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Synthesis and Reactivity of Ruthenium and Platinum Amido and Carbene Complexes: Application Toward Carbon-Nitrogen Bond Forming Reactions

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Figure 2.13. The Dewar-Chatt model for interactions between transition metals and olefins: A) HOMO and LUMO of a C=C bond; B) σ-donation from the olefin HOMO to the metal d orbital; C) π-backbonding from the metal dπ orbital to the olefin LUMO
Figure 2.5. 1H NMR spectrum of (Cl)2(PCy3)2Ru=CH(NH-n-Pr) (2.6) in C6D6.
Figure 2.6. 1H COSY NMR spectrum of (Cl)2(PCy3)2Ru=CH(NH-n-Pr) (2.6) in C6D6.
Figure 3.4. ORTEP (30% probability) of (PCP)Ru(CO)(NHC(Me)NPh) (N1, 2.186(2); Ru1-N2, 2.182(2); C7-N1, 1.333(3); C7-N2, 1.317(3); N1-C1, 1.393(3); C7-C8, 1.508(4); P1-Ru1-P2, 154.87(2); N1-Ru1-N2, 59.69(8); N1-C7-N2, 110.2(2); N1-C7-C8, 126.6(2); N2-C7-
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10 Proposed catalytic cycle for hydroamination of norbornene with an Ir catalyst. 5 Four types of reactions on study of imine metathesis: (a) reaction of metal alkylidenes with organic imines; (b) reaction of metal imides with organic imines; (c) Experimental Section 10 Possible pathway for the conversion of (PCP)Ru(CO)(NHPh)(PMe 3 ) ( 3.3 ) Conclusions 4 Proposed reaction pathway of [(PCP)Ru(CO)( η 1 ClCH 2 Cl)] + ( 4.3 ) with

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