A N O V E R V I E W O F T H E S U B J E C T
Semiconductor Material &
Devices
Contents
1. Subject Information
2. The study of Electronics
3. History
4. Semiconductor
4. Semiconductor
Materials
Subject Information
Code: EE120
Text Book: Electronic Devices & Circuits by Theodore F. Bogart 6th ed.
Electronic Devices & Circuits by David A Bell 4th ed.
Electronic Devices & Circuits by Floyd Electronic Devices & Circuits by Floyd
Electronic Devices & Circuits by Manzar Saeed Basics of Electronic Device by NIIT
Marks distribution
Total Marks: 150 Theory: 100
Practical: 50 Session Marks: 20
• Assignments: 05
• Assignments: 05
• Quiz: 05
• Project + Presentations: 05
Introduction
Semiconductor Devices
Building blocks of useful electronic devices Semiconductor devices include:
Diodes
PN junction PN junction
Light Emitting Diode (LED) Zener Diode
Tunnel Diode Varactor Diode Laser Diode
Transistors
Bipolar Junction Transistor (BJT)
• NPN BJT
• PNP BJT
Junction Field Effect Transistor (JFET)
(JFET)
Amplifier Fundamentals
Small Signal Transistor Amplifier
Integrated Circuits (ICs)
Analog ICs Digital ICs
Basic Atomic Theory
Every chemical element is composed of atoms All atoms within a single element have same
structure
Every element is unique because the structure of its atoms is unique
atoms is unique
Atom is composed of three basic particles:
Protons (+ive charge) Neutrons
Electrons (-ive charge)
Silicon Atom
Orbits or Shells
K, L, M,N Draw the atomic
structure of Ge (32) P=14 N=14 Valence Shell Ne( Electrons in nth orbit) = 2n2
+
Sub-shells
Shell Sub-shell Capacity
K s 2 L s 2 p 6 p 6 M s 2 p 6 d 10 N s 2 p 6 d 10 f 14
Free Electrons
When electrons get enough energy (e.g. from heating), they leave their parent atoms and become free electrons. Flow of free electrons is called current. Therefore more free electrons and more current.
+
Free electrons in (i) conductors (ii) Insulators & (iii) Semiconductors
Valence electrons have more tendency to become free electrons because of less attraction force between nucleus and valence shell
Flow of Free Electrons (Current)
Material containing free electrons
-Force of repulsion Force of attraction
-- +
Excess of electrons Lack of electrons
-Silicon Crystal (
Covalent
Bonding)
For stability there should be 8 electrons in valence shell
+
* * * * * * * *+
+
+
+
+
+ * * * * * * * * + * * * * * * + * * * * * * + * * * * * * + * * * * * * * * + * * * * + * * * * + * * + * * * * * * + * * * * * * + * * * * + * * Si CrystalH O L E C U R R E N T
Current in Semiconductors
Contents
1. Basics 2. Electron Energy 3. Energy Bands 3. Energy Bands 4. Temperature & ResistanceBasics:
Rupturing of covalent bond
The unit of energy is electronvolt(eV)
Energy acquired by one electron if it is accelerated through potential difference of one volt
1 eV = 1.602 x 10-19 J
1 eV = 1.602 x 10-19 J
Valence Electron energy considerably large and need a few amount of energy to release
Electrons in inner shell possess little energy and need a large amount of energy to release
Electrons can lose energy in the form of heat and light Free electrons can alco lose and fall into valence shell
Important Quantities
Quantity Symbol Unit Unit Symbol
Current I Ampere A
Voltage V Volt V
Charge Q Coulomb C
Energy W,E Joule J
Electric Field Strength E Volt/meter V/m
Volume V Cubic meter m3
Area A Squared meter m2
Resistance R Ohm Ω
Conductance G Moh, Siemens S
Resistivity ρ Ohm-meter Ω-m
Important Relations
V = IR (Ohm's Law) I = Q/t W = QV R = ρl/A G = 1/R σ = 1/ ρ σ = 1/ ρ Charge on electron = e = 1.602 X 10-19 C Electron energy = 1 eV = 1.602 X 10-19 JRupturing of Covalent Bonds
+
Electron Freed+
+
+
+
+
Electron Freed (Conduction Band) Hole createdCovalent bond ruptured
Valence band Energy is supplied in the form of heat to rupture covalent band
Electron Energy
Electrons closer to nucleus are more tightly bound and need more energy to become free
P=14 N=14 E1 E2 E3 Therefore: E1 > E2 > E3
If free electron loses energy and falls back to valence band, this process is called “Annihilation” or “Recombination”
Energy Bands:
Quantum theory explain these bands as
Conduction Band :
Free electrons accommodate there
Valence Band :
Electrons having lesser energy accommodate there
Forbidden band: Forbidden band:
The region between valence and conduction band No electrons can stay at this energy levet
Energy Bands
eV
Conduction Band (Free Electrons)
Valence Band
(Electrons in Valence Shell)
Forbidden Band
(Free Electrons)
Energy Gap
Energy gap is the energy required to rupture covalent bond
Energy Bands for Different Materials
Forbidden Band Conduction Band Forbidden Band Conduction Band ≤0.01eVValence Band Valence Band
Valence Band Forbidden Band Conduction Band Valence Band Forbidden Band Conduction Band Insulators Conductors Silicon Germanium 1.1eV 0.67eV Temperature dependent
Temperature & Resistance
dT dR = α Temp. Coeff. = α α = -ive T I R Conductors Semiconductors R I T α = +ive α = -iveHoles & Hole Current
+ + + + + + + + + + + + + Hole Movement Electron MovementHole Current Vs Electron Current
The movement of holes and electrons is in opposite directions
There are no holes in pure conductors, they are only created in semiconductors
There are two currents in semiconductors: There are two currents in semiconductors:
Hole current (Band ? Charge ?)
Free electron current (Band ? Charge ?)
The total current in semiconductor materials is the sum of hole current and electron current
Charge Carriers
Holes are called positive charge carriers
Free electrons are called negative charge carriers
For pure (Intrinsic) semiconductors: Number of positive charge carriers = Number of negative charge carriers
Is there any way to make charge carriers unequal? Is there any way to make charge carriers unequal?
Let hole density be pi (holes/m3) and electron density be n
i (electrons/m3)
where i denotes intrinsic semiconductor, then:
ni = pi + + + + + + -Intrinsic Semiconductor