S A F E T Y D A T A S H E E T
H Y D R O G E N PE R O X ID E 1 2 %
1 . I D E N T I FI C A T I O N O F T H E S U B ST A N C E /P R E P A R A T I O N A N D T H E C O M P A N Y :
P R O D U C T N A M E : HYDROGEN PEROXIDE 12% P A R T N o .: M055 S U P P L IE R : J M Loveridge plcSouthbrook Road, Southampton Hampshire SO15 1BH Tel: 023 8022 2008 Fax: 023 8022 2117
2 . C O M P O S IT IO N /I N F O R M A T I O N O N IN G R E D I E N T S :
NAME EINECS Nr.: CAS No.: CONTENT CLASSIFICATION PHENACETIN 200-533-0 T R-20/21/22, 45, 46 Carc1 Mut1 62-44-2 0-1 % HYDROGEN PEROXIDE 231-765-0 C ,O R-8, 34 7722-84-1 10-30 %The Full Text for all R-Phrases are Displayed in Section 16
C O M P O SI T IO N C O M M E N TS : Preparation containing: Phenacetin at ~ 0.01%.
3 . H A Z A R D S ID E N T IF I C A T I O N :
Irritating to eyes and skin.
4 . F I R S T A ID M E A S U R E S :
G E N E R A L : IN ALL CASES OF DOUBT OR WHEN SYMPTOMS PERSIST, ALWAYS SEEK
MEDICAL ATTENTION
IN H A LA T IO N : Move the exposed person to fresh air at once. Keep the affected person warm and at
rest. Get prompt medical attention.
IN G E ST I O N : DO NOT INDUCE VOMITING. In case of spontaneous vomiting, be sure that vomit
can freely drain because of danger of suffocation. Only when conscious, rinse mouth with plenty of water and give plenty of water to drink - (approx 500ml). Keep patient at rest and obtain medical attention.
soap and water. Get medical attention promptly if symptoms occur after washing.
E Y E S : Keeping eye open, immediately irrigate with water or eye-wash for 15 minutes. Obtain
medical attention.
5 . F I R E FI G H T I N G M E A S U R E S :
E X T IN G U IS H IN G M E D I A : Use extinguishing media appropriate for surrounding fire.
U N U S U A L F IR E & E X P L O S IO N H A ZA R D S:
Thermal decomposition may liberate oxygen which will contribute to the combustion of other materials.
P R O TE C T IV E M E A SU R E S I N F I R E : Fire fighters should wear self-contained breathing apparatus.
6 . A C C I D E N T A L R E L E A S E M E A S U R E S:
P E R S O N A L P R E C A U TI O N I N S P IL L : Avoid direct contact with skin, eyes and clothing.
P R EC A U T IO N S T O P R O TE C T E N V IR O N M E N T:
Prevent contamination of soil, drains and surface water.
S P IL L C L E A N U P M E T H O D S: Take-up spillage with absorbent, inert material and place in a suitable and closable labelled container for recovery or disposal. Wash the area clean with water and detergent, observing environmental requirements.
7 . H A N D L I N G A N D S T O R A G E :
U S A G E P R E C A U T IO N S : HANDLING - Product should be used in accordance with good industrial principles for handling and storing of hazardous chemicals.
Avoid contact with skin or eyes.
S TO R A G E P R E C A U T IO N S : Store in a cool, dry, well ventilated place, in securely closed original container. Keep container tightly closed and in cool place.
8 . E X PO S U R E C O N T R O L S A N D P E R S O N A L PR O T E C T I O N :
INGREDIENT NAME: CAS No.: STD LT EXP 8 Hrs ST EXP 15 Min
OES 1 ppm
HYDROGEN PEROXIDE 7722-84-1 2 ppm
P R O TE C T IV E G L O V ES : Use protective gloves.
E Y E P R O T EC T IO N : Use approved safety goggles or face shield.
O T H E R P R O T E C T IO N : Wear appropriate clothing to prevent any possibility of skin contact.
H Y G IE N IC W O R K P R A C T IC E S: SKIN PROTECTION - apply barrier cream to hands and exposed skin. Promptly remove any clothing that becomes contaminated.
9 . P H Y S I C A L A N D C H E M I C A L PR O P E R T I E S :
A P P EA R A N C E : Colourless liquid.
