SUBJECT INDEX TO VOLUME 50
Page Page
a= abstract
Acetic Acid,from syngas, a 209
Acetylenes,hydrogenation, selective 156
polymerisation, a 210
ADMET,production of specialty polymers 81
Alcohols,aryl, coupling, of amines, a 106
benzyl, oxidation, a 106
cyclohexanol, oxidation, a 106
EtOH, from Fischer-Tropsch reaction 22
MeOH, electrooxidation, a 107, 153
fuel, for fuel cells 38
oxidation, a 210
reforming 22
sensor, a 152
oxidation, aerobic, a 153, 209
Aldehydes,aromatic, oxidation, a 106
Alkanes,oxidation, partial, a 106
propane, dehydrogenation 22
Alkenes,metathesis 35
Alkylation,asymmetric allylic, a 48
Alkynes,addition, to cyclopropenes, a 106
cyclisation 171
hydrogenation 22, 194
Amination,aryl, in sc-CO2, a 48
Buchwald-Hartwig, a 49
Amines,coupling, of aryl alcohols, aryl halides, a 106
oxidation, aerobic, a 209
Aniline,oxidation, by PtCl62–, a 151 Aromatisation,pyrolysis gasoline 194
Aryl Halides,in reactions, a 48, 106, 153 N-Arylation,N-silyl derivatives, a 48
Arylboronic Acids,Suzuki-Miyaura couplings, a 153
Biaryls,by Suzuki coupling, a 106
Biomolecules,sensor, a 105
Book Reviews,“Electrodeposition of the Precious Metals” 67
“Principles of Fuel Cells” 200
“Ruthenium in Organic Synthesis” 95
“Supported Metals in Catalysis” 20
Brazil,PGEs, geology 13, 134
Buchwald-Hartwig Couplings,microwave-assisted, a 49
Bushveld Complex 130, 134
Cancer,anti-, Pt complexes, a 49
Ru-pac complexes 2
Capacitors,RuO2/TiO2nanorods, a 208 Carbenes 35, 48, 104, 150, 153, 171, 209
Carbocycles,synthesis, through metathesis 81
Carbon Oxides, CO,hydrogenation, a 209
oxidation 22, 106, 152, 177
selective 22, 48, 152, 194
as probe for Pt 21
tolerance, of PEMFC anodes 200
CO2,reduction, Ru catalysis 95
supercritical, solvent, a 48
tolerance, of PEMFC anodes 200
Carbonylation,Ru catalysis 95
Carbonyls,reduction, to alcohols, a 209
Carboxylic Acids,formic, oxidation, a 48
Catalysis,asymmetric 54, 107
book reviews 20, 95
conferences 22, 64, 177, 194
François Gault Lectureship, Johnson Matthey Award 22
fundamental studies; theoretical methods 22
heterogeneous, a 48, 105–106, 152, 209
homogeneous, a 48–49, 106–107, 153, 209–210
metathesis reactions, 2005 Nobel Prize for Chemistry 35
by supported metals 20
Catalysts,activity, test: microreactor; pilot plant 52
book reviews 20, 95
conferences 22, 64, 177, 194
contaminant levels 52
Catalysts, (cont.)
deactivation, in catalyst design 22
electrochemical promotion 22
improving service life 52
N2O greenhouse gas abatement 103
poisons, Hg, removal 156
S species 110
recycling, a 48, 106, 153, 209
S additions, activity control 110
supported, application, characterisation, preparation 20
three-way, see Three-Way Catalysts
Catalysts, Iridium,Co/alumina, + Ir, Fischer-Tropsch 22
electrocatalysts, PtIrCo, for PEMFCs 202
Catalysts, Iridium Complexes,Ir phosphine,
cyclisation of alkynes 171
[Ir(COE)2Cl]2/dppe, methyl oleate hydroboration, a 210
Ir(III) N-heterocyclic carbene, H transfer reduction 171
Catalysts, Palladium,Au-Pd, oxidation of CO, + H2 194
synthesis of H2O2 194
AuPtPd/SiO2-Al2O3, naphthalene hydrogenation, a 152
coupling of aryl alcohols, aryl halides, + amines, a 106
electrocatalysts, Pd-Co, Pd-Cr, Pd-Ni, for DMFCs, a 107
Pd, addition, TiO2, degradation of organics 22
+ Ag, hydrogenation of acetylene 194
CH4combustion 64
foil, pentyne hydrogenation 22
for motorcycles, a 105
oxidative reactions, diesel, gasoline 64
S-poisoned, regeneration, for CH4combustion 177
surfaces, pentyne hydrogenation 22
Pd + Au/alumina (from Ni3Al (111) single crystal) 22
Pd monolith + Pt/Rh/Ce monolith TWC 177
Pd nanoparticles-polymer, fine chemicals synthesis 22
Pd shell-Ni core/MgO, butadiene hydrogenation 22
CO oxidation 22
Pd(111), single crystal, pentyne hydrogenation 22
Pd/Al2O3, CH4combustion 64
Pd/γ-Al2O3, hydrogenation of sunflower oil, a 152
Pd/γ-Al2O3on metallic foams, washcoating method, a 106
Pd/Al2O3/metal foil, CH4combustion 22
Pd/Al18B4O33, CH4combustion 64
Pd/alumina, Hg posioning 156
hydrogenation of acetylenes 156
hydrogenation of dibenzothiophenes 22
