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KJLC Code:EJTPZ.9TO2A2
ACTIO MSDS ID: 776138
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SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION
(N/A)Product Name: Lead Zirconate−Titanium Oxide
Manufacturer Name:
Kurt J. Lesker Company
Address: 1925 Worthington Ave Clairton, PA 15205
TELEPHONE NUMBERS: (703) 527−3887 (outside USA)
US National Poison Hotline: (800) 222−1222
CHEMTREC Numbers:
For emergencies in the US, call CHEMTREC: 800−424−9300
Revision Date: 07/06/2006
Product Codes:
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SECTION 2 : COMPOSITION, INFORMATION ON INGREDIENTS
: (N/A)Ingredient Name CAS# Ingredient Percent
Lead Zirconate 12060−01−4 80 − 90% by Weight
OSHA PEL TWA: *0.05 mg/m3
ACGIH TLV TWA: *0.05 mg/m3 (as Pb)
EC Index Number: 1
Titanium oxide 130463−67−7 10 − 20% by Weight
OSHA PEL TWA: *10 mg/m3
ACGIH TLV TWA: *10 mg/m3 Total Dust
EC Index Number: 1
Comments: *All exposure limits are in milligram per cubic meter of air (mg/m3)
SECTION 3 : HAZARDS IDENTIFICATION
: (N/A) Emergency Overview: The material as sold in solid form is generally not considered hazardous. However, if the processinvolves grinding, melting, cutting or any other process that causes a release of dust or fumes, hazardous levels of airborne particulates could be generated.
Applies to all ingredients:
Route of Exposure: Inhalation, Skin contact.
Potential Health Effects: HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE: Listed below are certain potential health hazards, which apply to the hazardous ingredients, found in the subject alloy(s).
Target Organs: Central nervous system, blood system
Aggravation of Pre−Existing Conditions: Individuals who may have had allergic reactions to metals or sensitivity, may encounter skin rash or dermatitis, if skin contact with this product occurs. Persons with impaired pulmonary functions, may incur further impairment if dust or limes are inhaled
Lead Zirconate : Potential Health Effects:
Eye Contact: ZIRCONIUM:
Could be irritating to the eyes
Skin Contact: LEAD:
Irritating to skin and mucous membrane. Note: Lead can be absorbed though the skin.
ZIRCONIUM:
Irritating to skin and mucous membranes
Inhalation: LEAD:
Cutting and melting may produce dust and fumes, which may present potential health hazards. Prolonged inhalation or ingestion can result in lead poisoning. Symptoms include abdominal pain or colic, joint and muscle pain, muscular weakness.
ZIRCONIUM:
Inhalation of zirconium compounds may cause pulmonary granulomas.
Ingestion: LEAD:
Poison by ingestion Chronic Health Effects: LEAD:
Severe overexposure may lead to central nervous system disorder, characterized by sleepiness, stupor and ultimately death.
ZIRCONIUM:
Zirconium is not an important industrial poison. Carcinogenicity: NTP−2 “Reasonability anticipated to be a carcinogen”. IARC Designation: B−2 “Possible carcinogenic to humans”.
LEAD:
Toxicity: Lead and lead compounds may cause abdominal pain, diarrhea, loss of appetite, joint and muscle pain, irritability, headache and dizziness. Red blood calls may be damaged resulting in anemia. Injury to kidneys, liver and male gonads are possible. May cause harm to unborn child. Possible risk of impaired fertility.
Titanium oxide : Potential Health Effects:
Eye Contact: Irritating effects
Skin Contact: Irritating to skin and mucous membrane
Inhalation: Nuisance dust, may cause some irritation of the respiratory tract Ingestion: No information available
Chronic Health Effects: To the best of our knowledge the chronic toxicology of this substance is not fully known.
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SECTION 4 : FIRST AID MEASURES
: (N/A)Eye Contact: Dust or powder should be flushed from the eyes with running water for 15 minutes. If irritation persists obtain medical assistance.
Skin Contact: Skin cuts and abrasions can be treated by standard first aid. Skin contamination with dust or powder can be removed with soap and water. If irritation persists obtain medical assistance.
Inhalation: Breathing difficulty, caused by inhalation of dust or fume requires removal to fresh air. If breathing has stopped perform artificial respiration and seek medical assistance at once.
Ingestion: Obtain medical assistance at once.
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SECTION 5 : FIRE FIGHTING MEASURES
: (N/A)Flash Point: Non−flammable as a solid
Extinguishing Media: This material is non−combustible. For surrounding fires use appropriate extinguishing agent. Do not use water to extinguish fires around operations involving molten metal, due to the potential for steam explosion.
Fire Fighting Instructions: Self−contained breathing apparatus should be worn when fighting metal dust fires. High levels of dust or fine particles in the air may ignite or explode.
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SECTION 6 : ACCIDENTAL RELEASE MEASURES
: (N/A)Spill Cleanup Measures: In solid form this material poses no special clean−up problems. Use normal clean up procedures; wet sweeping or HEPA vacuum, for clean up of dust or powder. Do not use compressed air for cleaning.
