Quantum
Physics
Quantization of charge
• JJ Thomson
measured specific charge = q/m
• R Millikan
J.J. Thomson: Finding e/m
1. FB = FC
2. Bqv = mv2/r
v2 = B2r2q2/m2
3. qVA = ½mv2
v2 = 2qV
A/m
B = Magnetic Field (T)
r = radius of path of particles with B-field only (m) VA = accelerating potential
for particles (V)
v = velocity of particles (ms-1)
Combining these equation to eliminate v:
Specific Charge, q/m
Alpha particle
= 2.41 x 107 Ckg-1
Electron
= 1.76 x 1011 Ckg-1
Proton
= 9.58 x 107 Ckg-1
These distinct
‘particles’ were known to be different because of their ‘specific
charge’.
Millikan’s experiment enabled the charge
Millikan’s Oil-Drop
Experiment
http://omniknow.com/scripts/wiki.php?term=Oil-drop_experiment
FG is balanced by FE
m
g
=
e
V/d
q
= m
g
d/V
Millikan’s Oil-Drop Experiment
Weight FG = mg
Millikan’s Oil-Drop Experiment
Robert Millikan’s
Conclusions
• Charge exists in
quanta
(small discrete units)
• The smallest
quanta
= 1.6 x 10
-19C
Measuring
e
Blue Box
(
Page 62,
• Max Planck
Planck’s constant, h
• Maxwell
speed of light , c
• Einstein
E = mc2
• De Broglie (matter waves)
= h/mv = h/p
The Photo-electric Effect
• Known to Hertz
• Explained by Einstein …
• …who was disbelieved by Millikan
• Further evidence then found by Millikan • Light comes in small discrete packets of
energy.
The Photo-electric Effect
photoelectric effect.swf
Photocurrent v Intensity
The Classical (Wave) Theory
Could not explain why:
• KE of electrons is independent of light intensity
• KEmax depends on light frequency
• The threshold frequency is different for different materials
Einstein’s Explanation
• The photon • E = h
as suggested by Max Planck
(h = Planck’s constant = 6.6 x 10-34Js)
= c = 3.0 x 108 ms-1
as suggested by Maxwell
h
=
+ (½ mv
2
)
Einstein’s Explanation
h
=
+
(½ mv
2)
Potential well
Einstein’s Explanation
h
=
+ (½ mv
2
)
max
•
h
= Incoming energy of photon
= ‘
work function
’ of material
• (½ mv
2)
max
= maximum KE of
emitted electron
Worked Example (Duncan,
p392
)
Threshold wavelength for a material =
0.65m (650nm). Calculate the:
(i) Threshold frequency, =
(ii) Work function, =
(iii) Maximum speed of electrons emitted by
violet light ( = 400nm) =
0 = c/0 = 3.0 x 108 / 650 x 10-9 = 4.6 x 1014Hz
The
electron-volt
1eV
=
the work done (in joules) on an
electron when accelerated across a
potential difference of 1 Volt
= 1.6 x 10
-19J
e.g. 3.0eV = 4.8 x 10
-19J
Questions
SAQs 16.3 – 16.9
(Physics 1, pages 137-8) SAQs 16.10 – 16.12
(Physics 1, page 141)
Duncan, Advanced Physics:
Evidence – Atomic Line Spectra
Emission Spectra
Argon Iodine
Mercury
Atomic Line Spectra
Line spectra.swf
Atomic
Line
Spectra
Hydrogen Emission Spectrum
Lyman series
Ground state (n = 1)
Balmer n = 2
Electron Diffraction
The De Broglie Equation
=
h/mv
= h/p
Matter waves
What is your personal
De Broglie Equation
• SAQs 16.13 (Page 142, Physics 1)
• Questions (Page 143, Physics 1)
• Questions 23 – 29 (Pages 410 – 411,