pentyne hydrogenation 22
Pd/C, hydrogenation of alkynes 194
Pd/C/asymmetric α-Al2O3membrane, H2O2synthesis 22
Pd/C-coated monoliths, combustion of xylenes, a 209
Pd/polymer fibres, hydrogenation of sterols, a 106
Pd/TiO2, nitrate hydrogenation 22
Pd/TiO2(P25), reforming MeOH, using UV 22
Pd-TiO2film, oxidation of formic acid, a 48
Pd/zeolite, matairesinol production 22
Pd-Cu/γ-Al2O3, NO3– reduction, a 152
Pd-Mn/Al2O3/metal foil, CH4combustion 22
Pd-Pt, CH4combustion 64
diesel oxidation 177
S-poisoned, regeneration, for CH4combustion 177
Pd-Pt/alumina, hydrogenation of dibenzothiophenes 22
Pd-Pt/Ce-ZrO2, CH4combustion 64
PdPt nanoparticles-, PdZn nanoparticles-polymer 22
PdO/Al2O3, CH4combustion 64
Pt-Pd/Al2O3, CH4combustion 64
PtPd/C MWNTs, naphthalene hydrogenation, a 152
PtPd/SiO2-Al2O3, naphthalene hydrogenation, a 152
Catalysts, Palladium Complexes,Pd, Suzuki couplings,
microwave-promoted, a 209
Pd carbenes + poly(2-oxazoline)s, couplings, in H2O, a 48
Pd enolates, chiral, enantioselective fluorination, a 210
Pd(II) + N ligands/SiO2, Suzuki couplings, a 48
Pd2dba3+ X-Phos, amination reactions, in sc-CO2, a 48
Catalysts, Palladium Complexes, (cont.) [Pd(η3-C
3H5)Cl]2+ chiral fluorous aminophosphine,
asymmetric allylic alkylation, a 48
PdCl2+ PEPPSI-IPr, Negishi reaction, a 209
Pd(DPPF)Cl2, Suzuki coupling, aryl bromides, a 106
Pd(OAc)2+ 2-(di-t-butylphosphanyl)biphenyl, a 49
Pd(OAc)2+ 2-(dicyclohexylphosphanyl)biphenyl, a 49
Pd(OAc)2+ imidazolium salt, SM couplings, a 153
Pd(OAc)2/DMSO + MS3A, alcohol oxidation, a 153
Pd(OAc)2/[(Me)3PH]BF4/Et3N, addition of alkynes, a 106
Pd(OAc)2/P(OCH3)3, Heck coupling, a 48
Pd(OAc)2/pyridine + MS3A, alcohol oxidation, a 153
Pd–phosphine, addition of alkynes, a 106
Catalysts, Platinum,AuPtPd/SiO2-Al2O3,
naphthalene hydrogenation, a 152
BaO/Pt(111), NOx storage 177
CeO2-encapsulated Pt, -encapsulated Pt/Au, WGSR 21
Co/alumina, + Pt, Fischer-Tropsch reaction 22
electrocatalysts, Au/Pt, anodes, for AFCs 38
Pt, for fuel cells 38, 107, 200
polycrystalline, electrode, MeOH oxidation, a 107
porous, electrode, for nano fuel cells, a 107
Pt black layer, MEA, for PEMFCs, a 210
Pt nanoparticles, MeOH oxidation, a 210
Pt nanoparticles/Nafion, for PEMFCs, a 49
Pt/C, cathodes, for AFCs 38
MEA, for fuel cells, a 210
for PEMFCs 49, 202
Pt/C black, cathodes, for PEFCs, a 210
Pt/C cloths, cathodes, for DMFCs, a 49
Pt/SWCNTs, cathodes, for DMFCs, PEMFCs, a 107
Pt/Vulcan XC 72, thermal stability, a 153
Pt/Vulcan XC 72/Nafion layer, thermal stability, a 153
PtBi nanoparticles, MeOH oxidation, a 210
PtCo, for PEMFCs 202
PtCo/C, cathodes, for PEMFCs 202
PtIrCo, for PEMFCs 202
PtMo, anodes, for PEMFCs 200
PtMo/C, anodes, for PEMFCs, a 49
PtPb nanoparticles, MeOH oxidation, a 210
PtRu, anodes, for AFCs 38
anodes, for PEMFCs 200
for DMFCs 38, 202
Pt/Ru/C, electrodes, for DMFCs 38
PtRu black, anodes, for DAFCs 202
PtRu nanoparticles, MeOH oxidation, a 210
PtRuIr/C MWNTs, anodic oxidation of MeOH, a 153
PtSb, MeOH electrooxidation, a 107
PtSn, for DAFCs 202
Pd monolith + Pt/Rh/Ce monolith TWC 177
Pd-Pt, CH4combustion 64
diesel oxidation 177
S-poisoned, regeneration, for CH4combustion 177
Pd-Pt/alumina, hydrogenation of dibenzothiphenes 22
Pd-Pt/Ce-ZrO2, CH4combustion 64
PdPt nanoparticles-polymer, fine chemicals synthesis 22
Pt, addition, TiO2, degradation of organics 22
catalytic reforming units 52
hydrogenation of alkyl pyruvates, + ionic liquids 194
for motorcycles, a 105
Olefex process (propane to propylene) 22
oxidative reactions, diesel, gasoline 64
propane dehydrogenation 22
for reforming 110
soot + NO + O2 177
Pt coated Na-β''-alumina, NOx storage device 22
Pt/Al2O3, + AE oxide, NOx storage-reduction, a 105
pyrolysis gasoline, aromatisation, hydrogenolysis 194
+ RE oxide, NOx storage-reduction, a 105
soot + NO2+ O2 177
Pt/γ-Al2O3+ V, naphthalene oxidation, a 209
Pt/alumina, hydrogenation of dibenzothiophenes 22
Pt/Ba/Al2O3, by one-step flame synthesis 22
NOx storage 22
NOx storage/reduction 177
Catalysts, Platinum,(cont.)
