iron complexes
Hydrocarbon Oxidation with H2O2, Catalyzed by Iron Complexes with a Polydentate Pyridine-Based Ligand
... new iron complexes containing a pyridine-based pentadentate ligand and studied their ability to carry out alkane hydroxylation using dihydrogen peroxide as ...The complexes show the spectral and ...
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Copper and Iron Complexes with Unusual Coordination Geometries Enforced by Phosphine Chelates
... Chapter 0 revised COPPER AND IRON COMPLEXES WITH UNUSUAL COORDINATION GEOMETRIES ENFORCED BY PHOSPHINE CHELATES Thesis by Neal P Mankad In Partial Fulfillment of the Requirements for the Degree of Doc[.] ...
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Synthesis, Characterization, and Reactivity Studies of Pyridine Bis(anilide) Iron Complexes
... for iron complexes, in order to mimic much of the chemistry available to late ...for iron complexes are II and III, thus enabling a variety of radical-based reactions but not two-electron ...
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Asymmetric catalysis using iron complexes : 'ruthenium lite'?
... Detailed mechanistic studies revealed that several iron complexes form within the mixture, several of which were identified by ESIMS. The reaction also appears to proceed via a radical intermediate with ...
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Bis(Imino) Pyridyl Iron Complexes: the Effect of Polymerization Conditions on Activities and Thermal Behaviors of Polyethylene
... Catalyst A was prepared using equal molar chemicals of ligand A and anhydrous iron dichloride compounds. The ligand (0.3 gr) and anhydrous iron dichloride (0.2 gr) were mixed using a 50 ml flask containing ...
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A Ferromagnetic Resonance Study of Iron Complexes as Biologically Synthesized in Magnetic Bacteria
... Line width represents the strength of spin-spin interaction among paramagnetic spins. The line width for the WC was 191 mT. Thus the wide-band signal was obtained in FMR of the WC. The line width for the MS fraction was ...
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Biological Activities of Hydroxytriazenes and Their Iron Complexes
... The entire synthesized compound were subjected to antimicrobial activity by zone inhibition method.. KEYWORDS: Hydroxytriazenes, Antimicrobial Activity, Iron Complexe Biological Acti[r] ...
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Phosphine stabilized di-iron complexes.
... coordination environment, the bridging-hydrogen atom must be equally associated with each molybdenum atom (i.e. not bound directly to only one) and be situated equidistant from the two metals. However, due to the fact ...
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Some studies on the formation and interconversion of iron sulfur nitrosyl complexes
... 1.44). Iron complexes of the type Fe(J-R) (R = ph, mph) and Fe(bza-ph), where H2(J-R) are Jager-type ligands with the bridging group R (ph = o-phenylene, mph = 4-methyl-o-phenylene) combining two imino- ...
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Use of (Cyclopentadienone)iron tricarbonyl complexes for C–N bond formation reactions between amines and alcohols
... novel iron complexes, containing aryl groups fl anking the central C O in the cyclopentadienyl ring, were prepared and applied to the catalysis of the formation of C − N bond formation of aromatic amines ...
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Redox reactions of iron(III)-polypyridyl complexes with thiodicarboxylic acids: A Kinetic study
... with iron(III)-polypyridyl complexes depend on the nature of the carboxylic acids and ligands with the Iron ...complexes. Iron(III)-polypyridyl complexes were prepared and ...
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(Cyclopentadienone)iron shvo complexes : synthesis and applications to hydrogen transfer reactions
... (cyclopentadienone)iron complexes for hydrogen transfer reactions suggested that a higher catalyst loading was generally needed in comparison to the analogous ruthenium ...
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Pharmaceutical design of no release from iron, manganese and ruthenium nitrosyl complexes
... Fe complexes (MNIC) shows a concomitant increase in the fresh weight of sorghum ...dinitrosyl complexes can be easily synthesized in the air at ambient temperature (86) including consecutive addition to ...
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Potential alteration of iron–humate complexes by plant root exudates and microbial siderophores
... that iron complexed by humic acids can be displaced and solubilized by the action of micro- bially produced siderophores or root-exuded organic ...the iron removal from the iron complexes is ...
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The use of (cyclopentadienone)iron tricarbonyl complexes and ruthenium complexes for hydrogen transfer reactions
... using iron complexes 67, 69-71 and 80 with the use of the four alcohols of increasing carbon chain length, revealed no overall increasing or decreasing ...
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Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands
... anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of ...
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Synthesis and applications to catalysis of novel cyclopentadienone iron tricarbonyl complexes
... All solvents and reagents were degassed before use and all reac- tions were carried out under a nitrogen atmosphere. Reactions were monitored by TLC using aluminium backed silica gel plates, visualized using UV 254 nm ...
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IRON(III) COMPLEXES OF ISONICOTINOYL HYDRAZONES: SYNTHESIS, SPECTRAL PROPERTIES, DNA STUDIES
... metal complexes are discussed. Important IR spectral bands of complexes are presented in Table ...of iron complexes this peak is shifted (11-46cm -1 ) to lower wave numbers suggesting the ...
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Iron(II) complexes of 2,6-di(1-alkylpyrazol-3-yl)pyridine derivatives - The influence of distal substituents on the spin state of the iron centre
... of iron complexes of 3-bpp derivatives that are disubstituted at the pyrazole N1 ...coordinated iron centre ...metal complexes of L Me [13] and L All [16] have been reported before but their ...
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Spin state behavior of iron(II)/dipyrazolylpyridine complexes. New insights from crystallographic and solution measurements
... six-coordinate complexes; and, the narrow clamp angle of the 1-bpp ligand (Scheme 3), which causes the geometries to deviate from the ideal Bailar twist ...
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