Subject Index To Volume 33237-244

(1)

SUBJECT INDEX TO VOLUME 33

a=abstract Page

Absorption, spectra, of Pt(phpz), , Pt( 100)-CO, a 24. 85 Acetals, acetaldehyde dialkyl-, formation, a I46 Acetic Acid. Anhvdride. Acetvls. BP olant 168

Acetaldehyde 33, 60

- I

.

Acetone, hydrogeAation, ‘a

Acetylene, reactions with Pd catalysts, a

Adsorption, C, S, effect on H-Pd permeation, a 89. CI, on Pt electrode, in 0 reduction, a

CO, 0, on Pt, Pd, a EtOH. on Pt electrodes, a

H, on Pt electrodes, sulphurised Pt, a H, D, in Pd, hydride formation, a HCI, +H, +H,O, on P t ( l l l ) , a NO, on Rh(100). a

Alcohols, allyl, hydroformylation, a

aqueous, photocatalytic dehydrogenation, a benzyl, electro-oxidation, a

butyl, from propene hydroformylation, a ethyl. for H production, a

81, 129,

84,

oxidation on Pt electrodes, a

30 I46 214 I39 219 83 139 213 213 82 90 I 40 27 I43 I45 83

production, a 32, 220

isopropyl, reactions with H,PtCI,, PtCI,, a 26 84 adsorption on PdlCeO,, SiO,, TPD, a 219 catalysts for exhaust control, a 88 conversion to aromatics, a 144 decomposition on Pd, CO desorption, a 214

dehydrogenation, a 32, 85

for acetic acid, ace$% anhydride I68 for H, in Hot Spot reactor 1 I8

fuel cells, a 33, 91

oxidation, on Pt, Pd, a 26, 33, 83, 84, 139 preparation, on Pd/SiO, +Fe, MgO. a 89

waste, for H production 58

methyl, +H,O, for H photoproduction, a 141

oleyl, production, a I45

220 photoreactions, with Pt complex, a 141 production from hydrocarbons, a 32 secondary, oxidation to ketones, a 147 selective oxidation. by Ru(1V)-phosphine, a 26 91, 143, 144, 145, 221 see also Acetaldehyde, Formaldehyde,

222 Alkali Metal Thermoelectric Converter, a 1 40

Alkanes, a 32, 144, 147

Alkenes, a 32, 89, 186

2-Alkoxy 1,3-Diene, production, a I46 Alkyl Vinyl Ethers, vinylation with enol triflates, a 146

Alkynes, a 89, 147

Allylic Acetates, electroreactions with carbonyls, a 139 Aluminium, Pd thin films on, a 81 Aminonitriles? production, on RhlMgO, a 31 Ammonia, oxidation, catalyst gauze etching study 12

production, a 27. 216, 220

sensors, a 28, 217

Andrussow Process, catalyst gauze etching study 12

Antimony, a 142, 143

Arenes, C-C bond formation reactions I86 144 Aromatisation, n-hexane, a 30, 143, 218

Arsenic, detection, a 142

a-Keto Esters, hydrogenation, a 218

Battery, redox, rechargeable, with Ru complexes, u 91

Benzaldehyde, production, a 27

Benzene, a 90

220

Bicarbonate, photoreduction, a 141

Bonding, Pt wire wedge, for IC, microsensor, a 34 methyl, on

Pt(IOO),

R(l1 I ) electrodes, a

phenyl, synthesis, on Co-Rh, a

Aldehydes, a Benzaldehyde

Alditols, for aldonolactone synthesis, a

Aromatics, production from MeOH, a

2-Arylethanols, synthesis, a 220

Benzyl Halide, reaction with CO/H. a

Page

Chemistry I I7

Combustion Research in Japan, Vol. 5 I05

Geo-Platinum 87, symposium 13

21 Boundary Layers, subminiature sensor for, a I42 BP Chemicals Ltd, acetic acid, plant I68

Bronzes,

W

doped with Pt, a 26

1,3-Butadiene, catalytic reactions, a 29, 89 Butane, oxidation, by Pt black-MO,, a 87

Butyraldehyde, formation, a I43

Cadmium 84, 193

Cancer, antitumour properties of complexes. a 35, 92 cisplatin, carboplatin drug therapies I62 Pt pyrimidine greens, one-pot synthesis, a 148

Carbalkoxylation, C,H,, a 146

Carbon, C-C bond formation reactions I86 C , - 0 compounds, synthesis on Rh/V,O,, a 90 effect on H-Pd permeation, a 2 I4 Carbon Oxides, CO, adsorption, oxidation on

81, 137 adsorption on Pd/SiO,. Pd size effect, a 219

concentration sensor 180

disruption of RhlAl

,

0, , NO effect on, a 3 I effect on propene-D exchange reaction, a 143 emission control from gas turbines 46 for NO, reduction on Pt foil, a 81, 138 from MeOH decomposition on Pd(l I I ) , a 214 hydrogenation, for Rh,, RhFe zeolite, a 220 hydrogenation, a 31, 88, 142, 144, 219

in MeOH synthesis, a 89

oxidation, a 219, 220

poisoning of

Pt

in fuel cells, a 91 Pt-C stretch mode, in Pt( I I 1 )-CO spectra, a 24 reactions with H, a 144, 219, 220 CO, CO, , reduction on Ru pyrolysed

polyacrylonitrile, a 31

C O , , greenhouse gas 194

hydrogenation, on Pd/La,O, , a 30

reaction with alkynes, a 147

222

sensor, portable, cheap I27

Carbonylation 90. 145, 168

Carbonyls, addition to allylic acetates, a I39 Carboplatin, anti-cancer drug therapy I62

Castor Oil, hydrogenation, a 147

Catalysis, heterogeneous, a 29, 30, 31, 87, 88, 89, 90, 142. 143, 144, 145, 218, 219, 220

a 32, 90, 91, 145, 146, 147, 221, 222 61, 143, 194, 218 CeRu,, CeCo,: CeFe,, NH, synthesis, a 220 Co-Rh bimetallic. 2-arvlalcohol. a 220 Book Reviews, Advances in Metal Carbene

Gmelin Handbook of Inorganic Chemistry

Pt( I I I), Pt( 110). S/Pt( I 1 I ) , a

reduction, electrocatalytic, to fuels 2 reduction to CH,, via formamide. a

homogeneous, for COI electroreduction 2 Catalysts, automotive exhaust

.

,

Honeycat@

in fuel cells, review 63.