Pt/Ba/CeO2, NOx storage/reduction 177
Pt/Ba/CeZr, NOx storage 177
Pt/C-coated monoliths, combustion of xylenes, a 209
Pt/CeO2, WGSR 21, 22, 194
Pt/ceria-zirconia oxide, + Gd, La, Sm, CH4oxidation 64
Pt/CeZr, NOx storage 177
Pt/mordenite, oxidation of CO, in H2, a 48
Pt/SiO2, CO oxidation, a 152
Pt/TiO2(rutile), preparation, effect of Pt precursor, a 152
WGSR, at low-temperature, a 152
Pt/TiO2thin film, visible light-responsive 22
Pt/YSZ, monolith-type reactor 22
Pt-Ce, soot + NO + O2 177
Pt-Fe, + Na-A zeolite, oxidation of CO, in n-butane 22
Pt-Fe/mordenite, oxidation of CO, in H2, a 48
PtFe/SiO2, CO oxidation, a 152
PtFe2/SiO2cluster-derived, CO oxidation, + H2, a 152
Pt5Fe2/SiO2, cluster-derived, CO oxidation, + H2, a 152
Pt-Pd/Al2O3, CH4combustion 64
PtPd/C MWNTs, naphthalene hydrogenation, a 152
PtPd/SiO2-Al2O3, naphthalene hydrogenation, a 152
Pt-Re, catalytic reforming units 52
Pt-Rh gauze pack 103
Pt-Sn/HZSM-5 zeolite, denitration of drinking H2O, a 48 Catalysts, Rhodium,Pt-Rh gauze pack 103
Pt/Rh/Ce monolith TWC 177
Rh, oxidative reactions, diesel, gasoline 64
Rh coated K-β''-alumina, Fischer-Tropsch reaction 22
Rh-coated foams, alkane oxidation, a 106
Rh nanoparticles, hydroformylation of olefins, a 153
Rh nanoparticles/nanosized SiO2, CO hydrogenation, a209
Rh/C, hydroformylation of olefins, a 153
Rh/LaMnO3, CH4combustion 64
Rh/YSZ, monolith-type reactor 22
Rh-Ce-Mn/SiO2+ CNTs, CO hydrogenation, a 209
Catalysts, Rhodium Complexes,Rh, + β-diiminate,
+ NH3ligands, + phenoxy-imine,
polymerisation of acetylenes, a 210
Rh/BINOL, asymmetric hydrogenation 54
Rh/MonoPhos ligands, asymmetric hydrogenation 54
Rh phosphine, cyclisation of alkynes 171
Rh/phosphoramidites, asymmetric hydrogenation 54
RhCl(TPPTS)3/SiO2, cinnamaldehyde hydrogenation, a 210
Rh(COD)2BF4+ phosphoramidites 54
[Rh(cod)Cl]2, a 210
Rh(III) N-heterocyclic carbene, H transfer reduction 171
[Rh(nbd)Cl]2, a 210
Rhodium Bicentenary Competition, research 171
Catalysts, Ruthenium,carbonylations 95
Co/alumina, + Ru, Fischer-Tropsch reaction 22
CO2reductions 95
electrocatalysts, PtRu, anodes, for AFCs 38
anodes, for PEMFCs 200
for DMFCs 38, 202
Pt/Ru/C, electrodes, for DMFCs 38
PtRu black, anodes, for DAFCs 202
PtRu nanoparticles, MeOH oxidation, a 210
RuSe, cathodes, for DAFCs 202
Fischer-Tropsch reactions 95
oxidations 95
RuCl3, with H2O2, oxidation of organics, a 106
Ru(OH)x/Fe3O4, aerobic oxidations; reductions , a 209
separation, with a permanent magnet, a 209
Catalysts, Ruthenium Complexes,π-allyl-Ru 95
chiral, in asymmetric synthesis, a 107
Grubbs’ catalysts, first, second generation 35
in organic synthesis 95
Ru alkylidenes bearing N-heterocyclic carbenes 35
Ru allenylidenes, cationic, neutral 81
metathesis, ADMET, enyne, RCM, ROMP 81
Ru carbene, asarone-derived, olefin metathesis, a 106
ruthenacycle intermediates, in C–C bond formation 95
Cinnamaldehyde,hydrogenation, a 210
Coatings,Al-Pt, on Ti6242, a 47
thermal barrier, with PtNiAl diffusion bond coats, a 105
Combustion,catalytic, VOC emissions 64
CH4 22, 64, 177
xylenes, a 209
Composites,Pt-polyaniline, synthesis, a 151
Conferences,9th Grove Fuel Cell Symp., London, 2005 38 10th International Platinum Symposium, Finland, 2005 13
10th Ulm Electrochemical Talks, Germany, 2006 202
CAPoC7, Brussels, 2006 177
EUROPACAT-VII, Bulgaria, 2005 22
IWCC6, Isle of Ischia, Italy, 2005 64
SURCAT 2006, Cardiff, 2006 194
Coupling Reactions,industrial-scale, a 106
Creep,Ir, high temperature 158
CRT®,for diesel emission control 177
Crucibles,Ir 29, 158
Crystallographic Properties,Pt 118
CVD,Pd, Pd-Pt bilayer, Pt, films, on polyimide, a 208
Cyclisation,alkynes 171
Cycloolefins,ROMP 81
Cyclopropanation,Ru catalysis 95
Cyclopropenes,addition of alkynes, a 106
Dehydrogenation,propane 22
Denitration,drinking H2O, a 48 Dental,Au-Ag-Pd-In alloy, precipitation hardening, a 49
Deposition,Ag–Pd films, a 208
electroless, Pd nanowires, a 151
electrostatic spray, Pt/C MEA, a 210
photocatalytic, Pd membranes, a 209
TiPdNi thin films, a 105
Dibenzothiophenes,hydrogenation 22
