OCTAHEDRAL COORDINATION
Tetrahedral and octahedral coordination for zinc in polymeric tris(μ3 4 carboxyphenoxyacetato)di μ3 hydroxo bis(μ2 4,4′ bipyridine)tetrazinc(IV) dihydrate
... tetrahedral coordination for one of the zinc atoms in the asymmetric unit of the centrosymmetric structure and to octahedral coordination for the the other ...
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Poly[bis{μ N′ [(pyridin 4 yl)methylidene]benzohydrazidato}copper(II)]
... elongated octahedral coordination geometry with the equa- torial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the apices by the N atoms of two pyridine rings ...
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catena Poly[[[diaquacadmium(II)] di μ thiocyanato] bis(2 amino 4,6 dimethylpyrimidine)]
... in the triclinic space group P1. The asymmetric unit contains one 2-amino-4,6-dimethylpyrimidine molecule, a thiocyanate ion, a water molecule and a cadmium ion (site symmetry 1). The cadmium ions are symmetrically ...
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Bis(3 methylbenzoato κ2O,O′)(phenanthroline κ2N,N′)copper(II)
... atom is located on a twofold axis and is surrounded by a phenanthroline (phen) molecule and two methylbenzoate anions in a distorted octahedral coordination geometry. Two O atoms from carboxyl groups and ...
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Polymeric aqua(benzimidazole κN)(μ malonato)cobalt(II)
... The octahedral coordination is formed by a chelate malonate, two monodentate malonates from adjacent asymmetric units, a benzimidazole ligand and a coordinated water molecule.. The malon[r] ...
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Aquanitro(α,β,γ,δ tetraphenylporphyrinato)cobalt(III) dichloromethane solvate
... distorted octahedral coordination, with the water molecule in a position trans to the nitro ligand ...N9/N10/N11 coordination plane towards the nitro ligand. In the tpp coordination plane, the ...
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catena Poly[[aquazinc(II)] μ N,N′ bis(2 cyano 3 ethoxy 3 oxoprop 1 enyl)benzene 1,2 diaminido]
... distorted octahedral environment. The fifth coordination site in one apical position is held by a coordinating solvent water molecule whereas the complete octahedral coordination sphere is ...
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Di μ2 acetato 1:2κ2O:O′;2:3κ2O:O′ bis{μ2 4,4′ dichloro 2,2′ [2,2 dimethylpropane 1,3 diylbis(nitrilomethanylylidene)]diphenolato} 1:2κ6O,N,N′,O′:O,O′;2:3κ6O,O′:O,N,N′,O′ tricadmium
... distorted octahedral coordination geometry formed by four O atoms from two bidentate/ tetradentate Schiff base ligands and two O atoms from two bridging acetate ...The coordination geometry of the ...
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cis Bis(8 hydroxyquinolinato κ2N,O)diphenyltin(IV)
... the coordination geometry about the Sn atom, are given in Table ...cis- octahedral coordination geometry, with exactly the same arrangement of donor atoms as found in the previous struc- tures of ...
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Diaquabis(1H imidazole κN3)bis(nitrobenzoato κO)manganese(II)
... atom is located on an inversion center and has an octahedral coordination geometry (Table 1) formed by nitrobenzoate anions, imidazole molecules and water molecules. The nitro- benzoate anions are planar ...
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Aqua(oxydiacetato κ3O,O′,O′′)(1,10 phenanthroline κ2N,N′)cobalt(II) sesquihydrate
... asymmetric unit of (I) contains two molecules of the complex and three molecules of lattice water, as shown in Fig. 1. The two independent complex molecules display a similar octahedral coordination ...
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Triaqua(2,2′ biimidazole)oxovanadium(IV) sulfate dihydrate
... distorted octahedral coordination formed by vanadyl oxygen, three water ligands and two N atoms of the 2,2′-biimidazole ...in octahedral complexes (Kime-Hunt et ...
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Octacarbonyl μ dicyclohexylphosphido μ N,N diethyldithiocarbamato dirhenium
... ligand. Each Re atom is additionally attached to four terminal CO ligands and attains thus a slightly distorted octahedral coordination. Carbonyl groups 4 and 7, which are both in trans-position to the ReÐP ...
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Lithium tetrachloridoaluminate, LiAlCl4: a new polymorph (oP12, Pmn21) with Li+ in tetrahedral interstices
... While the lithium cations in LiAlCl4mP24 are in octahedral coordination and the aluminium and lithium ions in the solid of orthorhombic LiAlCl4 occupy tetrahedral interstices with site s[r] ...
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Bromido[1 (η6 4 tert butylbenzyl) 3 (2,4,6 trimethylbenzyl)benzimidazol 2 ylidene]chloridoruthenium(II)
... distorted octahedral coordination environment with the arene occupying three coordination ...further coordination sites are occupied by chloride and bromide ligands, while the sixth site is ...
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catena Poly[[trans bis(1,3 benzothiazole κN)manganese(II)] di μ chlorido]
... an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial ...
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catena Poly[[[diaquacobalt(II)] bis{μ 2 [3 (4 carboxylatophenyl)pyridin 1 ium 1 yl]acetato}] dihydrate]
... and one lattice water molecule. Each Co atom resides in a distorted octahedral coordination geometry completed by four carboxylate O atoms from four L ligands and two O atoms from two coordinated water ...
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catena Poly[[[bis[2,2′ (propane 1,3 diyldithio)bis(1,3,4 thiadiazole) κN4]copper(II)] bis[μ 2,2′ (propane 1,3 diyldithio)bis(1,3,4 thiadiazole) κ2N4:N4′]] bis(perchlorate)]
... distorted octahedral geometry. The ligand L adopts two kinds of coordination modes in the crystal structure; one is a monodentate coordination mode and serves to complete the octahedral ...
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Crystal structure of a CoII coordination polymer: catena poly[[μ aqua bis(μ 2 methylpropanoato) κ2O:O′;κ2O:O cobalt(II)] monohydrate]
... The structure of (I) contains one independent Co 2+ cation coordinated by four O atoms from four bridging isobutyrate ligands and two O atoms from two bridging water molecules (O1W) in a distorted octahedral ...
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Tris(1H benzimidazole κN3)(oxydiacetato κ3O,O′,O′′)cobalt(II)
... oxydiacetate dianion and three benzimidazole molecules coordinate to the Co II cation, resulting in a distorted octahedral geometry. The oxydiacetate ligand chelates to the Co II cation with a facial configuration ...
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