Ir, Rh/AI,O,, S O , , microstructure, a Iridium Complexes, Ir(CI)(CO)(Ph,P), , a

Ir/AI,O,, preparation, a 29,

Ni-Cr, Pd, F’t additive effects, a

Palladium, gauze damage, in HNO, reactor, a in combustible gas sensor

modified, 1.3-butadiene diacetoxylation, a Palladium Alloys, Pd-Mn, styrene oxidation, a Palladium Complexes, C-C bond coupling

metallo-ene reactions, a

organo-Sn coupling with vinyl epoxides. a PdBr, -LiBr-MeOH, ethylene oxidation, a PdBr,-P(OPh),-n-BuOH, formation, a

PdCI,(PPh,),, a 139, 146,

PdCl

,

-CuCI

,

-LiCI, ethylene oxidation, a I78 I69 145 222 143 144

88 180 89 30 186 145 146

146 146

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Catalysts (conid.) Page

22 I Pd(dba),:2PPh1, arene-alkene coupling 186 Pd(II), thiophene oxidation, a 146 Pd(lI)+salen, alkyne, hydrogenation, a 89 Pd(OAc),, Pd(PPh,), , vinylation, a I46

Pd,(dba) ,L, arene-alkene reactions I86 phosphine-Pd, fluoro olefin, reactions, a 90 Pd acetate, heterocycle’s formation 186 Pd,Mo/WO

/W,

reaction with N, a 90 Pd, Rh, R u k i O , , D exchange, a 143 PdCI,-CuCI, in SiO,. Wacker process 60 144 Pd(NH,),’ INaY, calcination study, a 219 Pd+La,O,la-AI,O,, cycled NO reduction, a 144 Pd-alizarin cly-Al,O

,,

hydrogenation, a 30 Pd-CelAl,O,, Ce effect on CO oxidation, a 219 Pd-MglX-zeolite, ethylene dimerisation, a 2 19 Pd-B-cyclodedrins, photoreduction of HCO- , a141

Pd/AI,O,, Ce effect on CO oxidation, a 219 HCI effect on activity, a 29 with H absorbed layer, hydrogenations, a 89 S O , , vinylacetylene hydrogenation, a 30 films, CH, oxidation, a 89 PdlC, preparation, surface properties, a 89 PdlCd),, TPD after MeOH, adsorption, a 219 Pd/La,O,, SiO,, La-PdlSiO,, for CO,

hydrogenation, a 30

Pd/SiO,, CO adsorption, Pd size effect, a 219

in H reactor I I8

+MgO, Fe, for CO+H reaction, a 89

PdITiO,, hydrogenation of CO, aldehydes, a 144

Pd/TSVM,/TSVK zeolites, xylene, reactions, a 144

phase-transfer, Pd extraction, a 147

Platinum, black 87, 180

colloidal +polytungstate, a 27 foil, CO+NO, reaction, a 81. 138 modified, 1.3-butadiene diacetoxylation, a 89

0 reduction, a 82

poisoning in PEM fuel cells, a 91

tunnelling, in graphite hydrogenation. a 24 Platinum Alloys, oxidation gauzes 12, 88 Platinum Complexes, H,PtCI,-Ln(NO,),, a 218 H , h C l &-(C &H

j

lN-(i-C,Hq), AIH, a 32 metallo-ene reactions, a I45 PtCI,(PPh,),, Pt(CO),(PPh ,),, iodide

carbonylation, a 145

Pt(lI), Pt(1V) ethyl, decay in iodide

solutions, a 22 I

Pt(phpz), , Pt(phpz)(thpy), luminescence, a 85

[PtH(PEt,),l , H production, a 145 [PI

,

(P, 0 I H ,),

1 ‘-.

photoreactions, a 141 [Pt2(RzS0),X,1, activity, a 32 Platinum Metals, gas turbine emission control 46 Pt clusters, in EDTA/Ru(bpy) MV”. H

photoproduction. a 85

Pt, Pd,

Rh,

Pd-Ag, AI,O,, MeOH exhaust, a 88 Pt, Pd, Rhla-Al,O,, propane, oxidation, a 142 Pt, Pt-Ir/Al,O,, preparation, a 29 Pt, RulPdlVlPdlAl, H oxidation, during

reactor accident, a 86

Pt, -Re, -Re-S/AI,O,, reforming, a 29 Pt,-RhlAl,O,, La doped, exhaust, study. a 218 PTFElR metallsubstrate, isotope exchange, a 30 PtZn,.,,Cd,., S/Cu,S, photocatalysts, a 85 Pt-Crl,Pt-SnlAl,O,

,

n-pentane,

methylcyclopentane conversions, a 29 Pt-CrlSiO,, in H reactor I I8 Pt-impregnated glass membrane,

Pt-Re-Cr/Al,O,,ly-Al2O1,

n-heptane Pd(0). pumiliotoxin synthesis, a

Pd-P(CH,OH),, a 22 1

PdQII), popmerisation, of aldehydes, a

gel, CO hydrogenation, a 144

powder, passivating oxidation, a 88

Pt-P(CH,OHk,, a 22 I

cyclohexane dehydrogenation, a 34

dehydrocyclisation, a 88. 143

Catalysts (conid.)

Pt-RelAl,O,, coked. sulphided, a

Pt-Rh gauzes, in HNO, production, a

Pt-RhlAl , O

,.

gas turbine emission control Pt-SblAl,O,, Pt-Te/Al,O reforming, a

Pt-SnlAl,O,, after redox cycling, a

Pt-TiO,, in H photoreactor, a

Pt-TiO, thin filmslglass, photocatalyst, a

Pt.H-ZSM-S.AI,O,, mass transfer effects, a

PtlAI,O,, CO hydrogenation, pathways, a

coking, a

HCI effect on activity, a

hydrogenation of a-keto esters, a S resistance, hydrogenolysis, a

SiO,, TiO,, C, NMR study, a

S O 2 , passivating oxidation, a

PtlC. deactivation, in oxidation, a

fibre, for C$l hydrogenation, a

PtlCdS, for [Ru’(H-EDTA)N,l-, a surface composites,

photodehydrogenation, a

PtlFecralloy, in CO, TEA lasers

PtlH-ZSM-5 zeolite, olefin hydrogenation, a

PtlKL-zeolite, aromatisation of n-hexane, a

Ptlphotosynthetic membrane, a

Ptlsilicalite, preparation, a

PtlSiO,, sintering, during C,H, oxidation, a

PtlTiO, , acetone hydrogenation, a

photo, in MeOH fuel cell, n

powder, H production, a

Pt/X-zeolite+Re, W, Mo, n-hexane dehydrogenation, a

Ptly-Al,O,, preparation, pH effect, a

RhFelNaY zeolite. structural characterisation. Pt dispersion study, a

Page

88 218 46 143 88

1 40 85

144

142 143 29 218 143 218 88 29 88 216

140 20

144

218 27 89 29 30 33 30

30 142 218

a 220 Rhodium, diacetoxylation of I ,3-butadienc. a 89 Rhodium Complexes, CoRh(C0)

,

.

for fluoro

olefin reactions. a 90

R h -r I promoter, acetyls production I68 RhCI(CO)(PR,),

.

irradiated C-H bond

activation, a 90

RhCI(PMe,), , vinylketones dimerisation. a 22 I RhCl ,/SiO,, nitrobenzene reduction. a 146 RhH(CO)(PPh ,)

,

+laser irradiation.

olefin hydrogenation. a 141, 221 Rh(ll), carbene insertion in 0-lactams. a 148 Rh-, Rh,-(TPPTS), two-phase, alkene Rh(diphos),+, for CO, reduction 2

32 h droformylation, a

RhA(C,Me,)(bpy)”. NAD(P) +

reductions, a - 32

Rh,(CO),,, fluoro olefin

hydroformylation. a 90

[RhCI(COD)I ,/SiO,, nitrobenzene

reduction, a . I46

[RhH(CO)(PPr’,),l, irradiated for H, a 145 2 [Rh(bpy),lCI, H production, a 145 [Rh(CO) ,CI1,