Dienes,butadiene, hydrogenation 20, 22
Diesel,oxidation catalysts 64, 177
Diffusion,volume, Au, into single crystal Ir 29
Diffusion Couples,Sn/Pd/Sn, a 46
Electrical Conductivity,Magnus’ salt derivatives, fibres112
Electrical Contacts,ohmic, Ni/Pd, oxidised; Pd, a 153
Schottky, Pd/GaAs, Pd/porous-GaAs, H sensing, a 105
Electrical and Electronic Engineering,a 107, 153
Electrical Resistivity,Pd 144
Electrochemical Promotion,catalysts 22
Electrochemistry,a 47, 151, 208 cathode reactivity, of platinised Pt, in super-dry DMF 180
polymerisation, C2H2, a 208
[Ru(bpy)(bpy-C60)]2+, [Ru(tpy)(tpy-C60)]2+, a 150
synthesis, Pt-polyaniline composite, a 151
Zr-Pd, Zr-Pt, in different solutions, a 47
Electrodeposition,Ir, Os, Rh, Ru 67
Pt-Cu nanowires, a 107
RuO2, on electrospun TiO2, a 208
Electrodeposition & Surface Coatings,a47, 105, 151, 208
Electrodes,in fuel cells, see Fuel Cells
micro-, array, Pd plated B-doped diamond, a 105
Pd nanoparticles/B-doped diamond, a 105
platinised Pt, cathode, reactivity, in super-dry DMF 180
polypyrrole films, + Ir, Pt, Ru particles, H evolution, a151
Pt, with ferroelectric films, a 153
Pt-Zn porphyrin nanocomposite/Nafion/glassy C, a 47
Rh, roughened, polymerisation of C2H2, a 208
RuO2–IrO2–SnO2/Ti, preparation, characterisation, a 208
RuO2/TiO2nanorods, a 208
SrRuO3, with ferroelectric films, a 153
Electroless Plating,Ir, Os, Pd, Pt, Rh, Ru, Pt-Rh 67
Pd nanowires, a 151
Electrospinning,Magnus’ salt derivatives, to fibres 112
Elongation,by tensile tests, Pt-Cu, Pt-Ru 15
Emission Control, motor vehicles 64, 177
VOCs, catalytic combustion 64
Enthalpy of Fusion,Pd 144
Enyne Metathesis,in synthesis 81
Fibres,Magnus’ green salt derivatives 112
Films,FePt nanocubes, a 107
Pd, Pd-Pt bilayer, Pt, on polyimide, a 208
platinised Pt, reduction 180
polypyrrole, + Ir, Pt, Ru particles, H evolution, a 151
‘Final Analysis’ 52, 110, 156
Fine Chemicals,synthesis 20
Fischer-Tropsch Reactions,Rh coated K-β''-alumina 22
Ru catalysis 95
Fluorescence,[Ru(bpy)(bpy-C60)]2+, a 150 Fluorination,enantioselective, a 210
Fracture,Ir 158
Fuel Cells,a 49, 107, 153, 210
AFC 38, 200
book review 200
conferences 38, 202
DAFC, electrocatalysts 202
DMFC, electrocatalysts 107, 200, 202
electrodes 38, 49, 107, 202
electrooxidation, MeOH, a 107
ORR, a 49
electrocatalysts 38, 153, 210
electrochemical losses 200
fuels 22, 38, 152, 200, 202
Fuel Cell Knowledge Transfer Network 119
MCFC 200, 202
membrane electrode assemblies 38, 49, 107, 200, 202, 210
nano, a 107
PAFC 200
PEFC, Pt/C black + Nafion ink, a 210
PEMFC, anodes 49, 202
CO tolerance, CO2tolerance 200
cathodes 107, 202
electrocatalysts 38, 49, 200, 202
Pt/Vulcan XC 72/Nafion layer, thermal stability, a 153
power, auxiliary supplies 22, 38
consumer electronics 38
Pt, availability, recovery, recycling 38
SOFC 200
transport, road vehicles: buses, cars, motorbikes 38
Fuels,H2 22, 38, 48, 152, 202
MeOH 38
for motorcycles, a 105
Gasoline,emissions, catalytic oxidation 64
Gauzes,Pt-Rh 103
Geology,Pt 13, 130, 134
Hardening,Ir-Hf-Nb, a 46
precipitation, Au-Ag-Pd-In, a 49
Heat Capacity,isobaric, Pd 144
Heck Reactions,a 48
Heterocycles,synthesis, through metathesis 81
High Pressure,synthesis, CePtSn, a 46
High Temperature,mechanical properties, Ir 158
synthesis, CePtSn, a 46
ultra-, Rh3X, thermophysical properties 69
High Throuhput Screening,ligands, used in catalysis 54
History,Frédéric Joliot-Curie, Iréne Joliot-Curie 97
Hans Merensky 130
Ir discovery, Smithson Tennant, commemorative plaque 77
metathesis, alkenes 35
Os discovery, commemorative plaque 77
Pd isotopes, discoverers 97
Pd print, Alfred Steiglitz; platinotype, Edward Steichen 78
Pt, discovery, in the Bushveld Complex 130
Pt, roubles, production, refining 120
Hydrazine,sensor, a 105
Hydroboration,methyl oleate, a 210
Hydrocarbons,oxidation 64, 106
processing applications 110
Hydrodearomatisation,pgm/alumina 22
Hydrodesulfurisation,pgm/alumina 22
Hydroformylation,solventless, olefins, a 153
Hydrogen,absorption, into Pd81Pt19foil, a 104
Hydrogen,(cont.)
