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LiCl-KCl

Electrochemical Behavior of Indium in LiCl-KCl Molten Salts

Electrochemical Behavior of Indium in LiCl-KCl Molten Salts

... the electrochemical studies. LiCl : KCl with the eutectic composition (58.2 : 41.8 mol%) was dried in a heating cabinet at 150 °C for at least 24 hours prior to the start of the experiments. In these ...

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Understanding of Electrochemical Reduction of Sm3+ in a LiCl-KCl Molten Salt Solution at 773 K

Understanding of Electrochemical Reduction of Sm3+ in a LiCl-KCl Molten Salt Solution at 773 K

... To avoid divergence in CV curve analysis, the diffusion coefficient of Sm 3+ was determined from the slope of chronamperometric current prior to CV experiments. For the measurement of chronoamperometric current (total ...

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Electrochemical Behavior of Zirconium in an in-situ Preparing LiCl-KCl-ZrCl4 Molten Slat

Electrochemical Behavior of Zirconium in an in-situ Preparing LiCl-KCl-ZrCl4 Molten Slat

... metastable compounds and would slowly disproportionate into Zr(IV) and Zr. At the anode, Zr and ZrCl are dissolved into the melt as Zr(IV). Ghosh et al.[23, 24] have reported the redox behavior of zirconium in ...

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Determination of Lanthanide Ions in a LiCl-KCl Molten Salt by Square Wave Voltammetry

Determination of Lanthanide Ions in a LiCl-KCl Molten Salt by Square Wave Voltammetry

... eutectic solution. Practical concentration of Gd(III) in the solution was analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES). The temperature of the eutectic salt was maintained at 773 K. ...

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Study on Electrodeposition of Ce(III) at a Tungsten Electrode in a LiCl-KCl Molten Salt Solution

Study on Electrodeposition of Ce(III) at a Tungsten Electrode in a LiCl-KCl Molten Salt Solution

... The electrodeposition of cerium ions at a tungsten electrode in the LiCl-KCl eutectic salt solution was elucidated by linear sweep voltammetry and digital simulation technique. To interpret the ...

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Electrochemical Reaction of Yb(III)/Yb(II) at Tungsten Electrodes in LiCl-KCl Eutectic Melts

Electrochemical Reaction of Yb(III)/Yb(II) at Tungsten Electrodes in LiCl-KCl Eutectic Melts

... The electrode reaction of the Yb(III)/Yb(II) redox couple at W electrodes in the LiCl-KCl eutectic solutions has been studied using linear sweep voltammetry (LSV) and digital simulation method. In this ...

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Electrochemical Investigation of Exchange Current Density of Uranium and Rare-earths Couples (M3+/M0) in LiCl-KCl Eutectic Electrolyte

Electrochemical Investigation of Exchange Current Density of Uranium and Rare-earths Couples (M3+/M0) in LiCl-KCl Eutectic Electrolyte

... Figure 3 shows the linear polarization curves for M 3+ /M 0 (La 3+ /La 0 , Ce 3+ /Ce 0 , Pr 3+ /Pr 0 , Nd 3+ /Nd 0 , Gd 3+ /Gd 0 , Y 3+ /Y 0 and U 3+ /U 0 ) on a tungsten electrode in a LiCl-KCl eutectic ...

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Electrode Reactions of Nd3+/Nd Couple in LiCl-KCl-NdCl3 Solutions at Solid W and Liquid Cd Electrodes

Electrode Reactions of Nd3+/Nd Couple in LiCl-KCl-NdCl3 Solutions at Solid W and Liquid Cd Electrodes

... solid W electrode. Subsequently, a current of 1 μA was applied, and the changes in potential over time were observed. Nd and Cd dissociate into LiCl-KCl salt because of the positive current flow. Fig. 10 ...

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Electrochemistry of Zr (IV) in molten LiCl–KCl–K2ZrF6 System

Electrochemistry of Zr (IV) in molten LiCl–KCl–K2ZrF6 System

... Because the copper electrode is easily available and non–toxic [12], it was introduced to the molten salts to extract zirconium by forming Cu–Zr intermetallic compounds in this work. The electrochemical signals of ...