+

phosphanorbornadiene,

Rh(C0) clusters/PS, animated, N - 0 bond Rh+SelZrO,, ethene hydroformylation, a 31 Rh-Felgraphite, surface structure, a 137 Rh-Ptly-Al,O,, preparation, pH effect, a 142 Rh-SnlSiO,

,

ester selective hydrogenation, a 220 220 31 RhlCdS, for

[Ru’

(H-EDTA)N,l-, formation, a 216 RhlMgO, dinitrile hydrogenation, a 31 220 RhlSiO,, C,H, hydroformylation, conditions, a 90 Rhlsupport, L,a,Ol promoted,

CO hydrogenation, a 31

Rh/V,O,, C , - 0 compounds synthesis, a 90 Rhly-Al,O,, preparation, pH effect, a 142

[Rh(bpy)

,X

,

1

-, CO, reduction

hydroformylations, a 22 1

deoxygenation, a 90

RhlAI,O,, CO oxidation, dissociation, a

effect of N O t C O disruption, a

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Catalysts ( c o d . j Page Rh,(CO),,lNaY zeolite, structure, a 220 RuO, +LalZrO,, preparation, stability. a 31 Ruthenium, NH

,

production. from N,

.

a 27 tunnelling. in graphite hydrogenation, a 24 Ruthenium Complexes, cis-[Rulll(L),(OH

? ) , I

+.

HC oxi tion, a 32

hydroformylation. a 90

RuCI,-,RuCI,, norbornadiene, arenes. for vinyl carbamates. a I47 RuH ,(PPh

,

), , aldonolactone synthesis. a 222 Ru(lI1)-EDTA. hydroformylation. a 91 Ru(I1)

+

hypochlorite, a 147 Ru(OAc)CI(PEtPh,)

,

+

Li.

MeOH dehydrogenation, a 32

Ru-Co system, EtOH production, a 32 [ H , R u C I , ( A S P ~ , ) ~ I . oil hydrogenation, a 147 LRu~,(N?)(PPh,),I, H production. a 145 IRu VO(bipy),(ERJ)l~+C, alcohol oxidation. a 26 Ru(bpy), z'lEDTA/MV*

',

Pt clusters.

H photoproduction, a 85

Ru-Co-MnlAl,O,, composite, high calorific fuel production. from syngas: a 145 Ru-Cu/Al,O,, syngas conversion, a 31 MgO, SiO,, propane hydrogenolysis. a 145 Ru-CulSiO,, H, chemisorption, a 31 Ru-PdlSiO,, synergism in C,H,

hydrogenation, a 90

Ru-Sn-BlAI,O,, oleyl alcohol production, a 145 Rulpyrolysed polyacrylonitrile,

CO,CO,, reduction, a 31

RulTiO, powder, H photoproduction, a 141

Cerium, a 143, 218

Cermets, Pt-AI,O, film. spectral selectivity. a 87 Chemisorption, H,, on Ru-Cu/SiO, , a 31 Chlorine, adsorption, on Pt electrode. a I39

Chloroplatinic Acid, a 26

Cholinesterase, activity in human serum, detector. a216

Chromium, dissolution rates, a 26

88. 143 141 Cisplatin, anti-cancer drug therapy I62 Coatings, Cr modified Pt aluminide, a 141 Pd, of stainless steel in nuclear reactors I85

Pt, on steel, slide wear 12

Pt, Pt alloys, for industry. jewellery I02 Pt modified aluminide, on gas turbine blades 127 Rh, thin films, by plasma enhanced CVD I93

Cobalt, dissolution rates, a 26

in ColPt magneto-optics 177, 222 MCo, in Pd coated steel, in reactors I85

Coking, in Pt/AI,O,, a 143

Cold Fusion I14

Colloids, Ir oxide

+

RuO,. a 28 Pd-8-cyclodextrins. HC0,- reduction, a 141 Pt, for H, photoproduction. a 27 Colombia, historical metallurgy 73. 80 Composites, for ORINEL electrodes, a 216

Pd thin filmlporous glass,

water gas shift reaction, a 87. 142 SPE, with Ir, Pt species, H,O electrolysis, a 139 surface layers, Pt, CdS, photocatalytic alcohol

dehydrogenation, a 140

Conferences, 26th Champion Ignition and Engine I05 Chemistry of the Platinum Group Metals,

1990, announcement I16

Electrochemical Society, California, May 1989 I13

Geo-Platinum 87, proceedings 13

Grove Fuel Cell Symp.,

I69 Int. Symp. Metal-Hydrogen Systems, 1988 17 National Fuel Cell Seminar, 1988 10 SAE Int. Congress, Detroit, 1989 61

Copper, electrokss plating, a 86

KIRu

P '

"(EDTA-H)CII .2H,O.

effect on Pt+Re+Cr/y-Al,O,, a modified Pt aluminide coatings on Ni, a

Performance, Munich, 25, 26 April 1989

London, 18-2 1 September 1989

Page Corrosion, CI- adsorption.+H.+H,. on P t ( l l l ) . a 213 hot. of Cr modified

Pt

aluminide coatings, a 141

in Pd-Ag dental alloys, a 35

Pt anodes in H,SO,. a ₈₄

Ti-Pd surfaces, a 82

(TiwRu,o)nSi,J, in saline, a 140

Cracking, isooctane, a 144

Crystallisation, PdSi, PdGe. H dissolved in, a 82 Crystals, cis-RuCI,(DMSO), , a 92

Ln,Ru,,P,,, a I39

quasi. Al-Cu-Ru, a 138

single, Pt(100). Pt(l1 I), MeOH adsorption, a 84 Pt-Ni, surface characterisation, a 24 TiO,. surfaces. Pt thermal deposition on. a 213 [Pt(en),I[Pt(en),CI,1(CIO,),, photo defects, a 27

Cyclic Voltammetry, a 84, 85

22 1 22 1 Cyclohexane, dehydrogenation reactions. a 34. 88. 143

from aromatisation of n-hexane, a 218 Cyclopentane, reactions over Pt, Ir/Al,O,. a 143 144 Dehydrocyclisation, n-heptane, a 88, 143 Dehydrogenation, aqueous alcohols, a I40

cyclohexane, a 34. 88. 143

cyclopentane. a 143

MeOH, a 32. 85

n-hexane, a 30

Deoxygenation, N - 0 bonds, a 90 Detectors, boundary layer measurements, a 142

CO

,

.

portable. cheap 127

fish freshness 23

for H, HC, CO concentrations 180

glucose, a 217

glucose, saccharides, micro-enzyme, a 28. 86

H, a 28, 87. 217

heat transfer probe, for circulating fluidised bed, a2 16

H,S, by Pd gate MOS, a ₂₈

H , O + , by Pt polypyrrole electrode, a 141 in spark ignition engines. book review 105

NH,. a 28. 217

N-acetyl-L-cysteine in H ,0. a 217

0, fast response, a 216

organic gases, with Rh probe, a 142 Pb, Cd, Sn in food slurries 193

proton, a 87

temperature, thin film Rh-Fe. cryogenic use 55

213 exchange reaction with propene, CO effect, a 143 isotopic exchange, on PTFEIPtlsubstrate, a 30 permeation with H, through Pd-Fe, a 25 Diacetoxylation, on Pt, Pd, Rh, a 89 Diesel, engines, pollution control 61 for H production, in Hot SpotTM reactor 118 Diffusion, barrier, Ta,N between Pd,SilAl. a 148 H, D, in Pd, Pd. alloys 17, 58, 82. 137. 213

