1 Identification of the substance, preparation and company
1.1 Product identification
Trade name (art. no.): Geberit filler (art. no. 464.015.00.1).
1.2 Use of the substance/preparation
Filler
1.3 Manufacturer/EC marketing authorisation holder
Geberit International AG Schachenstrasse 77 8645 Jona, Switzerland Phone no.: +41 55 221 63 00
E-mail (expert member of staff): [email protected]
1.4 Emergency information
EU: Emergency advice centre for poisoning symptoms and embryo toxicology, Berlin
Phone no.: +49 (0) 30-19240
CH: Swiss Toxicology Information Centre National phone no.: 145 (24 h)
International phone no.: +41 44 251 51 51 (24 h)
2 Hazards identification
2.1 Classification
In accordance with (EC) Directive No. 1272/2008, the product is not classified.
2.2 Label elements
Labelling not necessary in accordance with (EC) Directive No. 1272/2008.
Hazard pictograms: not applicable Signal words: not applicable Hazard information: not applicable Special information on
hazards
for personnel and the environment:
no hazards that need to be mentioned specifically
2.3 Other hazards
Results of the PBT and vPvB assessment do not apply.
3 Composition/information on constituents
3.1 Chemical characterisation of mixtures
Description: Filler made of calcium sulphate hemihydrate, powdered limestone, copolymers made of vinyl acetate and ethylene, cellulose ether, copper phthalocyanine complex pigment, fatty acid salt
Hazardous constituents: Not applicable
Other constituents: CAS: 7778-18-9, calcium sulphate EINECS: 231-900-3
Reg. no.: 01-2119444918-26-XXXX
Remark: See Section 8 for substances which have a workplace exposure limit value.
4 First aid measures
4.1 Description of the first aid measures
General information: No special measures required.
After inhalation: Take the person to an area with fresh air. If symptoms persist, seek medical attention.
After contact with skin: Wash with plenty of soap and water.
After contact with eyes: Rinse open eyes for several minutes under running water. If symptoms persist, seek medical attention.
After ingestion: Rinse out mouth and drink plenty of water. Seek medical treatment.
4.2 Key acute and delayed symptoms and effects
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
5.1 Extinguishing agent
Suitable extinguishing agents: All extinguishing agents are suitable. Use fire-fighting measures that suit the environment.
Extinguishing agents deemed unsuitable for safety reasons:
none
5.2 Hazards arising specifically from the substance or mixture
None
5.3 Fire-fighting instructions
Special
protective equipment:
No special measures required.
Additional information: The product is non-combustible.
6 Accidental release measures
6.1 Person-related safety precautions, protective equipment, and procedures to be followed in the event of an emergency
Avoid the build-up of dust. Avoid contact with the eyes and skin.
6.2 Measures for environmental protection
Do not allow the material to enter the sewage system, surface water or ground water.
6.3 Methods and materials for clearing up and cleaning
Use mechanical methods to dry.
6.4 Reference to other sections
Product solidifies upon contact with water.
See Section 7 for information on safe handling.
See Section 8 for information on personal protective equipment.
See Section 13 for information on disposal.
7 Handling and storage
7.1 Protective measures for safe handling
Information on fire and explosion protection: No special measures required.
7.2 Conditions for the safe storage, taking into account incompatibilities
Requirement for storage rooms and receptacles: No special requirements.
Combined storage instructions: Not required.
Further information on storage conditions: Store in a dry condition. Keep the container tightly closed.
Storage class: Storage class according to the VCI: 13 (non-
combustible solids).
7.3 Specific end uses
No further relevant information available.
8 Limitation and monitoring of exposure/personal protective equipment
8.1 Parameters to be monitored
Constituents with limit values which must be monitored at the workplace:
CAS: 7778-18-9, calcium sulphate (50–100 %)
OEL: 6 mg/m3 A DFG
Note: A = respirable fraction
Additional information: The lists which were valid during compilation were used as a basis.
8.2 Limitation and monitoring of exposure
General measures for protection
and hygiene:
Take the usual precautions that apply when working with chemicals.
Personal
protective equipment:
-
Breathing protection: In the event of dust formation, wear a respiratory mask with an FFP2 filter.
Hand protection: The glove material must be impermeable and resistant to the product, substance and preparation. The choice of glove material must be informed by the perforation times, rates of diffusion and the level of degradation.
Glove material: nitrile-impregnated cotton gloves.
Penetration time of the glove material: Details of the exact perforation time must be obtained from the safety glove manufacturer. This time must be observed.
Eye protection: Where there is danger of splashing, wear protective goggles with side guards (as per EN 166).
Body protection: Protective work clothing
9 Physical and chemical characteristics
9.1 Information on the fundamental physical and chemical characteristics
State: Powder.
