical

oxidation, a 35

trans-lPt(H)X(PPh,),l. a 23 1

35

from SiClPt high temperature reactions, a 153

fusion bonding, a 235

in IR imagers 45, 64, 208

PtSi, columnar grains. u 32

contact to Ge-Si/Si, a 112

in Schottky diodes, a 164, 228

in ULSI, a 240

hSi/Si(

IOO), formation, a

240 108

catalysts by S , a 39, 108, 235

CO, on Pd/SiO,, a 41

self, CO, NO on Pt{IOO} 188 94

diesel exhaust 178, 187

electrolyte effluent treatment, a 35

phenol in waste water, a 232

radioactive PGM waste 202

Polyaldehydes, from polybutadiene, a 44

Polymerisation, a 43, 110

Polymers, co-, Ru complex+DDA, in L-B films, a 233

layered conducting/Pt, a 35

+ RuO,, in electron detector, a

39

Potassium 41, 140

Prince of Wales Award for Innovation 20 1

Promoters, 10.11 -dihydrocinchonidine, a 39

Bi, on PdlC, a 40

Ca, K, La, on PdlSiO, catalysts, a 41

109

Mn, V, a 109, 160

43

Propadiene, effect on ethene hydrogenation, a 107

Propan-2-01, for ketone hydrogenation, a 239

Propionaldehyde, hydrogenation, by RuHI(tppts), a 1 12

Propylene, reactions, a 43, 160, 236, 237

43 Pyrimidine Nucleosides, reaction with triflates 160

Quasicrystals, in AI-Rh, -Pd, -Ir, -Os,

-Pt,

-Ru 21

Platinum Silicides, for H evolution, a

Poisoning, by metal ions, of Pd catalysts, a

Pollution Control, 1991 SAE conference reports

Cr, to Pd/HY catalysts, a

Mo, V, in PdCI, +Keggin-type anions, a

Propene, hydroformylation, a 109

Propylene Glycol, oxidation, a 160 Propylene Glycol Monoacetate, formation, a

Quinolines, a 110

Radioactivity, reprocessing PGM waste Rapid Thermal Processing, for electrical con Rare

Earths,

new compounds with Ru, a Reed Switches, a

Reforming, reactions, a

Resistance Thermometers, Pt, stability, a Resistors, Pt, in thermal conductivity meter,

in mine pit, a

RuO, thick film, thin film, a thick film, a

Reviews, electrocatalysts for PAFC, a metal complex anti-cancer drugs, a Pd catalysts in industry, a see also Conferences

Rhodium, coatings in reed switches, a compounds, RhGe, enthalpy of formation,

Rh,O,. a

202

tacts, a 46 34 165 39, 236

1 I3

234

113, 235

155, 240 45 46 44

165

a 154 34

Rhodium (conrd.) Page

foil, hydrazine decomposition, a I55

oxidation, high temperature, a 34

Rh/C multilayers. for soft X-ray use. a

Rh(1 I I ) , reactions. a 155. 228 39

thin films. a 38

on Ag{001}, Au{OOI), a 230

Rh-Cu, single crystal solidification, a I55

Rh-Pt, Rh-Pt-Au, volatilisation, a 32

Rh-U-In. magnetic, transport properties, a 32

Rhodium Complexes, Cp*Rh, electrochemical

reduction, a 36

Rhodium Alloys, Rh-AI quasicrystals 21

Rh(2.4.6-Me , C b H 2 ) J , a 34

Rh[P(OPh),

1

j [P(OCbH,)(OPh)z

I,

(I I56

ICp*RhCIl

,

, electrochemical production, a [Rhll’(L),C1,l+BF, -, films, electrochemical Royal Commission on Environmental Pollution, Ruthenium, colloids. of Ru double salt, a

36

properties, a 36

report on diesel exhaust I87 34

compounds, anti-cancer properties, a 46

RuGe. enthalpy of formation, a 154

Ruse, crystal growth, a I55

RuTiSnO, 0 evolution, a 104

LiRuO,, a 36

34 240

230

effect on Fe40Cr steel, a in thick film resistors, a

Ru(0001), thin Cu films on, a

Ru-rare earth systems, a 34

Ru-AI quasicrystals 21

Ruthenium Alloys, FeRuGaSi thin films,

magnetism, structure, a 155

Ru-Al-Mn-Si, icosahedral, a 23 I Ru-Ni, for OER electrodes, a I06

Ru-Ti, electrochemistry, a I03

Ruthenium Complexes, oxidants 31, 45

Ru organofluorophosphines 86

Ru(bpy),’+, for HI evolution, using pt blues, a 43

luminescence quenching, a 37, 158 Ru(bpy),’+ on Vycor glass, photo properties, a 37

Ru(I1) bipyridine, optical switching, in L-B film, a 23

Ru(II)polypyridines, photo properties, a I05

[ R u ( ~ - C , H , ) ( C S , ) ( P P h 3 ) ~ l + . a 156 45

IRuL,(p-(CN)Ru(CN)L,’),l,

light to

electricity conversion, a 37

[Ru(bipy),(L-L’)l(PF,), , photolysis, a I05 IRu(bp~) I (CN)

11

I Ru(bpY)(COO)z) I*

-.

antenna sensitised, a 37

IRu(bpy),(Vbpy)I’+, copolymers, in L-B

films, a 233

IRu(bpy): + .Hg,CI:

-1,

preparation,

characterisation, u 158

(Ph, )[RuO, (0Ac)CI

,I.

a

IRu(saloph)CI,l-, carbonylations 70

[RuhSH,)(PPh J)(’S,’)l.THF, structure, a 232

[Ru /EDTA-H (CO

I

carbonylatlons 70

I(TPP)Ru(CO)l.-, reaction with MeI, a I58 [ ( ~ s - C , H , ) L , ~ u N d - ~ ~ l l + , a I02

Ruthenium Oxides, Bi,Ru,O,, reaction

with CuO in resistors, a I55 I05

in resistors, a 113, 155, 240

reduction to LiRuO,, a 36

I I3 I06

RuO

,

, coatings for DSA, a

RuO

,

/Al, interface properties, a RuO,/C, electrode in alcohol detector, a RuO,,

+ polymer blends, for back

(C5-Me,)Rh(PMe3)H,, a 156 scattering electron detector, a 39

Platinum

Metals

Rev.,

1991,

35, (4)

263

I R ~ ( ~ P Y ) , ( ~ P ~ ) , - , I ~ + , “ 2 0 , photoproduction, a IRu(MeL)(CO)(PPh j)z(Cl)l, a

[Ru(PPh j )

,

(m-CIC H , C0,)CI

,

I ,

formation IRu(saloph)CI,l-, carbonylations [RuhSH,)(PPh j)(’S,’)l.THF, structure, u

[Ru /EDTA-H (CO

I

carbonylatlons ~ ( 7 s - C , H I )Lz RuNd-aT;11+ , a

I(TPP)Ru(CO)l.-, reaction with MeI, a

RuO

,

, coatings for DSA, u

in resistors, a 113,

reduction to LiRuO,, u RuO I IAl, interface properties, a RuO,/C, electrode in alcohol detector, u

RuO,,

+

polymer blends, for back scattering electron detector, a Ruthenium Oxides, Bi,Ru,O,, reaction

with CuO in resistors, a

233 34 I, u 45

70

232 70 102 158

155 105 155, 240 36 I I3 106