O D O U R /T A S T E: Slightly pungent odour.
~ 1 .02 - 1 .04 T em pera tu re (°C ):
S O L U B IL I TY D E S C R IP T I O N : Miscible with water in all proportions.
1 0 . S T A B I L I T Y A N D R E A C T I V I T Y :
S TA B IL I TY : Slowly decomposes, evolving oxygen. High pressure can develop in sealed containers.
C O N D IT IO N S T O A V O I D : Avoid excessive heat.
M A TE R IA LS T O A V O ID : Strong bases and alkalis - vigorous exothermic reaction. Oxidising agents. Combustible materials. Readily decomposed by dust, metals, carbon, salts.
Reacts vigorously with permanganates.
H A ZA R D O U S D E C O M P . P R O D U C TS : Oxygen.
1 1 . T O X I C O L O G I C A L I N F O R M A T I O N :
T o x ico lo g ica l d a ta LD50. Oral. Rat. 1518 mg/kg (12% solution)
H E A L T H H A ZA R D S, G E N ER A L : Extremely irrritating to eyes and respiratory system.
IN H A LA T IO N : Irritating to mucous membranes. Irritating to the respiratory system.
IN G E ST I O N : If ingested, sudden evolution of oxygen may cause injury by distention of stomach and
may cause nausea, vomiting and internal bleeding.
S K IN : May cause skin irritation.
E Y E S : May cause eye irritation, burning sensation or lacrymation.
1 2 . E C O L O G IC A L IN FO R M A T IO N :
E C O L O G IC A L IN F O R M A T IO N : No specific data or information available regarding environmental impact.
1 3 . D IS P O S A L C O N S I D E R A T I O N S :
D I S P O SA L M E T H O D S: This material and/or its container must be disposed of as hazardous waste according to Special Waste Regulations 1996 or according to local regulations, in compliance with Duty of Care Regulations and Special Waste Regulations.
W A S T E C L A S S: WASTE CODE: 0705** HAZARDOUS PROPERTY: H4
1 4 . T R A N SP O R T I N F O R M A T I O N :
U K R O A D P A C K G R .: III
A D R C L A S S N o .: 5.1
A D R I T EM N o .: 1°(c)
H A ZA R D N o . (A D R ): 50 Oxidizing (fire-intensifying) substance.
A D R M A R G I N A L : 2501
A D R L A BE L N o.: 5.1
H A ZC H E M C O D E : 2P
P R O P E R SH IP P I N G N A M E I: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
U N N o . S EA : UN 2984 IM D G C L A SS : 5.1 IM D G P A G E N o .: 5150 IM D G P A C K G R .: III U N N o ., A I R : UN-ID 2984 IC A O C L A S S: 5.1 A I R P A C K G R .: III
1 5 . R E G U L A T O R Y IN F O R M A T I O N :
LABEL FOR SUPPLY:
R I S K P H R A SE S : R-36/38 Irritating to eyes and skin.
S A F E T Y P H R A S E S: S-2 Keep out of reach of children. S-24/25 Avoid contact with skin and eyes.
S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S-46 If swallowed seek medical advice immediately and show this container label. S-56 Dispose of this material and its container to hazardous or special waste collection point.
U K R E G U L A T O R Y R E F E R E N C E S: Chemicals (Hazard Information & Packaging) Regulations 1993. Classification, Packaging and Labelling Regulations 1984.
1 6 . O T H E R I N F O R M A T I O N :
IN F O R M A T IO N SO U R C E S: This product has been classified in accordance with CHIP3 regulations.
R E V IS IO N C O M M E N TS : Edition 01; Revised item(s):
IS S U E D B Y : MK
S D S N o .: M065
D I S C L A I M E R : The foregoing data has been compiled for safety information only and does not form part of any selling specification. Information contained in this Data Sheet is to the best of JMLs knowledge correct at the time of publication. Customers should always satisfy themselves, that the product which they have selected is entirely suitable for their purpose under their conditions of use and in compliance with current regulations. For any further information, please contact the supplier.
R -P H R A S E S (F u ll T ex t): R-8 Contact with combustible material may cause fire. R-34 Causes burns. R-20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R-45 May cause cancer. R-46 May cause heritable genetic damage.
