Coordination cage
Catalysis in a Cationic Coordination Cage Using a Cavity-Bound Guest and Surface-Bound Anions: Inhibition, Activation, and Autocatalysis
... cationic coordination cage, which led to large increases in the rate of the Kemp elimination reaction of bound benzisoxa- zole, 11 is potentially general with other anions able to accumu- late around the ...
10
pH-dependent binding of guests in the cavity of a polyhedral coordination cage: reversible uptake and release of drug molecules
... We have demonstrated reversible pH-dependent uptake and release of several types of guest molecule into/out of the hydrophobic central cavity of a water-soluble coordination cage host; a graphical summary ...
7
Photoinduced energy and electron transfer from a photoactive coordination cage to bound guests
... self-assembled coordination cages offers possibilities that are only just beginning to be ...the cage assembly with a single bound ...the cage cavity, which can therefore interact with the chromophore ...
5
Binding of hydrophobic guests in a coordination cage cavity is driven by liberation of 'high energy' water
... the cage cavity in water, we have investigated sets of guest pairs which differ by the addition of a methylene group, and for each have measured by NMR spectroscopy the binding constant as a function of ...
8
Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage.
... The copyright exception in section 29 of the Copyright, Designs and Patents Act 1988 allows the making of a single copy solely for the purpose of non-commercial research or private study[r] ...
19
Photophysics of cage/guest assemblies : photoinduced electron transfer between a coordination cage containing osmium(II) luminophores, and electron deficient bound guests in the central cavity
... this cage/guest assembly in which one molecule of TCNB is centrally positioned in the cage cavity, astride the inversion centre, with an opposed pair of cyano groups directed into the two H-bond donor ...
27
Catalysis in a cationic coordination cage using a cavity bound guest and surface bound anions : inhibition, activation, and autocatalysis
... 16+ cage surface driven by ...the cage surface and displace hydroxide, inhibiting catalysis of the cage-based ...cationic cage surface, acting as the base for the next reaction ...the ...
10
Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage.
... refinement stable: these are described in detail in the CIF. We could locate and refine six of the expected eight [BF4]– anions in the asymmetric unit; all show disorder of the F atoms[r] ...
21
Imposing control on self assembly : rational design and synthesis of a mixed metal, mixed ligand coordination cage containing four types of component
... the cage allows us to identify how best to dissect the structure into component parts for a stepwise ...tris-chelate coordination geometry, and describe four triangular M 3 L 3 cyclic ...
6
Mapping the internal recognition surface of an octanuclear coordination cage using guest libraries
... of coordination cages, appropriate combinations of metal ions and bridging ligands can result in large pseudospherical arrays of remarkable complexity, generally having structures based on high-symmetry polyhedral ...
10
Mapping the Internal Recognition Surface of an Octanuclear Coordination Cage Using Guest Libraries
... of coordination cages, appropriate combinations of metal ions and bridging ligands can result in large pseudospherical arrays of remarkable complexity, generally having structures based on high-symmetry polyhedral ...
9
A chiral self-sorting photoresponsive coordination cage based on overcrowded alkenes
... discrete cage complexes, allowing cage-to-cage transfor- mations (Scheme ...the cage isomers can bind a tosylate anion in solution by formation of a host–guest ...
7
Economic Feasibility and Resource Use Efficiency of Coastal Cage Fish Farming in Kerala
... coastal cage farms in the state are located in this ...selected cage farms in Ernakulum district of Kerala was collected during the year ...320 cage farm units installed in the backwaters of ...
6
The chemistry of functionalised cage complexes
... In a few instances, cages undergo oxidation resulting in either a m id e 15 or imine16 groups being embodied into the caps or ethylene fragments of the ligand. The complex may do this by an internal redox reaction ...
395
Linear Diffusion into a Faraday Cage
... Abstract—In this paper, linear lightning diffusion into a Faraday cage is studied. The high-altitude Electromagnetic Pulse (HEMP) and nearby lightning are used as examples for a uniform field drive and the ...
13
Static Analysis of Roll Cage
... Roll cage of a single seated ...roll cage is created using CATIA software, Detailed description of material is provided, finite element meshing is done, the load condition is worked out and the boundary ...
8
PEACE, DEVELOPMENT AND SOCIAL HARMONY
... coordination of regional development, coordination of economic development and social development, coordination of humans and nature, and coordination of internal national de[r] ...
11
Engineering consideration for cage aquaculture
... cages. Cage culture of fish utilizes existing waterresources and fishes which are enclosed in a cage or basket allows water to pass freely between the fish and the ...Modern cage culture began in the ...
8
Design and Analysis of Roll Cage for an Electric Hybrid Tricycle
... The design of chassis was finalised for CAE analysis after few design modifications and iterative changes for the component mountings and C.G. adjustment. Then the wireframe model of the roll cage was generated to ...
6
Evaluation of unilateral cage-instrumented fixation for lumbar spine
... inserted cage can be held by the screw-rod system, and the cage can maintain adequate disc space, which is particularly effective for correcting instability associated with degenerative disc ...
7