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14.4
Gases: Mixtures and Movements
A list of gear for an expedition to Mount Everest includes
climbing equipment, ski
goggles, a down parka with a hood, and most importantly compressed-gas cylinders of oxygen. You will find out why a supply of oxygen is
Gases: Mixtures and Movements>
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14.4 Dalton’s Law
Dalton’s Law
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Gases: Mixtures and Movements>
14.4 Dalton’s Law
The contribution each gas in a mixture makes to the total pressure is called the
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14.4 Gases: Mixtures and Movements> Dalton’s Law
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Gases: Mixtures and Movements>
14.4 Dalton’s Law
Dalton’s law of partial pressures states
that, at constant volume and temperature, the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of
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Gases: Mixtures and Movements> Dalton’s Law
Animation 17
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Gases: Mixtures and Movements>
14.4 Dalton’s Law
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Gases: Mixtures and Movements>
14.4 Dalton’s Law
The partial pressure of oxygen must be
SAMPLE PROBLEM
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SAMPLE PROBLEM
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SAMPLE PROBLEM
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SAMPLE PROBLEM
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Practice Problems for Sample Problem 14.6
Problem Solving 14.32
Gases: Mixtures and Movements>
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14.4 Graham’s Law
Graham’s Law
How does the molar mass of a gas affect the rate at which the gas
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Gases: Mixtures and Movements>
14.4 Graham’s Law
Diffusion is the tendency of molecules to
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Gases: Mixtures and Movements>
14.4 Graham’s Law
Bromine vapor is diffusing
upward through the air in a
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Gases: Mixtures and Movements>
14.4 Graham’s Law
After several hours, the
bromine has
diffused almost to the top of the
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14.4 Gases: Mixtures and Movements> Graham’s Law
During effusion, a gas escapes through a tiny hole in its container.
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14.4 Gases: Mixtures and Movements> Graham’s Law
Thomas Graham’s Contribution
Graham’s law of effusion states that the
rate of effusion of a gas is inversely
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14.4 Gases: Mixtures and Movements> Graham’s Law
Comparing Effusion Rates
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14.4 Gases: Mixtures and Movements> Graham’s Law
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14.4 Gases: Mixtures and Movements> Graham’s Law
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14.4 Gases: Mixtures and Movements> Graham’s Law
Helium effuses (and diffuses) nearly three times faster than nitrogen at the same
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Gases: Mixtures and Movements> Graham’s Law
Animation 18
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Section Quiz
-or-Continue to: Launch:
Assess students’ understanding of the concepts in Section
14.4 Section Quiz.
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14.4 Section Quiz.
1. What is the partial pressure of oxygen in a diving tank containing oxygen and helium if the total pressure is 800 kPa and the partial pressure of helium is 600 kPa?
a. 200 kPa
b. 0.75 kPa
c. 1.40 104 kPa
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14.4 Section Quiz.
2. A mixture of three gases exerts a pressure of 448 kPa, and the gases are present in the mole ratio 1 : 2 : 5. What are the individual gas pressures?
a. 44 kPa, 88 kPa, and 316 kPa
b. 52 kPa, 104 kPa, and 292 kPa
c. 56 kPa, 112 kPa, and 280 kPa
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14.4 Section Quiz.
3. Choose the correct words for the spaces. Graham's Law says that the rate of diffusion of a gas is __________ proportional to the square root of its _________ mass.
a. directly, atomic
b. inversely, atomic
c. inversely, molar
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Gases: Mixtures and Movements> Concept Map 14
Concept Map 14