Si, in Pd,Si, a 214

,

+, dc, a 85 Electrochemistry, a 26, 27, 83. 84, 139, 140, 215, 216 Electrwhromism, in 110, thin films. a 34, 223 Electrodeposition, a 28, 86, 87, 141 86 I02 28 84 83 91, 222 dissolution in H,SO,, a 84

for MeOH oxidation, a 83

in fusion reactions 54

cathodes, Al sheet, Ru(bpy)

,

+ ECL, a 85

1 1 0 H evolution on, a I40

disc, Pt, Rh effects on dissolution rates, a 26

in solid state fusion I14

microplatinised, glucose, saccharide, a 28, 86 micro-, for glucose sensor, a 217 Pt, cylindrical, behaviour, a 216 ORINELs, with Ir oxide, polyaniline, a 216 Pd, Pd-Au, phase changes in hydride formation, a140 Pd, +Cd, TI, cyclic voltammetry, a 84 Pd-Ag, oxidative dimerisation of CH,, a 215 photoanodes, n-GaAs, stabilised with Pt grains. a216 Pt, allylic acetates electroreduction, a I39

EtOH oxidation on, a 83

hydrous oxide formation in acid, a 215

in H sensor, a 217

polyaniline deposition, a I39 Pt-AI surface alloy formation. a 84 glassy C, polypyrrole, for propylene

carbonate oxidation. a 215

metallised thick film, for cholinesterase

activity, u 216

rotating ring disc, 0, reduction on, a 33, 139 Pt phthalocyanine/C, fuel cell, evaluation, a 147 Pt polypyrrole, as H ,O+ sensor, a 141 Pt

+

adatoms, in formic acid fuel cell, a 33 Pt

+

CoTMPPIC, 0 reduction in fuel cell, a 222 Pt(100) electrofaceted, stabilisation in acid, a 84

Pt(100)/Pt foils, a 28

Pt(l I I), Pt(100). MeOH adsorption on, a 84 Pt-Mo-SPE, for MeOH oxidation, a 33, 139 Pt-SPE, H z O electrolysis, a I39 Pt-W bronze, for MeOH oxidation, a 26 33 Pt/Nafion, 0 reduction at, a 26 PtlNi, porous gas diffusion, evaluation, a I47 PtlPA/glassy C, H evolution, a 84 Pt/poly[RuL,Iz +-RuOz, oxidation reactions, a 27

Pt/PTFE, in CO, sensor 127

Pt/Ru. Pt(1V) species, in acid media, a 215 with thin polymeric films, for CO, reduction 2 WPt, WRh, in thermoelectric converter. a 140 Electrolysis, H,O, by Ir, Pt in SPE, a I39 Electronics, Pt, Pd powders for 16

Electroplating, a 28, 86, 102

Emission Control, 1989 SAE Int. Congress, Detroit 61

1992 E.E.C. standards 212

catalysts, book review 105

CeOl effects on, a 143

gas turbines 46

MeOH fuelled vehicles, a 88

motor vehicles, greenhouse effects I 94

print industry drying gas 178

Energy, solar, converter, a 85

Enol Triflates, reaction with alkyl vinyl ethers, a 146

Environment, protection 178, 194

Erythrocytes, detector, a 216

Esters, a _{145, 146, 147, 220}

Electrocatalysis, CO, by thin polymeric films

Pd-Ni alloys, from sulphamates, a

Pt films, from solution, a

Pt microparticles, on PAlglassy C electrodes, a Pt on graphite, STM study, a

Pt. Pt alloys, new baths

Electrodes, anodes, Pt, in MeOH fuel cell, a

Pd,% fusion reactions 54

Pt/C, in SPE. HJPO, fuel cells, a

Engines, combustion, book review I05 design, conference, Munich, 1989 I05

Page

Etching, Pt, a 12. 24

Ethers, oxidation. by Ru(1I) complexes. a 147 220 22 I Ethylene, conversion to CH ,CHO. Wacker process 60

29, 31, 89, 90, 146. 219, 221 Extraction, Pd, by phase-transfer catalysis. a I47

Films, 110,. a 25

Pd/SiO,/Si, H effect, a 87

Pd/MIS, Langmuir- Blodgett. a 87 Pt on polycrystalline Pt foil, for electrodes, a 28 Pt-AI,O, cermet, spectral absorption. a 87

Fischer Tropsch, a 31

Fish, freshness detector 23

Fluoro Amino Acids, synthesis, a 90 Formaldehyde, MeOH fuelled vehicle, a 88 Formamide, intermediate in C 0 2 to CH,, a 222

Formate, production 2, 141

Formic Acid, adsorption, oxidation, a 219

Fuel Cells, a 33, 91, 147. 222

alkaline, PtPc/C. Pt/Ni electrode evaluation. a 147 33 formic acid, with Pt+ad atoms electrodes, a 33 Grove Symp.. London 18-21 September 1989 169

methanol, a 33, 91. 222

National Fuel Cell Seminar, 1988 10

PEM, catalyst poisoning, a 91

phosphoric acid, a 33, 222

review 63, 169

SPE, electrodes, a 33. 222

Fuels, alternative, book review 105 high calorific, synthesis from syngas. a I45 in engines, conference, Munich, 1989 I05 Furnaces, Pd coated, for As, Sb. Se detection, a 142

Fusion, solid state I14

9 Ethyl Acetate, hydrogenation to EtOH. a

Ethyl Acrylate, hydroformylation, a

reactions, a

amorphous Ni alloy catalysts, a

Fusion Reactors, H purification for

Gas Turbine Engines 46.

Gases, organic, sensor for, a

Gasoline, Pb-free, for H production,

Gauzes, catalytic 12. 88.

Generators, H, Hot SpotTM reactor Geology, Geo-Platinum 87. conference report Germanium, Si,Ge,-,, reactions with Pt, a

Glass, porous, Pd, plated composite, a reactions with binary Rh alloys

Vycor membrane, Pt impregnated, reactor, a

Glucose, detectors, a 28, 86,

Gmelin, technology of the platinum group metals Graphite, hydrogenation, by tunnelling catalysts, a

Greenhouse Effect, caused by motor exhausts Grove Fuel Cell Symposium, London

127 I42 I I8 218 I I S 13 213 87 64 34 217 21 24 I94 I69 Halides, organic, photoreactions, a 141

Heavy Water, production. a 30

1-Heptaldehyde, formation, a 91

Heptanal, production, a I45

n-Heptane, dehydrocyclisation, a 88, 143 Heterojunctions, micro, for H production, a 85 n-Hexane, catalytic reactions, a 29, 30, 143, 218

1-Hexene, hydroformy lation, a 91

73 Honeycat@, catalyst used in print industry I78 I18 Hydrazines, voltammetric determinations, a 86 Hydride, measurements, in As, Sb, Se detection, a 142

concentration sensor I80

emission control from gas turbines 46

production, from syngas, a 31

unsaturated, hydrogenation, a 32, 144 Hydrwarboxylation, polybutadiene, styrene, a 146, 22 I 1-Hexane, hydroformylation, a 22 I