Colour: White, white-beige, white-grey; greenish when
mixed with water.
Odour: Odourless.
Odour threshold: Not determined.
pH value: Not applicable in delivery condition.
Melting point/melting range: Does not apply.
Boiling point/boiling range: Does not apply.
Flash point: Does not apply.
Flammability: Does not apply.
Ignition temperature: Does not apply.
Decomposition temperature: Not determined.
Spontaneous combustion: The product will not combust spontaneously.
Explosion hazard: The product is not explosive.
Steam pressure: Does not apply.
Density: approx. 2.7 g/m3
Relative density: Not determined.
Vapour density: Does not apply.
Evaporation rate: Does not apply.
Solubility in/miscibility with water: approx. 3 g/l (20 °C)
Partition coefficient: Does not apply.
Viscosity (dynamic): Does not apply.
Viscosity (kinematic): Does not apply.
9.2 Other information
Thermal decomposition of plaster: In CaSO4 and H2O from 140 °C.
In CaO and SO3 From 1000 °C.
10 Stability and reactivity
10.1 Reactivity
No further relevant information available.
10.2 Chemical stability/thermal decomposition/conditions to be avoided
No decomposition if used and stored according to specifications. Prevent exposure to moisture.
10.3 Possibility of hazardous reactions
No known dangerous reactions.
10.4 Conditions to be avoided
No further relevant information available.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
No known dangerous decomposition products.
11 Toxicological information
11.1 Information on toxicological effects
Further toxicological information: not toxic.
12 Environment-related information
12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability
No further relevant information available.
12.3 Bioaccumulative potential
No further relevant information available.
12.4 Mobility in soil
No further relevant information available.
Additional ecological information:
Do not allow product to reach ground water, water bodies or drainage system.
12.5 Results of PBT and vPvB assessment
PBT: Does not apply.
vPvB: Does not apply.
12.6 Other harmful effects
No further relevant information available.
13 Disposal considerations
13.1 Method of handling waste
Recommendation: Disposal in accordance with official guidelines.
European Waste Catalogue: 17 08 02 Gypsum-based building materials other than those mentioned in 17 08 01.
17 08 04 Mixed construction and demolition wastes other than those mentioned in 17 09 01, 17 09 02 and 17 09 03.
Uncleaned packaging: Recommendation: Ideally, contaminated packaging must be emptied.
After suitable cleaning, they can then be reused.
14 Transport information
14.1 UN number
ADR, IMDG, IATA: Not applicable
14.2 Proper UN transport ID
ADR, IMDG, IATA: Not applicable
14.3 Transport hazard classes
ADR, IMDG, IATA class: Not applicable
14.4 Packaging group
ADR, IMDG, IATA: Not applicable
14.5 Environmental hazards
Does not apply.
14.6 Special precautions for the user
Does not apply.
14.7 Transport of bulk materials in accordance with Appendix II of the MARPOL Convention 73/78 and in accordance with the IBC code
Does not apply.
UN Model Regulation:
-
15 Statutory regulations
15.1 Regulations regarding safety, health protection and environmental protection/specific statutory regulations for the substance or mixture
National regulations:
Water pollution class:
Water hazard class I (Annex 4, German Administrative Regulation on the Classification of Substances Hazardous to Waters, VwVwS, of 17.05.1999): slightly hazardous to water.
15.2 Substance safety assessment
No substance safety assessment has been carried out.
16 Other information
16.2 Data sheet issuing office
Geberit International AG Schachenstrasse 77 8645 Jona, Switzerland Phone no.: +41 55 221 63 00 [email protected] Department: Technical Authoring
16.3 Additional information
The information in this material safety data sheet is given to the best of our knowledge at the time of printing. The information is intended to provide you with points of reference for safe handling of the product specified in this material safety data sheet with respect to storage, processing, transport and disposal. This information cannot be applied to other products. In the event that the product specified in this material safety data sheet is combined or mixed or processed converted with other materials or is subjected to further treatment, the information contained in this material safety data sheet cannot be applied to the newly produced material, unless expressly specified otherwise.
16.4 Abbreviations used in this document
Abbreviation Meaning
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
CAS Chemical Abstracts Service DNEL Derived No Effect Level
EINECS European Inventory of Existing Commercial Chemical Substances IBC International Code for the Construction and Equipment of Ships Carrying
Dangerous Chemicals in Bulk
IATA International Air Transport Association
IMDG International Maritime Code for Dangerous Goods PBT Persistent, bioaccumulative and toxic
PNEC Predicted No Effect Concentration (predicted concentration up to which there are no noticeable effects on the environment)
VCI Verband der Chemischen Industrie (German chemical industry association) vPvB Very persistent and very bioaccumulative
VwVwS German Administrative Regulation on the Classification of Substances Hazardous to Waters
