DISTORTED SQUARE PLANAR
A distorted square planar PdII complex with a shortened Pd—Cl bond induced by the bulky terpyridyl ligand 6,6′′ dimesityl 2,2′:6′,2′′ terpyridine
... a distorted square-planar coordination formed by three N atoms and a chloride ion; the distortion is due to the extremely bulky terpyridyl ...almost planar coordination geometry, with similar ...
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Diaquabis(4 chlorobenzoato κO)bis(N,N diethylnicotinamide κN1)manganese(II)
... is a monomeric complex with the Mn II atom lying on an inversion center. It contains two 4-chlorobenzoate and two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the ...
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Tetraaquabis[4 (dimethylamino)benzoato κO]manganese(II) dihydrate
... slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two water O atoms in the axial ...
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cis [rac 1,3 Bis(phenylsulfinyl)propane S,S′]dichloroplatinum(II)
... slightly distorted square-planar geometry. The crystal repre- sents the racemate formed by the molecules with the (R,R) and (S,S) con®gurations of the sulfur chiral centres in the chelate ring. The ...
7
Diaquabis[4 (dimethylamino)benzoato κO](nicotinamide κN1)cobalt(II) dihydrate
... slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two NA N atoms in the axial ...
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(Acetonitrile)(6,6′′ dimesityl 2,2′:6′,2′′ terpyridine)copper(I) hexafluorophosphate
... a distorted square-planar coordination, with four N atoms from dmtpy and acetonitrile molecules, as a result of the extremely bulky terpyridyl ...
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Diaquabis(4 bromobenzoato κO)bis(N,N′ diethylnicotinamide κN1)zinc(II)
... is a monomeric complex with the Zn II atom lying on an inversion center. It contains two 4-bromobenzoate, two diethylnicotinamide ligands and two water molecules, all of which are monodentate. The four O atoms in the ...
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Diaquabis(2 chlorobenzoato κO)bis(nicotinamide κN1)cobalt(II)
... slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial ...
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Tetraaquabis(nicotinamide κN1)cobalt(II) bis(2 fluorobenzoate)
... slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial ...
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THIO-LIGANDS in MONOMERIC Pt(II) COMPLEXES – STRUCTURAL ASPECTS
... This review includes over three hundred derivatives in which each Pt(II) atom is in a distorted square planar environment with inner coordination spheres of PtS4, PtS3X, PtS2X2, PtSX3, PtS2XY, PtSX2Y ...
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Crystal structure of trans diaquabis(4 cyanobenzoato κO)bis(N,N diethylnicotinamide κN)cadmium
... slightly distorted square-planar arrangement around the Cd1 atom, while the slightly distorted octahedral coordination sphere is completed by the two pyridine N atoms (N1 and N1 i ) of two ...
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Diaquabis(3 chlorobenzoato κO)bis(nicotinamide κN1)cobalt(II)
... slightly distorted square-planar arrangement, while the slightly distorted octahedral coordina- tion is completed by the two N atoms of the NA ligands in the axial ...
8
Diaquabis(N,N diethylnicotinamide κN1)bis(4 ethylbenzoato κO)cobalt(II)
... slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial ...
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{2 [1 (2 Methoxy 6 oxidophenyl κO6)ethylidene] N methylhydrazinecarbothioamidato κ2N2,S}(triphenylphosphane κP)palladium(II) ethanol monosolvate
... slightly distorted square-planar environment by three donor atoms (NOS) from a thiosemicarbazonate ligand, forming five- and six-membered chelate rings, and a P atom from a neutral triphenylphosphane ...
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Ammine[2 hydroxy 1 naphthaldehyde 4 piperidylthiosemicarbazonato]nickel(II)
... is distorted square planar, as indicated by the distances and angles around the metal ...almost planar and the angle between the Ni1ÐS1ÐN1ÐN2ÐC12 and Ni1Ð O1ÐN1ÐC1ÐC2ÐC11 chelate rings is ...
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Chloro(pyrimidine 2 thiolato κ2N,S)(triphenylphosphine κP)palladium(II) methanol hemisolvate
... slightly distorted square-planar geometry ...slightly distorted square-planar geometry of the Pd atoms is also revealed by the displacements of the Pd atoms from the mean plane ...
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(Azido κN){(E) 2 [1 (pyridin 2 yl)ethylideneamino]phenolato κ3N,N′,O}copper(II)
... Comment In the title complex, [CuC13H11N2ON3], the CuII ion exhibits a slightly distorted square-planar coordination environment defined by the deprotonated tridentate Schiff base ligand[r] ...
7
Di μ hypophosphito bis[(2,2′ bipyridine)copper(II)] nitrate
... bipyridine) joined by two hypophosphite bridging ligands, with each metal center in a distorted planar arrangement. These joined subunits exist as a discrete cation with the equivalent of two nitrates as ...
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Synthesis, Spectral Characterization and Computational Studies of Metal Chelates of 4-N-(2-Thienylidene)aminoantipyrine
... Based on these data, an octahedral geometry for manganese(II) and cobalt(II) complexes whereas distorted square planar geometry for copper(II) complex has been assigned to the complexes [r] ...
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Tetra μ2 cyano κ8C:N μ2 2,6 dimethylpyrazine κ2N:N′ hexakis(2,6 dimethylpyrazine κN)octa μ2 thiocyanato κ16N:S decacopper(I,II)
... pendent Cu atoms, four thiocyanate anions and two cyanide anions, as well as four 2,6-dimethylpyrazine ligands. Two of the six Cu atoms and one of the four 2,6-dimethylpyrazine ligands are located on centres of ...
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