History, Pt metallurgy 80

Hot SpotTM Reactor, H generation

(5)

Page Hydrocracking, n-hexane, catalyst selectivity, a 143 Hydroformylation, 1 -hexme, by Ru(I11)-EDTA, a 9 I

alkenes, by Rh, compl es, a 32 ally1 alcohol, by KIRu (EDTA-H)CII.2H2O, a 90 by [Rh(CO),CIl I

+

phosphanorbornadienes, a 221 C,H,. on Rh catalysts, a 31. 90 90 propene, during D exchange reaction, a I43 213 catalytic reactions with CO, a 144, 219 charging in Pd. Pd-Au electrodes, a I40 chemisorbed on Pd/AI,OJ, for hydrogenations, a 89 chemisorption, on Ru-Cu/SiO, , a 31 coadsorption on Pt( I 1 I ) with HCI, a 213

concentration detection I80

detectors, a 28, 87, 214, 217

diffusion 17, 58, 137

diffusion electrodes, in fuel cell, a I47 effect on PdlLB filmlSi MIS devices, a 87 effects, in Pd films/SiO,/Si, optical transport, a 87 in MeOH synthesis, on PdlSiO, +MgO. Fe, a 89

in metals, Int. Symp. 17

in PdGe, PdSi, properties, a 82 isotopes, H, D, H-D. permeability, a 25 isotopic exchange, PTFElPtlsubstrate catalyst. a 30 oxidation, on sulphurised Pt, electrochemistry, a 139 Pd-Ce-H solid solutions, properties, a 82 permeation in Pd, C, S, effects on, a 2 I4

with D, through PdlFe 25

photoproduction, a 27. 85. 140, 141 production, by Hot SpotTM reactor 1 I8 from aqueous solutions, over Pt/TiO,, a 30 from EtOH, by Ru, Rh, complexes, a 145 from MeOH, in fuel cell, a 33 from PtIPAIC electrodes, a 84

from waste MeOH 58

in water gas shift reaction, a 90, 142

on IrO, cathodes, a 1 40

purification, by Pd-Ag 9, 58

220 reduction, on RuO, +La/ZrO,. a 31 removal from nuclear accidents, a 86 response, by microionic insertion sensor, a 87 separation, from N,. CO. by Pdlporous glass, a 87 solubility, in Pd-Rare Earth alloys, a 82, 214 uptake in Pd-Mg sandwiches, a 214 Hydrogen Chloride, a 29, 213

Hydrogen Sulphide, a 28. 85

Hydrogenation, I , 3-butadiene, a 29

acetone, a 30

alkynes, alkenes, a 89

a-keto esters, a 218

benzene, on Ru-PdlSiO, , synergism, a 90 CO, for Rh, RhFe zeolite structure, a 220 on Pt, Pd, Rh catalysts, a 31, 88. 142. 144, aldehydes, unsaturated HC. on PtlTiO, , a 90 CO,. on PdlLa20J, ISiO,, La-PdlSiO,, a 30 C z H 2 , C 2 H , , on H on PdlAI,O,, a 89 C,H,, by Pt(1I) ethyl complexes, a 22 1

dinitriles, on Rh/MgO. a 31

ethyl acetate, to EtOH, on Rh-SnlSiO,. a 220 graphite, by tunnelling catalysts, a 24

jojoba, castor oils, a 147

methyl oleate, a I45

olefins, a 25, 141, 220, 221

thiophene, by Pd-alizarin cly-Al,03, a 30

unsaturated hydrocarbons, a 32

vinylacetylene, a 30

Hydrogenolyses, a 143, 145

Hydroisomerisation, olefins, branched chain, a 144

Hydronium, ion, sensor, a 141

Inquartation, historical method of separating Pt 73 Iodides, organic. carbonylation, a I45 Ion Beam Bombardment, Pt( I 1 I ) surfaces, a 137

fir

fluoro olefins, by Rh,(CO) 11, a

Hydrogen, adsorption in Pd, a

reaction with CO

+

benzyl halide, a

Page Iridium, density, crystallographic data 14 in SPE, for H I O electrolysis, a 139 35 Ir(1V) hydroxide, thermal change to IrO,, a 138 Ir-Ta buffer layer, in Y-Ba-Cu-0 thin films, a 92 Iridium Alloys, Iridium-Palladium, a 217 Iridium Complexes, carbenes, book review 1 I7 [IrCI(CO),LI, liquid crystals, a 83 Iridium Oxides, colloid, stabilised, a 28 electrochromic films, a 34, 223

in ORINEL electrodes, a 216

IrO, films, for electrodes, a 25

powder, formation, a I38

I r O ~ / A I ~ O J , resistors, a 35

110,. cathodes, evolution. a 140

35 Iron, qromoter, to PdlSiO, catalyst, a 89

Isomerisation, a 32, 88, 143, 144

Isooetane, cracking, catalyst intercrystalline effect, a 144 Isopropyl Alcohol, from acetone, on PtlTiO,, a 30 ITS-90, new temperature measurement scale I28 Johnson Matthey, HoneycatR industrial catalyst 178 Hot SpotTM Reactor H generation I I8

“Platinum 1989” 1 I3

Jojoba Oil, hydrogenation, by Ru complex, a 147 KELEX 100, for Pd extraction, a 147

Ketones, production, a 32, 147

P-Lactams, synthesis, a 148

Langmuir-Blodgett Films, in Pd/MIS devices, a 87

Lanthanum, a 30. 31, 218

20 for irradiating RhH(CO)(PPh,), catalyst. a 141, 221 for measuring luminescence decay, a 27

used in CVD of Pt, a 27

Lead, detection in food slurries 193 Lewis Acid, base titration. of Pd, Nb, a 84 Luminescence, in Ru, Pt complexes. a 27, 28, 85

Magnesium, a 89, 214

Magnetism, Dy I Ru Ip P

I,,

a _I39

in PtlCo, Pd/Co films, for magneto-optics, a 222

PtMnSb films, a 223

Pt-Fe-B, a 24

Ru-Fe-Ga-Si, films, a 25

I77

in PtMnSb 54, 148

in PtlCo, Pd/Co ultrathin films, a 222 35, 92. 148, 223

anti-cancer drug therapies I62

detectors, a 216, 217

Membranes, catalysts, a 142, 219

Metallo-Ene, reactions in organic synthesis. a 145

Metallurgy, history 73. 80

Methane, a 31, 89, 214, 215, 222

Methanol, see Alcohols, methyl

Methyl Oleate, hydrogenation, a 145 Methylcylopentane, conversion on Pt catalysts, a 29 Mineralogy, Geo-Platinum 87, conference report I3

Molybdenum, a 30, 139. 217

MOSFET, with Pd-Ir gate, for NHJ detection, a 217

Naphtha, reforming, a 29

Nickel, dissolving rates, a 26

Nickel Alloys, amorphous catal$p, in fuel cells, a 33 Nicotinamide, reduction. by Rh

+

Na fonnate. a 32 Nitric Acid, catalyst gauze studies, a 88. 218 Nltrobenzene, reduction, by Rh complexes, a 146 Nitrogen, implanted in PtTil, PdTilsteel, wear, a 81 27 90 89 Ir tin oxide, in optical attenuator, a

in an optical attenuator, a

Lasers, CO, TEA, PtlFecralloy catalyst in

Magneto-Optics, ColPt layers for storage media Medical, a

N-0 bonds, deoxygenation. a 90

(6)