evolution, from polypyrrole, + Ir, Pt, Ru particles, a 151
fuel 22, 38, 48, 152, 202
isotope separation, a 208
microwave plasma irradiation, Co-Pd, a 207
permeation, of Pd membranes, a 152, 208, 209
presence, CO oxidation 48, 152, 194
production 20, 22, 47
sensor, a 105
Hydrogen Peroxide,+ RuCl3, oxidation of organics, a 106
synthesis 22, 194
Hydrogenation,alkyl pyruvates 194
alkynes 194
asymmetric 54
asymmetric transfer, a 107
butadiene 20, 22
cinnamaldehyde, a 210
CO, a 209
dibenzothiophenes 22
naphthalene, a 152
nitrates, in H2O 22
in organic synthesis 95
pentyne 22
selective, acetylenes 156
sterols, a 106
sunflower oil, a 152
transfer, in organic synthesis 95
α,β-unsaturated carbonyl compounds 20
Hydrogenolysis,hydroxymatairesinol 22
pyrolysis gasoline 194
Imines,transfer hydrogenation, asymmetric, a 107
Ionic Liquids 153, 194
Iridium,creep, high temperature 158
crucibles 29, 158
discovery, commemorative plaque 77
electrodeposition, electroless deposition 67
high-temperature mechanical properties 158
impurities, mass transfer 29
particles, in polypyrrole films, H evolution, a 151
single-Ir, volume diffusion of Au 29
stress-rupture strength, high temperature 158
tensile strength, high temperature 158
vacancy-impurity complexes, growth 29
Iridium Alloys,Ir-Hf-Nb, hardening behaviour, a 46
superalloys, refractory, a 46
Iridium Complexes,Ir N-heterocyclic carbenes 171
trans-[IrCl(C8H14)(PiPr3)2] + benzene, a 208
IrCl(CO)2(p-toluidine) + tetraphenylporphyrin, a 150
[Ir(dF(CF3)ppy)2(dtbbpy)](PF6), electroluminescene, a 47
photoinduced H2production, a 47
[IrH2(Cl)(PiPr3)2], preparation, a 208
[IrH(C6H3F2)(Cl)(PiPr3)2], preparation, a 208
[IrH(C6H4X)(Cl)(PiPr3)2], preparation, a 208
[IrH(C6H5)(Cl)(PiPr3)2], preparation, a 208
[IrH{(C6H3F(CH3)}(Cl)(PiPr3)2], preparation, a 208
Ir(I), inverted N-confused porphyrin, a 150
Ir(III), bis-terpyridyl/pyridyl groups, luminescence, a 104
(MeCp)Ir(COD), precursor for MOCVD, a 151
Iridium Compounds,Ir nitride, synthesis, a 104
IrO2nanorods, by MOCVD, a 151
RuO2–IrO2–SnO2/Ti electrodes, a 208
Isomerisation,methyl oleate, a 210
organic substrates, Ru catalysis 95
Isomerism,[Pt(SC(NH2)2)4][C5O5]·4DMSO crystals, a 47
Isotopes,Pd, discoveries 97
Johnson Matthey,Award for Innovation in Catalysis 22
marketing, N2O abatement catalyst 103
“Platinum 2006” 143
Rhodium Bicentenary Competition 171
Susan V. Ashton, retirement as Editor, a tribute 205
Ketones,H transfer reduction 171
transfer hydrogenation, asymmetric, a 107
Kharasch Addition Reactions,Ru catalysis 95
Lignans,matairesinol production 22
Luminescence,bis-terpyridyl Ir(III), + pyridyl groups, a104
electro-, [Ir(dF(CF3)ppy)2(dtbbpy)](PF6), a 47
Ru(II) polypyridyls, containing 5-aryltetrazolates, a 105
Magnetism,Ce(Pd1–xAgx)2Al3, a 150
CePtSn, a 46
FePt nanoparticles, a 49
FePt/Fe composite nanotubes, a 46
MnxPd1–x, a 150
[Ru(C9H6NO)3]·MeOH, a 47
in separation of Ru(OH)x/Fe3O4, a 209
TbRhIn5, a 207
MEAs 38, 49, 107, 200, 202, 210
Mechanical Properties,high temperature, Ir, a 158
Pt-5 wt.% Cu, Pt-5 wt.% Ru 15
Medical Uses 2, 49, 107
Membranes,Pd, H2permeation, a 152
microfabrication, a 152
permeation, for H isotope separation, a 208
Pd/C coated asymmetric α-Al2O3, H2O2, synthesis 22
Pd/TiO2, by photocatalytic deposition, a 209
reactor; series; Pd, in H2generation, a 152
Metallopharmaceuticals,Ru polyaminocarboxylates 2
Metathesis 35, 81, 95, 106
Methane,combustion 22, 64, 177
emissions, oxidation 64
Methyl Oleate,hydroboration, isomerisation, a 210
Microwaves,in organic synthesis, a 49, 209
plasma H irradiation, Co-Pd, a 207
MOCVD,Al-Pt coatings, on Ti6242, a 47
IrO2nanorods, a 151