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Electrochemical Behaviour of Tin in a LiCl-KCl Eutectic Melt

Electrochemical Behaviour of Tin in a LiCl-KCl Eutectic Melt

... All the chemical reagents used in the experiment were analytically pure. The electrolyte was a LiClKCl (58.5:41.5 mol%) eutectic placed in an alumina crucible, dried for more than 72 h at 300 ℃ and later ...

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Uranium Dissolution Behavior in LiCl-KCl Molten Salts

Uranium Dissolution Behavior in LiCl-KCl Molten Salts

... Uranium (U) dissolution behavior at an anode during electrorefining was investigated by employing the potentiodynamic polarization method, galvanostatic potential transient technique, AC impedance spectroscopy, and ...

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Electrochemical Behavior of Tin in Molten LiCl-KCl at 450°C

Electrochemical Behavior of Tin in Molten LiCl-KCl at 450°C

... This study is a part of a systematic research into the possibility of using of molten salt LiCl-KCl for the recovery of Sn and In contained in ITO (Indium oxide combining with 10 percent tin oxide) powder. ...

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Addition Effect of Fluoride Compounds for Zr Electrorefining in LiCl-KCl Molten Salts

Addition Effect of Fluoride Compounds for Zr Electrorefining in LiCl-KCl Molten Salts

... This indicates direct evidence that Zr complexes in molten salts can be modified by changing the anions. According to the free energies of formation of metal halides in the gas phase [27], the order of affinity for ...

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Predominance Diagrams of Spent Nuclear Fuel Materials in LiCl-KCl and NaCl-KCl Molten Salt Eutectics

Predominance Diagrams of Spent Nuclear Fuel Materials in LiCl-KCl and NaCl-KCl Molten Salt Eutectics

... Predominance phase diagrams for metal-molten salt systems are diagrams of potential vs. the negative logarithm of the activity of O 2- ions (E-pO 2- ); they are a valuable tool for predicting and understanding ...

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Electrolytic Recovery of High Purity Zr from Radioactively Contaminated Zr Alloys in Chloride Salts

Electrolytic Recovery of High Purity Zr from Radioactively Contaminated Zr Alloys in Chloride Salts

... in LiCl-KCl at 500 °C, only Zr was dissolved as Zr 4+ ion from Zircaloy-4 cuts into the electrolyte and the other elements were not oxidized into the ...in LiCl-KCl at the ZrCl 4 concentration ...

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Separation of inorganic anion from biomaterial using methacrylate based column in ion chromatography capillary system

Separation of inorganic anion from biomaterial using methacrylate based column in ion chromatography capillary system

... Figure 3 shows of the separation inorganic anions on monolith column using NaCl, LiCl KCl, NH4Cl, and RbCl with concentration 100 mM, respectively, as the mobile phase.. NaCl have a shor[r] ...

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The effect of sodium chloride substitution with potassium chloride on chemical, physical and microbiological characteristics  of Mediterranian cheeses

The effect of sodium chloride substitution with potassium chloride on chemical, physical and microbiological characteristics of Mediterranian cheeses

... Potassium chloride is a potential candidate salt that can be used in partial substitution for NaCl. Increased intake of potassium has been reported to have a protective effect on people with hypertension (Fregly, 1981; ...

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Toxin-Induced Gustatory Conditioning in Rats: Examining the Effects of Low Dose Toxins in Food on Rat Feeding Behaviour and Avoidance Conditioning

Toxin-Induced Gustatory Conditioning in Rats: Examining the Effects of Low Dose Toxins in Food on Rat Feeding Behaviour and Avoidance Conditioning

... ingested LiCl can produce robust conditioned taste avoidance (Ladowsky & Ossenkopp, 1986; Loy & Hall, 2002) and even small quantities are able to decrease ingestive responses to the toxin-containing flavor ...

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Solubility of CaS in CaCl2 LiCl Eutectic Melt

Solubility of CaS in CaCl2 LiCl Eutectic Melt

... the added concentration of CaS was 0.5 mol%CaS. There- fore, the solubility of CaS at 923 K may locate at 0.2 mol%. However, the analytical data at 973 K scattered largely. The excess value from the solubility limit can ...

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Chapter 17 and 18 WS.doc

Chapter 17 and 18 WS.doc

... On the solubility chart the x-axis represents ______________ and the y-axis represents _________________________. The most soluble salt at 0.0 °C is ________, the least soluble is _______. Comparing NaCl to KCl at ...

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