Page Nitrogen Oxides, exhaust control, greenhouse effect 194 82 cycled reduction on automotive Pd catalyst, a144 effect on CO disruption of RhlAI,O,, a 31 81, 138

Nuclear Fuel, a 28. 86, 91

Nuclear Fusion, see Solid State Fusion 54 Nuclear Reactors, Pd coated steel 185 Nucleic Acid, reactions with Ru ion complexes, a 26 N-Acetyl-L-Cysteine, determination in water, a 2 17 Olefins, hydrogenations, a 25, 90, 141, 144, 220, 221 22 I Organic Synthesis, using Pd complex catalysts 145. 186 Organostannanes, coupling with vinyl epoxides, a 146 Osmium, density, crystallographic data 14 Osmium Complexes, IosII(N-N)(L), I “ + ,

[Osl’(N-N),(L~(L’)lRe, preparation, properties, a 83

Osmium Tetroxlde 138, 181

Oxidation, alcohols, by Ru(1V)-0x0 phosphine. a 26 alkanes, by alkylhydroperoxides +Ru, a 32 ethers, by Ru(I1) complexes, a I47 benzyl alcohol, by Pt/poly[RuL, l’+-RuO,, a 27 butane, by Pt black-MO,, a 87

CO, a 137, 219, 220

33 ethylene, in PdCI,-CuCI, systems, a 146 PtlSiO sintering during, a 29

EtOH, on Pt electrodes, a 83

formaldehyde, for exhaust catalyst, a 88 H, on sulphurised Pt, electrochemistry. a I39 MeOH, at Mo-Pt-SPE electrodes, a 33, 139 26. 83, 84 91 methane, deep, on Pd/AI,O,, a 89 products of gas turbine engines 46 propane, propylene, on Pt, Pd, Rhla-AlzO,, a 142 222 propylene carbonate, on electrodes, a 215 Pt in catalysts, passivation. a 88 Rh. I r o n SiO,, A1,Oj, microstructure. a 145

styrene, on Pd-Mn, a 30

thiophene, by Pd(I1) complexes, a 146 181 137

deactivation of PtlC, a 29

reduction, on fuel cell electrodes, a 33, 147 26, 83. 139 sensor, with SPE+Pt black electrode, a 216 Palladium, additives, effects on Ni-Cr catalysts, a 144 black, reactions with Pt chloro complexes, a 27 coating in furnace, for As, Sb, Se detection, a 142 coatings, of steel in nuclear reactors 185 complexes, compounds, for organic syntheses 186 compounds, Pd-Er, H solubility, a 214 electrode. catalytic behaviour, +Cd, TI, a 84

electroplating bath, a 86

extraction, by phase-transfer catalysis, a 147 91 films, in SiO,/Si, H effect, properties, a 87 gate layers, in microionic H insenion sensor, a 87

gate MOS transistor, a 28

Ge/Pd electrical contacts to n-AIGaAs, a 148 H permeation through, C, S effects on, a 214 hydride formation, from H, D adsorption, a 213

in electrodes. a 1 40

in PH 13-8 Mo stainless steel, structure, a 82

in sensors, a 87, 214, 217

modifier, to detect Pb, Sn, Cd in food slurries 193 Pd gates/LB filrn/Si MIS devices, a 87 Pd(l lo), D adsorption, phases, a 213 Pd(l 1 I ) , H diffusion. a I37 MeOH decomposition on, a 214 Pd(II), complexation with macrocyclic ligand, a 2 15

NO, adsorption on Rh(100). a NO,, reduction by CO, on Pt foil, a

for aldehyde synthesis, a

C L - , in fuel cell, a

at Pt electrodes, a

on Pt bimetalliclC in fuel cell, a

propylene. in phosphoric acid fuel cell, a

Oxidations, using OsO,, Ru oxides Oxygen, adsorption, on Pt( 110). a

on Pt electrodes, a

from spent nuclear fuel, a

Palladium (conrd. ) Page

Pd-Fe-Zr, phase studies, a 25

Pd-Mg sandwiches, H uptake in, a 214

Pd-n-GaAs, contacts, a 92

Pd-Se system, superconductivity in, a 92 222 Pd/Fe, H-D permeation through, a 25 PdlInP(1 lo), Schottky barrier formation. a 92 Pdln-InP, MOS, barrier height, a 223 Pdlporous glass, for H separation, a 87 Pd’+lpoly(acrylic acid) film, for Cu plating, a 86 Pd,SilTa,NlAl, diffusion barrier, a 148 PdraTi,, films, implanted in stainless steel, a 81 powder production, for electronics 16 selective deposition on polyimide, by Ar laser. a 86 thin films, on Al surfaces, reactions, a 81 thin filmlglass, water gas shift reaction, a 87. 142 used in solid state fusion I I5 +hydroxylamine hydrochloride, for Mo, a 217 Palladium Alloys, Palladium-Cerium-Hydrogen, a 82 Palladium-Gold, electrodes, a 1 40 -Rhodium, short-range order in, a 24 Palladium-Iridium, for NH, sensor, a 217 Palladium-Nickel, electrodeposited, a 86

electrodes, a 215

membranes, for H, purification 9 , 58

Palladium-Titanium, a 82, 84

Palladium-Yttrium, H solubility in, a 82 Pd-Rare Earth, H solubility,

thermodynamics, a 214

Pd-(B,P), thin films, olefin hydrogenation, a 25 Pd,,Ge,,,Pd.,,Si,,, H in, properties, a 82 Palladium Chlonde, PdCI, , MgCl, , complexes, a 26 to measure N-acetyl-L-cysteine in water, a 217 Palladium Complexes, in PdC12-MgCI, solution, a 26

organo-Pd, cationic, a 83

Pd(I1) carbenes, book review I I7 Palladium Hydride, formation, a 213

Palladium Silicides, a 214. 219

Paraffins, a 90

n-Pentane, reactions on Pt-XIAI,O,, a 29, 88 Permeability, H, D, through Pd, a 9. 25, 87, 142

H

separation, a 87

Pt electrolytes, a 28

I02 selective of Pd on polyimide by Ar laser, a I13

“Platinum 1989” 86

Platinum, additives, effects on Ni-Cr catalysts, a 144 amorphous phases with Al, a 24 anodes, corrosion in H,SO,, a 84

for MeOH oxidation, a 83

anti-cancer drugs I62

Bi,- ,Pb,Pt,-,RurOI

-,.

conductivity, a 223 black, electrode, in SPE 0 sensor, a 216 compounds, PtMnSb films, bulk, for

magneto-optics 54. 148

81 215 PdlCo ultrathin films, magneto-optics, a

Palladium-Silver, dental alloys, a 35

Pt. Pt alloys, new baths

(7)

Platinum (conrd.) Page Co/Pt layers, for magneto-optics 177, 222 crystallites, for 0 reduction, a 83

CVD, thin films, a 27

deposition of polyaniline, electrochemically, a I39 eletrodeposited, on graphite,