Nanocomposites,Pd-polyaniline, synthesis, a 152
Pt-Zn porphyrin, in detection of organohalides, a 47
Nanodroplets,fluorous, in organopalladium sphere, a 207
Nanofilms,polycrystalline Pt, thermal conductivity, a 207
Nanofiltration,solvents, a 153
Nanoparticles,FePt, a 49, 107
Pd, a 105, 151, 152
Pd70Ag30, a 207
Pt, a 47, 49, 210
PtBi, PtPb, PtRu, a 210
Rh, a 153, 209
Nanorods,IrO2, by MOCVD, a 151 Nanotubes,composite, FePt/Fe, a 46
Nanowires,Pt silicide, a 105
Pt-Cu, a 107
self-assembled, Pd, by electroless deposition, a 151
Naphthalenes,hydrogenation, a 152
oxidation, a 209
Naptha,reforming 20
Negishi Couplings,PdCl2+ PEPPSI-IPr, a 209
Nitrates, in H2O 22, 48, 152
Nitric Acid,plants, N2O abatement catalyst 103 Nitrogen,from nitrate hydrogenation, in H2O 22 Nitrogen Oxides, N2O,abatement catalyst 103
NO,+ O2, soot oxidation 177
scavengers, Ru-pac complexes 2
NO2,+ O2, soot oxidation 177
NOx,HC SCR, NH3SCR 177
lean, catalysis 22
storage 22, 177
storage-reduction 105, 177
trap, regeneration, by H2 22
Nobel Prize,Chemistry, metathesis reaction 35
Noble Gases,displacement of H, from Pd, a 46
Oil,sunflower, hydrogenation, a 152
OLEDs,in O2sensor, a 151
Olefex Process,propane, to propylene 22
Olefins,hydroformylation, solventless, a 153
Optical Properties,Magnus’ salt derivatives, fibres 112
Organohalides,Negishi couplings, a 209
sensor, a 47
Osmium,discovery, commemorative plaque 77
electrodeposition, electroless deposition 67
Hf–Os system, thermodynamic assessment, a 104
patents 27
Oxidation,aerobic, alcohols, a 153, 209
amines, a 209
Al-Pt coatings, on Ti6242, a 47
aldehydes, aromatic, a 106
alkanes, a 106
aniline, a 151
benzyl alcohol, a 106
CH4 64
CO 22, 106, 152, 177
in n-butane 22
in presence of H2 48, 152, 194
cyclohexanol, a 106
electro-, MeOH, a 107, 153
enzymatic 2
formic acid, a 48
hydrocarbons 64, 106
MeOH, a 210
naphthalenes, a 209
Pd0.97Ce0.03, a 150
Ru catalysis 95
soot 177
Zr-Pd, Zr-Pt, a 104
Oxygen,reduction, in fuel cells, a 49, 107
sensors, a 151
Palladium,Ag–Pd films, tarnish resistance, a 208
electrical resistivity 144
electroless deposition 67
enthalpy of fusion 144
film, on polyimide, a 208
H displacement, by noble gases, a 46
isobaric heat capacity 144
isotopes, history of the discoveries 97
membranes 22, 152, 208, 209
nanoparticles, a 105, 151, 152
nanowires, self-assembled, by electroless deposition, a151
ohmic contacts, oxidised Ni/Pd, Pd, a 153
Pd hydride, from Co-Pd, by microwave H plasma, a 207
Pd nanoparticles/B-doped diamond electrode, a 105
Pd plated B-doped diamond microdisc array, a 105
Pd-polyaniline nanocomposite, synthesis, a 152
Pd-Pt bilayer film, on polyimide, a 208
Pd/GaAs, /porous-GaAs, Schottky contact, a 105
print, Alfred Steiglitz 78
Sn/Pd/Sn diffusion couples, a 46
specific enthalpy 144
thermal conductivity 144
thermal diffusivity 144
thermophyical properties 144
Palladium Alloys,Ce(Pd1–xAgx)2Al3, magnetism, a 150
Co-Pd, demixing, a 207
dental, Au-Ag-Pd-In, precipitation hardening, a 49
Fe-Pd shape-memory thin films, stress evolution, a 46
MnxPd1–x, preparation, magnetism, a 150
Pd0.97Ce0.03, oxidisation, a 150
Pd70Ag30nanoparticles, preparation, a 207
Pd40Ni40B10P10, preparation, properties; Pd40Ni40P20, a 46
Pd81Pt19foil, H absorption, a 104
PdSn2, PdSn3, PdSn4, a 46
TiPdNi thin films, shape memory effect, a 105
Zr-Pd, electrochemical behaviour, in solution, a 47
oxidation, a 104
Palladium Complexes,arrow shaped N-donor ligands, a 207
Pd-octaethylporphyrin, OLED-based O2sensor, a 151
Pd2(η2-C60) structure, a 207
PdnC60, DFT calculations, a 207
[Pd(hypy)2]+, DFT modelling, IR spectroscopy, a 207
[Pd(hypy)2]Cl2, a 207
Palladium Complexes, (cont.)
