C-H...N HYDROGEN BONDING
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Crystal structure analysis of [5 (4 methoxyphenyl) 2 methyl 2H 1,2,3 triazol 4 yl](thiophen 2 yl)methanone
... weak C—H N hydrogen-bonding dimeric motifs (Table 1) involving the methyl hydrogen H15C (sp 3 ) of the methoxy group with the triazol nitrogen N3 [C15 N3 = ...thiophene ...
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Crystal structure of a mononuclear copper(II) complex with 2 methoxy N,N bis(quinolin 2 ylmethyl)ethylamine (DQMEA)
... molecular C—H N hydrogen-bonding interaction takes place between a quinolyl hydrogen (H11) and the nitrogen atom of the acetonitrile ligand (N4), which may help stabilize the ...
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N—H⋯O hydrogen bonding in the adduct of N (2 aminoethyl) 2 hydroxybenzamide with picric acid
... of N-(2-aminioethyl)-2-hydroxybenzamide are interlaced with the benzene rings of picric acid, to form columns along the a,b ...by N—H···O interactions to two adjacent nearly perpendicular aromatic ...
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Intermolecular N–H⋯O hydrogen bonding interactions in 5 fluorocytosinium salicylate
... O2 hydrogen bonds to form a linear hydrogen-bonded supramolecular chain ...O2 hydrogen bond was previously proposed for a single stranded poly(C) nucleotide based on an NMR study (Broido & ...
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Crystal structures of (acetonitrile κN)tris(pyridine 4 thioamide κN)bis(thiocyanate κN)cobalt(II) acetonitrile disolvate and tetrakis(pyridine 4 thioamide κN)bis(thiocyanate κN)nickel(II) methanol pentasolvate
... intermolecular N—H S hydrogen bonding between the H atoms of the amino groups and the S atoms of the thiocyanate anions or the pyridine-4-thioamide ligands into a three-dimensional ...
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Crystal structure of catena poly[bis(tetraethylammonium) [tetraaquatris(μ dicyanamido κ2N1:N5)bis(dicyanamido κN1)dicobaltate(II)] dicyanamide]
... O—H N hydrogen bonding between aqua ligands and dicyanamido ligands or the dicyanamide ...addition, C—H N interactions are present between the tetraethylammonium cations ...
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Highly fluorinated naphthalenes and bifurcated C–H⋯F–C hydrogen bonding
... weak hydrogen bonding acceptor groups, Dunitz and Taylor examined the C – F group 6 in a survey of crystal structures from the Cambridge Structural Database 7 and Protein Data ...– H ⋯ F – ...
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Crystal structure of trans diammine(1,4,8,11 tetraazacyclotetradecane κ4N)chromium(III) tetrachloridozincate chloride monohydrate from synchrotron data
... through N—H Cl and O—H Cl hydrogen-bonding ...includes N—H Cl, C—H Cl, N—H O and O—H Cl hydrogen bonding between ...
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Crystal structure of bis(quinolin 1 ium) tetrachloridoferrate(III) chloride
... are N—H Cl hydrogen-bonding interactions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with – stacking between adjacent quinolinium ...
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Crystal structure of bis[bis(1,4,7 triazacyclononane κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X ray data
... The structures of the molecular components in the asymmetric unit of the title complex (I), drawn with displacement ellipsoids at the 70% probability level. Dashed lines represent hydrogen-bonding ...
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catena Poly[[[bis(1,10 phenanthroline)cadmium(II)] μ naphthalene 2,6 dicarboxylato] monohydrate]
... it is a rigid linear ligand with two carboxylate groups on opposite sides, so that it is a building block that can link other building blocks in the polymer, and also because the bulky nature and extended -conjugate ...
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Crystal structure of 5 [2 (9H carbazol 9 yl)ethyl] 1,3,4 oxadiazole 2(3H) thione
... A mixture of 3-(9H-carbazol-9-yl)propanehydrazide (1.09 g, 4 mmol) and carbon disulfide (3 ml) in pyridine (15 mL) was heated under reflux on a water bath (333–343 K) overnight. The excess carbon disulfide was removed ...
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Crystal structure of 1 ethyl 3 (2 oxo 1,3 dithiol 4 yl)quinoxalin 2(1H) one
... The title molecule I crystallizes in the monoclinic space group C2/c with Z = 8. The quinoxaline ring system [C4–C11, N1, N2; largest deviation from plane = 0.041 (2) A ˚ for C5] and the dithiolene ring [C1–C3, ...
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Synthesis and Crystal Structure of the Hydrogen Bromide Salt of 1,4,7,10 Tetrakis(2 ((4 methoxy)phenoxy) ethyl) 1,4,7,10 tetraazacyclododecane
... I > 2 σ (I). Corrections for LP factors and semi-empirical absorption were applied based on Sadabs [15]. Unique data (Rint = 0.1233) were used to solve the struc- ture by direct methods with SHELXS-97 program [16]. ...
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Supramolecular hydrogen bonding patterns in the N(9)—H protonated and N(7)—H tautomeric form of an N6 benzoyladenine salt: N6 benzoyladeninium nitrate
... of N 6 -substituted adenines, adeninium salts and their metal complexes have been inves- tigated in a variety of crystalline ...include N 6 -benzyladenine (Raghunathan et al., 1983), N 6 ...
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2 (2,4 Dichlorophenyl) 5 fluoro 6 morpholin 4 yl 1H benzimidazole monohydrate
... In order to obtain 2-(2,4-Dichlorophenyl)-5-fluoro-6-morpholin-4-yl-1H-benzimidazole (Kuş, 2002), to a suspension of 4-fluoro-5-morpholin-4-yl-benzene-1,2-diamine (Sanna et al., 1998) (0,211 g, 1 mmol) in DMF (5 ml), the ...
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Bis(2,4,6 triaminopyrimidin 1 ium) sulfate pentahydrate
... and the mixture was stirred for 1 h. The resulting clear solution was filtered and left to evaporate at room temperature. The crystalline material that formed upon standing for several days was filtered off and ...
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2,4 Dichloroanilinium 4 chlorobenzenesulfonate monohydrate
... two H atoms of the water molecule have two O atoms of two different negatively charged sulfonate anions as ...simultaneous hydrogen bonds with two H atoms, one from the positively charged NH 3 group ...
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Crystal structure of (2 amino 7 methyl 4 oxidopteridine 6 carboxylato κ3O4,N5,O6)aqua(1,10 phenanthroline κ2N,N′)copper(II) trihydrate
... 60 h at 310–312 K under subdued light; additional NaOH solution was added for adjusting the initial pH at ...for C 20 H 21 CuN 7 O 7 : C ...
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Diaquabis(N,N diethylnicotinamide)bis(4 nitrobenzoato)zinc(II)
... The title compound, (I), was prepared as part of a series of studies of the coordination chemistry of the ligand N,N-di- ethylnicotinamide (DENA). It has a molecular structure (Fig. 1) very similar to that ...
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