STM

studies, a 83 electrodes, as hydronium sensor, a 141 for cholinesterase, erythrocyte activity, a 216

for EtOH oxidation, a 83

for 0 reduction in saline, a I39 for propylene carbonate oxidation, a 215 in fuel cells, a 33. 147, 222

in sensors, a 141. 217

R(ll I), Pt(100) single crystals, a 84 h-Al surface alloy formation, a 84 PtIPAlC, H evolution, MeOH oxidation, a 84 WPt, WRh in thermoelectric converter 140 (100)-type, stabilisation in acid, a 84 foils, films, catalytic etching, a 24 gates in MOS gas detectors, a 28 grains, to stabilise n-GaAs photoanodes, a 2 16 HCHO-Pt-H,SO,, for hydrazine

determinations, a 86

heat probe, for circulating fluidised bed, a 216 in cermets, optical absorption, a 87 in electrodes, SPE, for

H 2 0

electrolysis, a 139 in low resistance electrical contacts, a 223

in spark plugs I05

microelectrodes, cylindrical, behaviour, a 2 16 on electrodes, in CO, sensor I27 particles deposition, on TiO, crystal surfaces, a 213 photodeposition, from hexachloroplatinate ion, a 27

plating 28, 102

powder production, for electronics 16 PtMnSb thin films, magnetic properties, a 223 Pt(ll0). CO, 0 adsorption, CO oxidation, a 137 Pt(l I I), deposition, characterisation, a I37 HCI, adsorption on, +H, +H,O, a 213 hydrogenation of I ,3-butadiene on, a 29 81 Pt(II), complexation with macrocyclic ligand, a 215 Pt(1V) species, on PtlRu electrodes, a 215 Pt-C stretch mode in Pt{ 1 1 I}-CO spectra, a 24 PtlCo ultrathin films, magneto-optics, a 177, 222 PtlGaAs, interfacial reactions, a I47 Ptl(l I I)Si, thickness effect on silicide, a 213 S adsorbed, H response, a I39 Schottky contacts, production, properties, a 223 sponge, reaction with alkali hydrides, a 26 substrates for ErBaCuO superconductors, a 34 Tennant, Wollaston, partnership, history 129 thermal reactions with Si,Ge,-,, a 213 thin coating on steel, slide wear 72 thin film deposition, for electrodes, a 28 used in solid state fusion 115 +SnO,/Si wafers, H sensing properties, a 217 Platinum-Aluminium, surface alloy on Pt

84 Platinum-Boron-Iron, magnetic properties, a 24 Platinum-Iron, martensitic transformation. in, a 8 I Platinum-Nickel, single crystals, a 24

Platinum-Rhodium, a 137, 142

Platinum-RhodiumlSiO,, heat treated, a I37 Pt50Ti50 films, implanted in stainless steel, a 81 UPt,-B, superconductor T, enhancement, a 91 Platinum Aluminide, coatings for gas turbine blades 127 C r modified, coatings on superalloys, a 141

Platinum Chloride, PtCI,, a 26

35 S/Pt( 1 I I). CO adsorption on, a

wire wedge bonding, a 34

Platinum Alloys, plating baths I02

electrode in AI,Br, solution, a

Platinum Complexes, antitumour tests, a

A,PtH,, structure, a 26

bis(Pt) with diammines, affinity for DNA, a 35

carbenes. book review 1 I7

cis-diammine Pt greens, one-pot synthesis, a 148 cis-diamminedichloro-Pt(I1). a I48

Platinum Complexes (conid.) Page

cis-dichloroethylene-diamine-Pt(II), a 148 35 K,PtCI , reactions with Pd black, a 27 Pt ethyrenediamine single crystals, defect states, a 27 Pt(II), reaction with PtCl,, H,PtCI,, a 26 83 trans-lh(PMe,)CI,(NH,)l, in 0-cyclodextrin, a 25 1 I6 use in spark ignition engines, book review 105

with H, Int. Symp. 17

34, 91, 213, 223 28 91 142. 144 194, 212

88

from gas turbine engines 46

H burning after reactor accident, a 86 motor vehicle exhausts, greenhouse effects 143, 194

print industry drying gas 178

SAE Int. Congress, Detroit, 1989 61 139

144 Potassium, adsorption on Rh(100). a 82 Powders, 110,. Ir(1V) hydroxide thermolysis, a 138

Pt, Pd production 16

RulTiO,, for H photoproduction, a 141 Printing Industry, catalytic cleanup of gases 178 Promoters, CeO,, in three-way catalysts, a 143 30, 89 31 30 31 90 Propane, catalytic reactions, a 142, 145 Propene, exchange reaction with D, CO effect, a 143

Propylene, a 142, 222

Propylene Carbonate, a 215

Proton, detector, by Pd gate MIS Schottky diodes, a 87 K2PtCI,, binding to metallothioneins, a

sorption on ZrO, , a

Platinum Metals, conference announcement Platinum Silicides, a

Plutonium, analysis in nuclear fuel, a Poisoning, Pt catalyst, in fuel cell, a

self, in catalysts, by 0, HC, a Pollution Control, E.E.C. laws

catalysts in MeOH fuelled vehicles, a

Polyaniline, deposition, on Pt, a

Polybutadiene, hydrocarboxylation, a 22 I Polymerisation, aldehydes, on Pd(III), a

Cr, in Pt-Rely-Al,O,, a 88

Fe, MgO, La, in PdlSiO, catalysts, a La,O

,,

in

Rh

catalysts, a

Mo, Re, W , in PtlX-zeolite catalysts, a Se, in Rh/ZrO, catalysts, a

VOCI,.5HI0, in Rh/SiO, catalyst, a

Pumiliotoxin, synthesis, a 22 I

Redox, cycling, for catalyst characterisation, a 88 Reduction, bicarbonate, photocatalytically, a 141 Carbon oxides, on Rulpyrolysed polyacrylonitrile. a3 1

H,, on RuO,+La/ZrO,, a 31

Ir, Rh on A1,O1, microstructure, a I45 nitrobenzene, by Rh

complexeslSi0,. a 146

144 0, on Pt, a 26, 33, 83, 139, 147 21

Reforming, a 29, 143

Resistance Thermometers, Pt, use in new ITS-90

temperature scale 55, 128

Resistors, thick film, a 35, 92

Rhenium, promoter, in PtlX-zeolite catalyst, a 30 Rhodium, compounds, Pt-Rh clusters, NMR, a 81 215 in electrode, in AMTEC, a I40

in organic gas sensor, a I42

Rh(100), adsorption of K and NO, a 82 RhlTiO, system, for H sensor, a 217 thin film coatings, by plasma enhanced CVD 193 64 Rhodium-Gold-Palladium, short-range order, a 24 Rhodium-Niobium, thermodynamic stability, a 84 Rhodium-Platinum, (4 10) interactions, a 137 Rhodium-PlatinumlSiO, , microstructure, a 137 Rhodium-Titanium, thermodynamic stability, a 84 Rhodium Complexes, carbenes, book review 1 I7 Rh(phen),phi I+, DNA shape targeting, a 223

CO,, electrocatalytically 2

NO, cycled on Pd

+

La, 0

,

la-Al 0

,

, a

Refining, platinum metals, in Gmelin

Rh,(CO),,, on graphite, structure, a

Rhodium Alloys, binary, mechanical properties

(8)