[Pd(hypy)2]Cl2·2MeOH, crystal structure, a 207
Pd(II), with tetrazolecalix[4]arenes, a 104
phospha-palladacycle, with an acyclic carbene, a 104
Palladium Compounds,NbPdSi, structure, synthesis, a150
Particulates,control 177
Patents 50–51, 108–109, 154–155, 211–212
Os 27
Phoscorite-Carbonatite Pipe Complexes,PGEs 134
Phosphoramidites,synthesis 54
Phosphorescence,electro-, PFO-PtTPP, a 47
Photocatalysis 22, 209
Photoconversion,a 47, 104–105, 151
Photoproperties,Magnus’ salt derivatives, fibres 112
Pt-acetylide polymer, a 151
[Ru(bpy)2(5-CNphen)]2+, a 151
Ru(II) fullerene polypyridines, a 150
[(tpy)Ru(bis(U-terpyridine))Ru(tpy)]4+, a 208
[{(tpy)Ru}3(tris(U-terpyridine))]6+, a 208
Photoreactions,H2PtCl6/Zn porphyrin, + ascorbic acid, a47 Photosensitisers,[Ir(dF(CF3)ppy)2(dtbbpy)](PF6), a 47
[Ru(bpy)2(5-CNphen)]2+, a 151
Plating Baths,Ir, Os, Pd, Pt, Pt-Rh, Rh, Ru 67
Platinotype,photograph, record price 78
Platinum,Al-Pt coatings, on Ti6242, a 47
availability, for fuel cells 38
“blackberry-like”, “cauliflower-like” structures 180
crystallographic properties 118
discovery, in the Bushveld Complex 130
electrodes, a 153
electroless deposition 67
film, on polyimide, a 208
geology 13, 130, 134
nanoparticles, a 47, 49, 210
particles, in polypyrrole films, H evolution, a 151
Pd-Pt bilayer film, on polyimide, a 208
platinised Pt films, reduction 180
polycrystalline, nanofilms, thermal conductivity, a 207
print, Edward Steichen, record price 78
production, history 120
Pt-polyaniline composite, synthesis, a 151
Pt/Co overlayers, adhesion, bonding, a 151
Pt/Ni overlayers, adhesion, bonding, a 151
reactions, with refractories 197
recovery, recycling, from fuel cells 38
refining, history 120
roubles 120
thermal expansion 118
thermal vacancy 118
thermocouples, maintenance, reliability, specification 197
Platinum Alloys,(Fe0.75P0.25)75B25, phase tranformations, a46
FePt nanoparticles, self-assembly, a 107
surface PEGylation, a 49
FePt/Fe composite nanotubes, synthesis, a 46
Pd81Pt19foil, H absorption, a 104
PtBi nanoparticles, a 210
Pt-5 wt.% Cu, mechanical properties 15
Pt-Cu nanowires, electrodeposition, a 107
PtNiAl, diffusion bond coats, a 105
PtPb nanoparticles, a 210
Pt-Rh, electroless deposition 67
Pt-5 wt.% Ru, mechanical properties 15
PtRu nanoparticles, a 210
Rh-Pt thermocouples 197
Zr-Pt, electrochemical behaviour, in solution, a 47
oxidation, a 104
Platinum Complexes,bis(oxalato)platinate(II), PO, a 207
Me3(MeCp)Pt, for MOCVD, a 47
PFO-PtTPP, phosphorescence, a 47
[Pt2–, TAA+, TAAX], [Pt4–, TMA+, TMAX] 180
Pt-acetylide polymer, in solar cells, a 151
Pt-octaethylporphyrin, OLED-based O2sensor, a 151
Pt(II), containing N-bonded acetamide, a 104
containing O-bonded acetamide, a 104
Platinum Complexes, (cont.)
