RHENIUM(I) COMPOUNDS
fac,cis Bromidotricarbonylbis(tribenzylphosphine)rhenium(I)
... Mn I and Re I , together with structural studies on selected compounds: mer,trans- [MnBr(CO) 3 {P(C 6 H 4 Cl-4) 3 } 2 ], fac,cis-[MnBr(CO) 3 ...
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fac,cis bromidotricarbonylbis(tribenzylphosphine)rhenium(I)
... Mn I and Re I , together with structural studies on selected compounds: mer,trans- [MnBr(CO) 3 {P(C 6 H 4 Cl-4) 3 } 2 ], fac,cis-[MnBr(CO) 3 ...
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Grimminger, Philipp (2009): Rhenium(V)-Carbohydrate Complexes with Amino Acids. Dissertation, LMU München: Fakultät für Chemie und Pharmazie
... As a kinetic phenomenon, the trans effect was originally observed for square pla- nar complexes (like Cisplatin or its trans isomer), where ligands in trans position to a certain group are substituted more rapidly. But ...
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Synthesis and Photophysical Properties of Rhenium(I)-Alkynyl Molecular Rectangles
... use. Compounds 1, 4-bis(4’-pyridylethynyl)benzene (bpeb), 1,4-bis (4’-pyridylethynyl)naphthalene (bpen) and 1,4-bis (4’-pyridylethynyl)anthracene (bpea) were synthesized by published methods 16–18 ...
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Crystal structure of fac tricarbonyl(cyclohexyl isocyanide κC)(quinoline 2 carboxylato κ2N,O)rhenium(I)
... Tricarbonylrhenium(I) compounds are being explored as luminescent probes for cell imaging, photosensitizers in photocatalysis (Lyczko et ...Re compounds in nuclear medicine for pain palliation and ...
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Crystal structure of fac tricarbonylchloridobis(4 hydroxypyridine)rhenium(I)–pyridin 4(1H) one (1/1)
... The structures of several complexes with the metal centre fac- tricarbonylrhenium(I) and pyridine-based ligands have been reported (Abel & Wilkinson, 1959; Farrell et al., 2016). The pyridine fragment can be ...
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Synthesis and crystal structure of tricarbonylchlorido{1 [(pyridin 2 ylmethylidene)amino]adamantane}rhenium(I)
... tricarbonylrhenium(I) compounds have received considerable ...of rhenium carbonyl-based photoCORMs towards the eradication of aggressive malignant cells, as well as oxidatively damaged cell ...
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Crystal structure of fac aquatricarbonyl[(S) valinato κ2N,O]rhenium(I)
... compounds are of interest as the closest non-radioactive analogs of 99m Tc-based systems, which could be particularly important for visualization and immu- notherapy. Studies of the cytotoxicity of rhenium ...
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Crystal structure of tricarbonyltris(pyridine κN)rhenium(I) tetrafluoridoborate
... tricarbonyl rhenium complex and demonstrated the suitability of this complex in ...novel rhenium tricarbonyl compounds to prove that heavy metals are not only erroneously termed as poisons, but can ...
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The Development of Metal-Organic Compounds for Use as Molecular Imaging Agents
... Histidine is well suited as a chelator for the radiolabelling of peptides by coordination of rhenium or technetium-99m. It can be used in histidine tags, which consist of repeating linear sequences of histidine ...
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fac Tricarbonylchloro(1,10 phenanthroline)rhenium(I)
... of rhenium(I) diimine complexes result in properties which make these molecules useful as photosensitizers in photochemical and photo- electron transfer reactions (Luong et ...of rhenium(I) ...
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Tricarbonylchlorido{N [2 (diphenylphosphino)benzylidene]benzylamine κ2N,P}rhenium(I) dichloromethane solvate
... a non-planar, six-membered chelate ring. The N—Re—P bite angle of 83.86 (12)° deviates from the ideal of 90° expected for an octahedron. The Re1—P1 and Re1—N1 bond lengths are 2.4561 (13) and 2.210 (4) Å, respectively. ...
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fac Tricarbonyl(2,9 dimethyl 1,10 phenanthroline)(2,6 dimethylphenyl isocyanide)rhenium(I) hexafluorophosphate
... The title compound, (I), was synthesized as part of a series of diimine tricarbonylrhenium(I) complexes containing the ligand 2,6-dimethylphenyl isocyanide. These complexes are highly emissive. The emission ...
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(2,2′ Bipyridine κ2N,N′)tricarbonyl(acetonitrile κN)rhenium(I) hexafluoroantimonate dichloromethane hemisolvate
... Rhenium(I)±tricarbonyl±diimine systems are of increasing interest because of their rich photoluminescent properties and their possible effect in electrochemically promoted reductions of carbon dioxide (Yam ...
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fac Acetonitriletricarbonyl(dimethylcarbamodithioato κ2S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis
... ca 2.5 and 3.0 A ˚ , respectively; Fig. 3b and f. These contact distances are approximately 0.25 A ˚ shorter than the sum of the respective van der Waals radii (Batsanov, 2001) and constitute about 33.8 and 5.7%, ...
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Crystal structure of fac tricarbonyl(quinoline 2 carboxylato κ2N,O)(triphenylarsane κAs)rhenium(I)
... Tc, Re) has expanded continuously with the development of suitably derivatized novel ligand systems which efficiently displace the coordinating water molecules to produce complexes with high in vivo stability, favorable ...
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Crystal structures of a manganese(I) and a rhenium(I) complex of a bipyridine ligand with a non coordinating benzoic acid moiety
... in I and II, the benzoate substituent in these complexes is deprotonated and coordinates to the metal forming a seven- membered chelate ...in I and II would be expected to disfavor deprotonation of the ...
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Formation of Thin Rhenium Films on Nickel Plate by its Chloride Electrolysis
... the rhenium discharge at the cathode is originated by the chlorinate ...metallic rhenium crystallization, as opposed to other aqueous ...the rhenium deposits obtained from the alkali water solution ...
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fac Bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate
... The title compound, (I), was prepared as a standard molecule for comparison with the properties of other heterocyclic tri- carbonylrhenium(I) complexes containing pyridine as the sixth ligand. Complexes of ...
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Aquatricarbonyl(4 carboxypyridine 2 carboxylato κ2N,O2)rhenium(I)
... The Re(I) core is coordinated by three facial carbonyl groups, one pyridine-2-carboxylato-4-carboxylic acid ligand and a water molecule. A slightly distorted octahedral geometry around the Re(I) metal ...
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