Page Ruthenium, Bi2-~Pb,Ptl-,Rux0, a 223 Dy,Ru,,P,,, preparation, structure, a 139 Pb,Ru,O, +Ti oxide, in resistors, a 35 URu I Si

,

, compression, a 25

in fish freshness detector 23

isotopes, for spent nuclear fuel analysis, a 28 Ruthenium Alloys, Ruthenium-Aluminium, a 25 Ruthenium-Aluminium-Copper, a I38 Ruthenium-Gallium-Iron-Silicon, a 25 106 (Ti?,Ru,,),,Si I j , amorphous, corrosion, a 140

Ruthenium Complexes, bathophenanthroline-Ru(II), non-radioactive labels, for oligonucleotides, a 92

binding to DNA, a 92, 148

K,IRu(H,O)CI,l. spectroscopic properties, a 35

0x0. for oxidations 181

ruthenocenoylester, organ distribution, a I48 RuX,(DMSO), , synthesis, cancer activity. a 92 Ru(bpy)

’

+, luminescence, a 27, 85 Rul(CnHlnt ,),bpyl,, redox potentials, a 85 Ru” reactions with nucleic bases, a 26

IRu(bpy),I(BF,),lCH,CN. a 91

[Ruppy)

1

*+/C,V’+, photocurrents, a 86

IRu (H-EDTA)N,l-, a 216

[(bpy),Ru(b-b)Ru(biq),l‘+ , luminescence, a 28 Ruthenium Oxides, RuO,. thermodynamics, a 215 thick film resistors, a 35. 92 colloids, stabilised in polyelectrolyte, a 28 RuO,, Ru(VI1) ions, Ru(V1) ions, oxidants 181 compounds, Bi,Ru,O,, resistors, a 35

with Ti aluminides, structure, properties

Saccharides, detection, a 28

Schottky Barrier Devices, n-Si/Pd, Si/Ta,N/AI, a 148 Schottkv Barrier Transistors. PMOS. with PtSi. a

~~.

~ ~~ ~ ~~~~~~ 223

Ghottky Barriers, formation.. a 92

Schottky Contacts, Pt, F’tSi,, production. a 223 Schottky Diodes, proton detection, a 34. 87. 91

Selenium, a 31, 142

Semiconductors, MOS Pd gate, a 28 MOS Pt gate, as H,. NH, detectors. a 28

Pd films/SiO,/Si, a 87

Pd-MIS Schottky diodes, for proton detection, a 87 Pd/n-lnP, barrier height, a 223

PMOS, with PtSi, a 223

Si MISlLB filmslPd, a 87

SilSiO,. in H microionic insertion sens0r.a 87 +microheterojunctions, photocatalyst, a 85 Sensors, see Detectors

Silicon, a 213, 214

Sintering, PtlSiO,, during C,H, oxidation, a 29

SMSI, a 30, 218

sodium, effect on Pd, Rh, Ru/SiO,

.

a 143

Solid State Fusion I14

Solubility, H, in metals 17, 82. 214 see also Diffusion, Permeability

Solvent Extraction, reprocessing of Pd. a 91

Spark Plugs I05

Standard, frequency, using OsO, beam, a I38 Steam, effect on coking on Pt/AI 0 j , a I43

Steels, a 72, 81, 82. 185

Structure, I ,3-bridged 8-lactams. a I48

Al-Cu-Ru alloys. a I38

Dy,Ru,,P,,. a I39

Ir oxide films, a 25

micro, Rh, Ir particles on S O , . A1,Oj. a 145 137 81 PtlGaAs, during interfacial reactions, a I47

Ru-Ti aluminides 106

surface. Fe-Rhlgraphite catalyst particles, a 137

Styrene, a 30, 146. 221

Sulphides, ions, for H photoproduction, a 85 Sulphur, effect on H-Pd permeation, a 214

effects on Pt, a 81. 139, 143

Sulphuric Acid, corrosion of Pt anodes. a 84 Pt-Rh particles on SiO,, heat treated, a Pt-Fe alloys, martensite transformations. a

Page

Superalloys, coated 127, 141

Superconductivity, a 34, 91, 92

Surface Science, Pt(l I I ) single crystals. a 137

Pt-Ni, a 24

Fe-Rhlgraphite catalyst particles, a I37 110, formation, structure, a 138 h-Rh(410) single crystals, interactions, a 137 90 Synthesis

Gas,

conversions, a 31, 32, 90, 91, 145

Tellurium, a 84, 143

Temperature Measurement, 0.01 -800K. by

Rh-Fe sensor 55

ITS-90 128

Tennant, Smithson, history 129

Thermodynamics, Pd-Rare Earth-H systems, a 214

RuO,. a 215

Synergism, in Ru-PdlSiO, catalysts, a

Thermomagneto-Optics, ColPt, for storage media Thick Films, cholinesterase activity, a

Thin Films, uRh,As on GaAs(001). growth, a 177 216

resistors, a 35, 92

34 Ir oxide, electrochromism, a 223 Pd. H, D adsorption in, a 213 81 Pd-(B,P) heat treated, olefin, hydrogenation, a 25 PdlCo, PtlCo, magneto-optics, a 177, 222 Pdlglass composite, water gas shift reaction, a 142

Pt, catalytic etching, a 24

in heat probe, a 216

produced by CVD, a 27

thermal reactions with Si,Ge,-,. a 213

PtMnSb 54. 223

PtSi. incoherent light annealed, a 91 PtTi, PdTi, on steel, wear, a 81

Pt-AI, amorphous phases, a 24

Pt-TiO,/glass, photocatalysts, a 85

Pt/( I 1 I)Si, silicide formation, a 213 Rh. deposition by plasma enhanced CVD I93 SnO,, +Pt/Si wafers, for H sensor, a 217 Y-Ba-Cu-0, with Ta-lr sandwich, a 92

Thiophnne, production, a 30

Thiophene, reactions, a 30, 146

Tin, detection in food slurries I93

Tin Oxide, a 214. 217

Titanium, TiO, crystal surfaces, Pt deposition, a 213

Titanium Alloys, Pd plated, a 82

Titanium Aluminides, alloy with Ru 106

Tungsten, a 30, 140

Tunnelling, of Pt, Ru. Ni, a 24 Uranium, URu,Si,, compression, a 25 Vinyl Carbamates, synthesis. a I47 Vinyl Epoxides, alkylations, a 146. 221 Vinylacetylene, hydrogenation, a 30 Vinylation, alkyl vinyl ethers. a 146 Vinylketones, dimerisation, by RhCI(PMe,), , a 221

Voltammetry, of hydrazines, a 86

on AI(I 1 I ) , Al(110). reactions, a

Rh-Fe temperature sensor 55

Toluene, irradiated carbony!ation. a 90

Wacker Process, catalyst for 60

Water, coadsorption on Pt( I 1 I ) with HCI; a 213 determination of N-acetyl-L-cysteine in. a 2 17 electrolysis, by Ir. Pt SPE. a 139

M L

determination in. a 217

photolysis, with Pt-TiO, powders. a 1 40 Water Gas Shift Reaction, a 90. 142, 145 Wear, behaviour of Pt on steel 72 81

Wires, Pt. a 34. 142

Wollaston, William Hyde. history I29 Pt, Pd alloy films on stainless steels, a