[Pt(L)Me2], protonation, a 150
[Pt(L)Me(CH3CN)]+, by protonation, a 150
tetra(cyano)platinate(II), PO, a 207
Platinum Compounds,CePtSn, magnetism, a 46
cisplatin, dinuclear analogues, DFT/CDM study, a 107
Magnus’ salt derivatives, fibres, by electrospinning 112
Pt nitride, synthesis, a 104
Pt-silicide nanowires, biomolecule sensing, a 105
Pt-Zn porphyrin nanocomposites, synthesis, a 47
PtCl62–, oxidation of aniline, a 151
reduction, a 151
[cis-{Pt(NH3)2}(μ-OH)]22+, a 107
[Pt(NH2dmoc)4][PtCl4], [Pt(NH2eh)4][PtCl4], fibres 112
[Pt(SC(NH2)2)4][C5O5]·4DMSO crystals, isomerism, a 47 Platinum Group Elements,geology 13, 130, 134
Pollution Control,flame combustion, fossil fuels 20
motor vehicles 177
photocatalysed degradation, organic pollutants 22
Polyaminocarboxylates,Ru complexes 2
Polymerisation,acetylenes, a 210
by metathesis 35, 81
electrochemical, of C2H2, a 208
Polymers,bis(oxalato)platinate(II), partial oxidised, a 207
Pd-polyaniline nanocomposite, synthesis, a 152
PFO-PtTPP, phosphorescence, a 47
polypyrrole films, + Ir, Pt, Ru particles, H evolution, a151
Pt-acetylide polymer, in solar cells, a 151
Pt-polyaniline composite, synthesis, a 151
specialty, by ADMET, ROMP 81
synthesis, Ru catalysis 95
tetra(cyano)platinate(II), partial oxidised, a 207
Protonation,[Pt(L)Me2], a 150 Pyruvates,alkyl, hydrogenation, + ionic liquids 194
RCM,in synthesis 81
Reactors,industrial, hydrogenation of sterols, a 106
membrane, Pd, in H2generation, a 152
micro-, catalyst activity tests 52
monolith-type, YSZ, coated with Pt, Rh 22
pilot-plant, hydrogenation of sterols, a 106
Reduction,asymmetric, carbamates, enamides,
enol acetates 54
to α-alkyl succinic acid derivatives 54
to α-amino acid, β-amino acid, derivatives 54
α,β-unsaturated acids 54
carbonyl compounds, a 209
CO2 95
H transfer, ketones 171
NO2–, NO3–, a 152
O, in fuel cells, a 49, 107
platinised Pt films 180
PtCl62–, a 151
Refining,Pt, history 120
Reforming,catalysts 52, 110
dimethyl ether 22
MeOH 22
naptha 20
Refractories,insulation, for Pt-based thermocouples 197
reactions, with Pt 197
Rhodium,electrodeposition, electroless deposition 67
electrodes, roughened, polymerisation of C2H2, a 208
nanoparticles, a 153, 209
Rhodium Bicentenary Competition, research 171
Rhodium Alloys,Pt-Rh, electroless deposition 67
Rh-Pt thermocouples 197
Rhodium Complexes,Rh N-heterocyclic carbenes 171
Rh(CO)2I(NHC), structure, a 150
Rh(COD)X(NHC), synthesis, structures, a 150
Rhodium Compounds,CeRhIn5, a 207
intermetallic, Rh3X (X = Hf, Nb,Ta, Ti, V, Zr),
thermal conductivity, thermal expansion 69
TbRhIn5, crystal growth, magnetic properties, a 207
ROMP,cycloolefins; production of specialty polymers 81
Roubles,Pt 120
Russia,Pt 13, 130, 134
Ruthenium,electrodeposition, electroless deposition 67
particles, in polypyrrole films, H evolution, a 151
Ruthenium Alloys,Pt-5 wt.% Ru, mechanical properties 15
Ruthenium Complexes,[(C6H6)RuCl2]2+ quinolines, a 47
Ru polyaminocarboxylates, as antitumour drugs 2
as metallopharmaceuticals 2
as NO scavengers 2
as protease inhibitors 2
Ru(bpy)2(5-CNphen)]2+, photoproperties, a 151
[Ru(bpy)(bpy-C60)]2+, electrochemistry, fluorescence, a150
[Ru(C9H6NO)3]·MeOH, magnetism, a 47
Ru(II) polypyridyls + aryltetrazolates, luminescence, a105
[Ru(tpy)(tpy-C60)]2+, electrochemical study, a 150
solar cells, a 47
[(tpy)Ru(bis(U-terpyridine))Ru(tpy)]4+, photo, a 208
[{(tpy)Ru}3(tris(U-terpyridine))]6+, photo, a 208
Ruthenium Compounds,RuO2, electrodeposition, a 208
electrodes, a 153, 208
Selective Catalytic Reduction,HC, NH3 177
Sensors,biomolecules, a 105
H2, a 105
hydrazine, a 105
MeOH, a 152
O2, a 151
organohalides, a 47
Shape Memory Effect,Fe-Pd thin films, a 46
TiPdNi thin films, a 105
Single Crystals,Ir, volume diffusion of Au 29
Solar Cells,a 47, 151
Soot,oxidation 177
South Africa,Pt 13, 130, 134
Specific Enthalpy,Pd 144
Sputtering,co-, magnetron, of Ag–Pd films, a 208
Fe-Pd shape-memory thin films, a 46
Pt, on C cloths, a 49
Sterols,hydrogenation, a 106
Stress,by tensile tests, Pt-Cu, Pt-Ru 15
Stress-Rupture,strength, Ir, high temperature 158
Sulfur,catalyst poison 110
Superalloys,Ir-Hf-Nb, hardening behaviour, a 46
Supercritical Solvents,propane, in catalysis, a 152
Suzuki Couplings,a 48, 106, 153, 209
Suzuki-Miyaura Couplings,a 153
Syngas,in synthesis of acetic acid, a 209
Tensile,strength, high temperature, Ir 158
Tetraalkylammonium Salts,influences on platinised
Pt layers 180
Thermal Conductivity,Pd 144
polycrystalline Pt nanofilms, a 207
Rh3X (X = Hf, Nb, Ta, Ti, V, Zr) 69
Thermal Diffusivity,Pd 144
Thermal Expansion,Pt 118
Rh3X (X = Hf, Nb, Ta, Ti, V, Zr) 69
Thermal Vacancy,Pt 118
Thermocouples,Pt, reliability 197
Thermophysical Properties,Pd 144
Rh3X 69
Thin Films,Ag–Pd, deposition, tarnish resistance, a 208
Fe-Pd, shape memory, a 46
TiPdNi, shape memory, a 105
Three-Way Catalysts,ageing 177
developments 177
Vacancy-Impurity Complexes,growth, in Ir 29
Vitamins,intermediates, synthesis 22
VOCs,emissions, catalytic combustion 64
Water,-soluble, FePt nanoparticles, a 49
drinking, denitration 22, 48
Water Gas Shift Reaction 21, 22, 152, 194
