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Combined Measurement of Directional Raman Scattering and Surface-Plasmon-Polariton Cone from Adsorbates on Smooth Planar Gold Surfaces

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Figure

Fig. 1  Schematic illustrating the Weierstrass prism (formed by optically coupling a sapphire hemispherical prism to a sapphire window) in the Kretschmann configuration with a 50-nm thick gold substrate
Fig. 2 Instrument schematic from the top of the 785-nm excitation directional-surface-plasmon-coupled Raman spectrometer
Fig. 3  (A) Experimental cone intensity (dotted symbol) and calculated reflectivity (solid gray line) for prism/50-nm gold/air
Fig. 4 (A) Directional Raman spectrum of a self-assembled monolayer of thiophenol at a Weierstrass
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