A titanium industry for
New Zealand?
Paul Ewart Ph.D (Candidate)
Professor Deliang Zhang Chief Supervisor
Monday, 7 September 2020
•
Overview
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 2 Introduction
Titanium and its uses
Titanium in New Zealand Powder metallurgy
Metal injection moulding The science of MIM
•
Introduction
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 3 The minerals rutile, anatase and brookite
serve as a source for commercial Ti
The metal can also be mined from minerals such as ilmenite or leucoxene ores, or rutile beach sand
•
Titanium and its uses
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 4 Ti and its alloys are used for bicycle parts to
orthopaedic devices and spacecraft
They have superior corrosion resistance, strength and temperature performance Negative aspects include high cost, poor
•
Titanium in New Zealand
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 5 The use of Ti in NZ is limited to imported
goods and some bar stock with use restricted because of high processing cost
NZ has its own resource, Titanomagnetite, the black iron sand of the West Coast
•
Powder metallurgy
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 6 Powder metallurgy utilises the high surface
energies of fine powders to process high
temperature metals at reduced temperatures Processing metal powders using press forming
and sintering is limited to simple geometries Metal Powder Injection Moulding (MIM) is a
•
Injection moulding
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 7 Injection moulding in New Zealand is a
mature industry with many world leading companies
Equipment is produced in Europe, North America, China
•
Injection moulding process
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 8 Heat feedstock
•
Metal injection moulding
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 9 Batching/ mixing
Compounding Granulation
Injection moulding Debinding
•
Batching/ mixing
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 10 Measuring correct ratio of metal powder to
binder Mixing:
•
Compounding
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 11 The batched and mixed powder feedstock is
intensively mixed at elevated temperature to produce solid granular feedstock
•
Injection moulding
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 12 The feedstock is processed in the injection
moulder at temperatures to enable uniform flow that fills the mould
•
Debinding
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 13 Thermal
Solvent Catalytic
•
Sintering
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 14 Held at ~1100C in inert atmosphere or a vacuum
•
Finishing
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 15 HIP
Minimal machining Internal threads
•
Automated MIM
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 16 With the advent of rapid binding technologies it
should be possible to automate the MIM process with the use of robotic takeoff and computer
•
Quality of part
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 17 The optimum mechanical properties are possible
but rely on essential operations to ensure best: Green Part
Monday, 7 September 2020
© THE UNIVERSITY OF WAIKATO • TE WHARE WANANGA O WAIKATO 18
[1] Fabricating sports equipment components via powder metallurgy. V S Moxson; F H Froes. JOM; Apr 2001; 53, 4 [2] The Metal Injection Molding Association, Princeton, New Jersey 08540 USA . www.mimaweb.org
[3] Catamoldâ Feedstock for Powder Injection Molding: Processing - Properties – Applications. Technical Information, BASF
Aktiengesellschaft 2002.
Monday, 7 September 2020