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SECTION 7 : HANDLING and STORAGE
: (N/A)Handling: In solid form this material poses no special problems. Storage: Store metal in a dry area. Do not store adjacent to acids.
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SECTION 8 : EXPOSURE CONTROLS, PERSONAL PROTECTION
: (N/A) Ventilation System: GENERAL: RecommendedLocal Exhaust: Recommended, When cutting, grinding or melting or any other operation where dust or fumes are created
Skin Protection Description: Protective gloves are recommended, to prevent mechanical irritation. Eye/Face Protection: Safety glasses are recommended.
Respiratory Protection: Not normally required. Use an appropriate NIOSH approved respirator if airborne dust concentration exceed the OSHA, PEL or ACGIH, TLV
Other Protective: Eye wash fountain should be readily available in areas of use or handling. Exposure Limits: Refer to Section 2.
ENVIRONMENTAL SURVEILLANCE: If the operation generates dust or fumes, exposure to airborne materials should be determined by having air samples taken in the employees breathing zone and work area.
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SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES
: (N/A)Physical State/Appearance: FORM: Solid metal
Color: Silver/gray
Odor: None
Vapor Pressure: Not Applicable Vapor Density: 9.37 g/cm3 (100% Pb) Melting Point: 327 deg C (100% Pb) Solubility: IN WATER: Insoluble Specific Gravity: Varies
Percent Volatile: BY WEIGHT: Essentially zero
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SECTION 10 : STABILITY and REACTIVITY
: (N/A)Chemical Stability: This is a stable material.
Conditions to Avoid: Conditions which create dust or fumes.
Incompatibilities with Other Materials: Acetylene, Ammonia, Acids and Strong Oxidizers. Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: None under proper usage conditions.
SECTION 11 : TOXICOLOGICAL INFORMATION
: (N/A) Toxicological Paragraph: Under normal use of the solid form of this material there are few health hazards. Welding, cuttinggrinding or any process creating dust, fume or oxide may cause hazardous levels of certain elements, as addressed in Section 2.
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SECTION 12 : ECOLOGICAL INFORMATION
: (N/A)Ecological Paragraph: In solid form this material poses no special environmental problems. Metal powder or dust may have significant impact on air and water quality. Emissions, spill sand releases to the environment should be controlled immediately.
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SECTION 13 : DISPOSAL CONSIDERATIONS
: (N/A)Waste Disposal: Because of its high intrinsic value this material should be reclaimed. Dispose of in accordance with all applicable Federal, State and Local Regulations.
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SECTION 14 : TRANSPORT INFORMATION
: (N/A)DOT Shipping Name: Not regulated
DOT UN Number: None
DOT Hazard Class: None
DOT Hazard Technical Name: Metal Alloy
IATA: IATA, Dangerous Goods Regulations: Not Regulated, in solid form Reportable Quantity: PRODUCT RQ: None
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SECTION 15 : REGULATORY INFORMATION
: (N/A)Applies to all ingredients:
TSCA 8(b): Inventory Status: Components of these products are listed on the TSCA Chemical Substance Inventory of Existing Chemical Substances.
Section 313 Toxic Release Form: SARA TITLE III: The constituents of this alloy contain hazardous substances, above one(1) percent, and are subject to the reporting requirements under SARA Title III Section 313.
SUBSTANCE: Lead CAS No.: 7439−92−1 PERCENT MAXIMUM: 90
OSHA 29 CFR 1200: OSHA STATUS: Special attention is drawn to the OSHA Standard for Lead 29 CFR 1910−1025. The Hazard Communication Standard of the Occupational Safety and Health Administration, 29 CFR 1910.1200, considers components of this product a Hazardous Substance.
Canada WHMIS: WHMIS Disclosure List:
Lead falls into − Subdivision A of Division 2 of Class D, as defined by Section 52, of SOR/DORS−88−66
Risk Phrases: EUROPEAN UNION:
R−61, R−62, R−20/22, R−33, R−48
RCRA STATUS: Spent material could be considered a Hazardous Waste when materials are disposed of.
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SECTION 16 : ADDITIONAL INFORMATION
: (N/A)MSDS Revision Date: 07/06/2006 Disclaimer:
Kurt J. Lesker Company ("KJLC") believes the information contained in this Material Safety Data Sheet is accurate as of the "Date of Last Revision" specified. The information relates only to typical properties of the product. Do not use the information for product performance or specification purposes. The information is for use by technically skilled persons at their own risk. KJLC MAKES NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND, INCLUDING WITHOUT LIMITATION WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE PRODUCT OR THE INFORMATION. The information may not be valid for product use in combination with any other product or material or in any process. KJLC expressly disclaims any liability arising from any use of the product or any reliance on the information. Do not treat the information (a) as assurance that use of the product will not infringe patent or other rights or (b) as a license or grant of patent or other property rights. "KJLC"
means KJLC and each of its subsidiaries.
