[PDF] Top 20 Crystal structure of a CoII coordination polymer: catena poly[[μ aqua bis(μ 2 methylpropanoato) κ2O:O′;κ2O:O cobalt(II)] monohydrate]
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Crystal structure of a CoII coordination polymer: catena poly[[μ aqua bis(μ 2 methylpropanoato) κ2O:O′;κ2O:O cobalt(II)] monohydrate]
... polynuclear cobalt carboxylates in turn have attracted great attention because of their utilization in homogeneous oxidation catalysis (Gates, 1992; Parshall & Ittel, 1992; Partenheimer, 1995; Ward et ...the ... See full document
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Crystal structure of catena poly[[[diaquabis(2,4,6 trimethylbenzoato κO)cobalt(II)] μ aqua κ2O:O] dihydrate]
... carboxylate O atoms (O1 and O1 i ) of the two symmetry-related TMB anions and the two symmetry-related water O atoms (O3 and O3 i ) around the Co II cation form a slightly distorted square-planar ... See full document
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Crystal structure of a looped chain CoII coordination polymer: catena poly[[bis(nitrato κO)cobalt(II)]bis[μ bis(pyridin 3 ylmethyl)sulfane κ2N:N′]]
... Co II cation is coordinated by four pyridine N atoms from four symmetry-related L ...Co II cation binds to two O atoms of two symmetry-related monodentate nitrate anions, forming a distorted ... See full document
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Crystal structure of a zigzag CoII coordination polymer: catena poly[[dichloridobis(methanol κO)cobalt(II)] μ bis(pyridin 3 ylmethyl)sulfane κ2N:N′]
... the crystal structure of a looped-chain Co II coordination polymer obtained through the reaction of cobalt(II) nitrate with L (Moon et ...the crystal ... See full document
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catena Poly[[aqua(4,4′ dimethyl 2,2′ bipyridine)copper(II)] μ fumarato κ2O,O′:κ2O′′,O′′′ [aqua(4,4′ dimethyl 2,2′ bipyridine)copper(II)] μ fumarato κO:κO′]
... chain structure in which fumarate ligands link the Cu atoms; the chains are then linked together by hydrogen ...Cu II ion exhibits a distorted octahedral coordination geometry defined by three ... See full document
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catena Poly[[[tetraaquacopper(II)] μ sulfato κ2O:O′ [bis(malonamide κ2O,O′)copper(II)] μ sulfato κ2O:O′] dihydrate]
... octahedral coordination, while for atom Cu1 the deviation is more pronounced (Table ...(Table 2) involves the uncoordinated water molecules and stabilizes the crystal ... See full document
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catena Poly[[aquabis(3 chlorobenzoato κ2O,O′)cadmium] μ N,N diethylnicotinamide κ2N1:O]
... Cd II cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b ...Intermolecular O—H O hydrogen bonds between ... See full document
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catena Poly[[[bis(4 methylbenzoato κ2O,O′)zinc(II)] μ 4,4′ bipyridine κ2N:N′] tetrahydrate]
... two N atoms of two 4,4′-bipy ligands [Zn—N, 2.064 (2) Å] and chelated to two 4-methylbenzoate anions [Zn1—O1, 2.159 (3) Å and Zn1—O2, 2.261 (3) Å]. The crystallographic inversion center and glide plane present at ... See full document
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Crystal structure of a CoII coordination polymer with a dipyridyl ligand: catena poly[[bis(nitrato κ2O,O′)cobalt(II)] μ N (pyridin 2 ylmethyl)pyridine 3 amine κ3N,N′:N′′]
... Co II atom, one L ligand and two nitrate anions, which coordinate the cobalt ion in a bidentate chelating ...Co II atom is distorted pentagonal bipyramidal with the five basal sites being occupied by ... See full document
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Orientational disorder in the one dimensional coordination polymer catena poly[[bis(acetylacetonato κ2O,O′)cobalt(II)] μ 1,4 diazabicyclo[2 2 2]octane κ2N1:N4]
... Co II atom is six-coordinated, the O-donor atoms of the chelating acac ligands occupying the equatorial positions and the bridging DABCO ligands being in trans-axial ...the crystal structure, ... See full document
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Crystal structure of bis(acetato κ2O,O′)diaqua[1 (pyridin 2 ylmethylidene κN) 2 (pyridin 2 yl κN)hydrazine κN1]terbium(III) nitrate monohydrate
... forming coordination compounds with metal ions and can generate a wide variety of coordination ...N, O or S binding sites, designed to yield special topological struc- tures (Binnemans, ...molecular ... See full document
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Tetrakis(μ 4 chlorophenoxyacetato κ2O,O′)dimolybdenum(II)
... carboxylate O atom in a neighbouring molecule and their symmetry-generated atoms, forming a parallelogram with Mo—O atom distances of ...(Fig. 2), resulting in an infinite chain ...[Mo 2 (OCOC ... See full document
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catena Poly[[[di μ acetato 1κ2O:2κ2O′ bis[(acetato κ2O,O′)cadmium(II)]] di μ 4,4′ bipyridine 1κN:1′κN′;2κN:2′κN′] monohydrate]
... The construction of metal-organic frameworks (MOFs) is currently receiving considerable attention owing to their potential properties as functional solid materials, as well as their fascinating framework structures ... See full document
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Bis(μ acetylacetonato κ2O:O′)bis[(acetylacetonato κ2O,O′)aquanickel(II)] hemihydrate
... 0.831 (17) 2.106 (18) 2.906 (2) 161 (2) O10—H10E O8 i 0.816 (16) 2.051 (17) 2.8494 (18) 166 (2) O10—H10D O4 0.843 (16) 1.924 (17) 2.7649 (19) 175 (3) O11—H11D O9 0.970 (18) 1.96 (2) 2.890 ... See full document
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Bis(μ 2 hydroxybenozato) κ3O,O′:O′;κ3O:O,O′ bis[(2 hydroxybenozato κ2O,O′)(1,10 phenanthroline κ2N,N′)cadmium(II)]
... solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008) and ORTEP-3 (Farrugia, 1997); soft- ware used to ... See full document
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Disodium diaquabis(malonato κ2O,O′)cobalt(II) monohydrate
... solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: ... See full document
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catena Poly[[aqua(1,10 phenanthroline κ2N,N′)cobalt(II)] μ 4 carboxyphenoxyacetato κ3O,O′:O′′]
... 4-CPOA 2 ligand shows various coordination modes, including bi-, tri- and tetradentate (Gu, Gao, Huo et ...reported polymer, namely {[Co(4-CPOA)(3-hydroxypyridine) 2 (H 2 O) ... See full document
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catena Poly[[[diaquacobalt(II)] μ tartrato κ4O,O′:O′′,O′′′] monohydrate]
... ation mode; the hydroxyl O atom and one O atom of the carboxyl group are involved in the chelate bonding but the other O atom of the carboxyl group is uncoordinated. Thus, the carboxyl group binds in ... See full document
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Bis(2 formylphenolato κ2O,O′)nickel(II)
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ... See full document
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Bis(2 aminopyrimidine κN1)diaquadinitrato κO;κ2O,O′ cadmium(II) monohydrate
... solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for ... See full document
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