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(1)

Chemical Reactions and Quantities

(2)

Molar Mass

The molar mass

is the mass of one mole

of an element or compound.

is the atomic mass

(3)

Molar Mass from Periodic Table

Molar mass is

the atomic mass

(4)

Give the molar mass for each (to the tenths decimal place).

A. 1 mole K atoms = ________

B. 1 mol Sn atoms = ________

(5)

Give the molar mass for each (to the tenths decimal place).

A. 1 mole K atoms = 39.1 g

B. 1 mole Sn atoms =118.7 g

(6)

Molar Mass of a Compound

The molar mass of a compound is the sum of the molar masses of the elements in the formula.

Example: Calculate the molar mass of CaCl2.

Element Number of Moles

Atomic Mass Total Mass

Ca 1 40.1 g/mole 40.1 g

Cl 2 35.5 g/mole 71.0 g

(7)

Molar Mass of K

3

PO

4

Calculate the molar mass of K3PO4.

Element Number of Moles

Atomic Mass Total Mass

in K3PO4

K 3 39.1 g/mole 117.3 g

P 1 31.0 g/mole 31.0 g

O 4 16.0 g/mole 64.0 g

(8)

Some One-mole Quantities

(9)

What is the molar mass of each of the following?

A. K2O

B. Al(OH)3

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A. K2O 94.2 g/mole

2 mole K (39.1 g/mole) + 1 mole O (16.0 g/mole) 78.2 g + 16.0 g = 94.2 g

B. Al(OH)3 78.0 g/mole

1 mole Al (27.0 g/mole) + 3 mol O (16.0 g/mole) + 3 mol H (1.01 g/mole)

27.0 g + 48.0 g + 3.03 g = 78.0 g

(11)

Prozac, C17H18F3NO, is an antidepressant that inhibits the uptake of serotonin by the brain. What is the molar mass of Prozac?

1) 40.1 g/mole 2) 262 g/mole 3) 309 g/mole

(12)

Prozac, C17H18F3NO, is an antidepressant that inhibits the uptake of serotonin by the brain. What is the molar mass of Prozac?

3) 309 g/mole

17 C (12.0) + 18 H (1.01) + 3 F (19.0) + 1 N (14.0) + 1 O (16.0) =

204 + 18.2 + 57.0 + 14.0 + 16.0 = 309 g/mole

(13)

Molar mass conversion factors

are written from molar mass.

relate grams and moles of an element or compound.

Example: Write molar mass factors for methane, CH4,

used in gas stoves and gas heaters. Molar mass:

1 mol CH4 = 16.0 g

(14)

Acetic acid C2H4O2 gives the sour taste to vinegar. Write two molar mass conversion factors for acetic acid.

(15)

Calculating Percent Composition

The formula is found on table T of the

reference table.

Mass of the part

Mass of the Whole X100

NaCl

(16)

Claculating Percent Composition

To determine the % composition of

sodium in NaCl

Mass of sodium in formula 22.99

Mass of entire formula 58.44 X100

39.34 %

(17)

Determining Percent

Composition

What is the percent composition of

Chlorine in NaCl?

Total mass of Cl in formula 35.45

Total mass of formula 58.44

(18)

Determining % Composition

What is the % composition of oxygen in

CuSO4?

Cu = 1 X 63.55 = 63.55

S = 1 X 32.07 = 32.07

O = 4 X 15.99 = 63.96

Total mass 159.58

Mass of Oxygen 63.96

(19)

Acetic acid C2H4O2 gives the sour taste to vinegar. Write two molar mass factors for acetic acid.

Calculate molar mass:

24.0 + 4.04 + 32.0 = 60.0 g/mole

1 mole of acetic acid = 60.0 g acetic acid Molar mass factors

1 mole acetic acid and 60.0 g acetic acid

(20)

Molar mass factors are used to convert between the grams of a substance and the number of moles.

Calculations Using Molar Mass

(21)

Aluminum is often used to build lightweight bicycle frames. How many grams of Al are in 3.00 mole Al?

Molar mass equality: 1 mole Al = 27.0 g Al

Setup with molar mass as a factor:

3.00 mole Al x 27.0 g Al = 81.0 g Al 1 mole Al

(22)

Learning Check

Allyl sulfide C6H10S is a

(23)

Calculate the molar mass of C6H10S.

(6 x 12.0) + (10 x 1.01) + (1 x 32.1) = 114.2 g/mole

Set up the calculation using a mole factor.

225 g C6H10S x 1 mole C6H10S

114.2 g C6H10S

molar mass factor (inverted)

(24)

Grams, Moles, and Particles

A molar mass factor and Avogadro’s number convert

grams to particles.

molar mass Avogadro’s number

g mole particles

particles to grams.

Avogadro’s molar mass number

(25)

Learning Check

How many H2O molecules are in 24.0 g H2O?

1) 4.52 x 1023

2) 1.44 x 1025

(26)

Solution

How many H2O molecules are in 24.0 g H2O?

3) 8.02 x 1023

24.0 g H2O x 1 mole H2O x 6.02 x 1023 H

2O molecules

18.0 g H2O 1 mole H2O

= 8.03 x 1023 H

(27)

Learning Check

If the odor of C6H10S can be detected from 2 x 10-13 g

(28)

Solution

If the odor of C6H10S can be detected from 2 x 10-13 g

in one liter of air, how many molecules of C6H10S are present?

2 x 10-13 g x 1 mole x 6.02 x 1023 molecules

114.2 g 1 mole = 1 x 109 molecules C

References

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