PHOSPHANE LIGAND
![Crystal structure of trans dihydridobis[tris(dimethylamino)phosphane κP]platinum(II)](data:image/gif;base64,R0lGODlhAQABAIAAAP///wAAACH5BAEAAAAALAAAAAABAAEAAAICRAEAOw==)
Crystal structure of trans dihydridobis[tris(dimethylamino)phosphane κP]platinum(II)
... a ligand on the catalyst is capable of hydrogen bonding, the entering water nucleophile can be activated by hydrogen bonding interactions, avoiding the need for strongly basic ...as ligand assisted ...
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Tris(naphthalen 1 yl)phosphane chloroform hemisolvate
... The molecular structure of the title compound is shown in Fig. 1. The chloroform solvent molecule is disordered across an inversion center. The average P–C distance and C–P–C angle are 1.837 (3) Å and 102.43 (12)°, ...
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trans Dichloridobis[tris(4 methoxylphenyl)phosphane κP]platinum(II) acetone disolvate
... Molecules of the title compound (Fig. 1) crystallizes in the P1 (Z = 1) space group with the Pt atom on an inversion center and two acetone solvate molecules accompanying it. Each pair of equivalent ligands is in a trans ...
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cis Dichloridobis[tris(4 chlorophenyl)phosphane κP]platinum(II) acetonitrile monosolvate
... monomeric units with a square-planar geometry around the Pt II atom. The two tris(4-chlorophenyl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt— Cl angles of 99.36 (2) and 88.02 (2) ...
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trans Dichloridobis[dicyclohexyl(4 isopropylphenyl)phosphane κP]platinum(II) acetone monosolvate
... For background to our investigation of the steric and elec- tronic effects of group 15 ligands, see Roodt et al. (2003); Muller et al. (2006, 2008). Examples of the packing disorder observed in Vaska-type complexes of ...
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[4 (Dimethylamino)phenyl]diphenylphosphine selenide
... of phosphane ligands a variety of models have been developed, of which the Tolman cone angle (Tolman, 1977) is still the most commonly used ...the phosphane (calculated as 158° and 161° ...free ...
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(Nitrato κO)tris[tris(4 fluorophenyl)phosphane κP]copper(I)
... atoms define a distorted tetrahedon with the three tris(4- fluorophenyl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intramolecular – interaction ...
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trans Dichloridobis{tris[4 (trifluoromethyl)phenyl]phosphane κP}palladium(II) dichloromethane monosolvate
... this phosphane ligand in ...the phosphane from 16 hits, containing 17 useable observations with a standard deviation of ±4° and a spread from 149° to ...
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Diphenyl(pyridin 2 yl)phosphane selenide
... Molecules of the title compound (Fig. 1) adopts a distorted tetrahedral arrangement about the P atom with average C—P —C and Se—P—C angles of 105.47° and 113.20° respectively. Describing the steric demand of ...
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Development of artificial metalloenzymes via covalent modification of proteins
... containing phosphane-ligands have been created with the non-covalent approach, using the biotin-avidin system 4 and ...a phosphane-ligand is the aforementioned modification of the active site serine ...
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← Return to Article Details SYNTHESIS, CHARACTERIZATION, LUMINESCENCE AND DNA BINDING PROPERTIES OF Ln (III)-SCHIFF BASE FAMILY
... each of the lanthanide complexes (La(III), Pr(III), Nd(III), Sm(III) and Eu(III) and is attributed to metal coordination by the ligand. The higher energy band in the free ligand is observed as a single band ...
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Modification on Synthesis of Mixed Ligand Chelates by Using Di and Trivalent Transition Metal Ions with Schiff Base as Primary Ligand
... primary ligand and malonyldihydrazide as secondary li- gand have been ...Mixed ligand of Ni(II), Cu(II) and Zn(II) chelates of nicotinanilide and thiocyanate was ...
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Original Article Macrophages polarization is mediated by the combination of PRR ligands and distinct inflammatory cytokines
... The combination of iE-DAP or MDP with each TLR ligand was also investigated. Using the def- initions of “synergy” and “inhibition”, the inter- actions between TLR ligands and NOD ligands were studied. Compared ...
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Iodido{4 phenyl 1 [1 (1,3 thiazol 2 yl κN)ethylidene]thiosemicarbazidato κ2N′,S}{4 phenyl 1 [1 (1,3 thiazol 2 yl)ethylidene]thiosemicarbazide κS}cadmium(II)
... other ligand via ...deprotonated ligand is twisted due to intra-molecularly hydrogen bonds (N7H···N5), while the ligand forms an intermolecular hydrogen bond via S2 with NH group (N4) from the other ...
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(Di tert butylphosphanyl)bis(diphenylphosphanyl)phosphane
... The molecular structure of (1) is shown in Fig.1. The geometry around P3 atom in (1) is pyramidal, the sum of angles around P3 is 310.26 degrees. The geometry around P1 atom indicates more pyramidal character (the sum of ...
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Docking Evaluation of Catechin and its Derivatives on Fat Mass and Obesity-Associated (FTO) Protein for Anti-Obesity Agent
... The three-dimensional structure of FTO protein (PDB code 3LFM) was downloaded from www.rcsb.org (Han et al., 2010). The receptor’s structure data were downloaded and opened using Discovery studio 3.5 Client program to ...
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Dockres: a computer program that analyzes the output of virtual screening of small molecules
... the ligand and the protein (nHB), the ligand charge (q), the protein atom (atom and residue names and numbers) closest to the ligand (pa), the distance from the binding site (Rbs) and the chemical ...
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Synthesis and biological evaluation of some new schiff base metal complexes
... For the Preparation of Cu(II) and Ru (II) metal chloride salts were used. Dissolve 3.1532g(0.01 Mole)of newly synthesized ligand in adequate of methanol. To this solution, aqueous solution of 1.3434 g(0.01Mole) ...
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Synthesis, Characterization and Antioxidant Activities of Transition Metal Complexes
... In recent years the importance of metal ions for smooth operation of plant and animal organisms were evidenced by the publication of numerous papers in the field of biophysics and biochemistry. Latest researches in these ...
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Biomacromolecule ligand interactions
... Competitive binding studies and molecular dynamics simulations were used to probe the binding geometries of the cnantiomers of the parent cylinder and two mcthylated cylinders to DNA as [r] ...
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