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DISTORTED OCTAHEDRAL COORDINATION GEOMETRY

Acetato­(methanol)[N phenyl N,N bis­(2 pyridyl­methyl)­amine]copper(II) hexa­fluoro­phosphate

Acetato­(methanol)[N phenyl N,N bis­(2 pyridyl­methyl)­amine]copper(II) hexa­fluoro­phosphate

... In the cation of the title complex, (I) (Fig. 1), atom Cu1 displays distorted octahedral coordination geometry (Fig. 2 and Table 1). The three N atoms of the phbpa ligand are approximately ...

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Bis(3 methyl­benzoato κ2O,O′)(phenanthroline κ2N,N′)copper(II)

Bis(3 methyl­benzoato κ2O,O′)(phenanthroline κ2N,N′)copper(II)

... atom is located on a twofold axis and is surrounded by a phenanthroline (phen) molecule and two methylbenzoate anions in a distorted octahedral coordination geometry. Two O atoms from carboxyl ...

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catena Poly[[[di­aqua­calcium(II)] μ oxydi­acetato [tetra­aqua­manganese(II)] μ oxydi­acetato] dihydrate]

catena Poly[[[di­aqua­calcium(II)] μ oxydi­acetato [tetra­aqua­manganese(II)] μ oxydi­acetato] dihydrate]

... a distorted tetragonal antiprism coordination ...a distorted octahedral coordination geometry formed by four water molecules and two carboxyl O atoms from monodentate ODA ...

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Di­aqua­bis­(4 hy­droxy­benzoato κO)(1,10 phenanthroline κ2N,N′)­cobalt(II) monohydrate

Di­aqua­bis­(4 hy­droxy­benzoato κO)(1,10 phenanthroline κ2N,N′)­cobalt(II) monohydrate

... a distorted octahedral coordination geometry about the Co II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline (phen) molecule and two water mol- ...

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trans Bis(3 hy­droxy 2 phenyl 4H 1 benzo­pyran 4 onato)­bis­­(pyridine)copper(II)

trans Bis(3 hy­droxy 2 phenyl 4H 1 benzo­pyran 4 onato)­bis­­(pyridine)copper(II)

... The coordination bond distance in the axial direction, Cu1ÐN1, is longer than those in the equatorial ...the distorted octahedral coordination geometry of the Cu II complexes ...

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Bis(5 amino 1H tetra­zole κN4)di­aqua­(oxalato κ2O1,O2)cadmium

Bis(5 amino 1H tetra­zole κN4)di­aqua­(oxalato κ2O1,O2)cadmium

... a distorted octahedral coordination geometry, with the equatorial plane defined by two O atoms from an oxalate ligand and two N atoms from two 5-amino- 1H-tetrazole ligands; the axial sites ...

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Aqua­bis­(1H imidazole κN3)bis­­(4 methyl­benzoato κ2O,O′)cobalt(II)

Aqua­bis­(1H imidazole κN3)bis­­(4 methyl­benzoato κ2O,O′)cobalt(II)

... distinct coordination modes, namely monodentate and ...a distorted octahedral coordination geometry, defined by three O atoms from the 4- methylbenzoate ligands [the Co O3 distance is ...

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catena Poly[(di­aqua­cadmium) μ iminodi­acetato κ4O,N,O′:O′′]

catena Poly[(di­aqua­cadmium) μ iminodi­acetato κ4O,N,O′:O′′]

... a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water ...

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Di μ2 acetato 1:2κ2O:O′;2:3κ2O:O′ bis­­{μ2 4,4′ di­chloro 2,2′ [2,2 di­methyl­propane 1,3 diylbis(nitrilo­methanylyl­­idene)]diphenolato} 1:2κ6O,N,N′,O′:O,O′;2:3κ6O,O′:O,N,N′,O′ tri­cadmium

Di μ2 acetato 1:2κ2O:O′;2:3κ2O:O′ bis­­{μ2 4,4′ di­chloro 2,2′ [2,2 di­methyl­propane 1,3 diylbis(nitrilo­methanylyl­­idene)]diphenolato} 1:2κ6O,N,N′,O′:O,O′;2:3κ6O,O′:O,N,N′,O′ tri­cadmium

... a distorted octahedral coordination geometry formed by four O atoms from two bidentate/ tetradentate Schiff base ligands and two O atoms from two bridging acetate ...The coordination ...

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catena Poly[[[di­aqua­cobalt(II)] bis­­{μ 2 [3 (4 carboxyl­atophen­yl)pyridin 1 ium 1 yl]acetato}] dihydrate]

catena Poly[[[di­aqua­cobalt(II)] bis­­{μ 2 [3 (4 carboxyl­atophen­yl)pyridin 1 ium 1 yl]acetato}] dihydrate]

... a distorted octahedral coordination geometry defined by four O atoms from two pairs of equivalent monodentate carboxylate groups from 2-[3-(4- carboxylatophenyl)pyridin-1-ium-1-yl]acetate ...

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(μ Perfluoro­sebacato κ2O:O′)bis­­[aqua­bis­(1,10 phenanthroline κ2N,N′)zinc(II)] perfluoro­sebacate bis­­[tri­aqua­(perfluoro­sebacato κO)(1,10 phenanthroline κ2N,N′)zinc(II)] 3 32 hydrate

(μ Perfluoro­sebacato κ2O:O′)bis­­[aqua­bis­(1,10 phenanthroline κ2N,N′)zinc(II)] perfluoro­sebacate bis­­[tri­aqua­(perfluoro­sebacato κO)(1,10 phenanthroline κ2N,N′)zinc(II)] 3 32 hydrate

... a distorted octahedral coordination geometry, defined by four N atoms from two chelating phen ligands and an O atom from the carboxylate group of a bridging perfluorosebacate ligand and the O ...

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catena Poly[[bis­­(N,N di­methyl­formamide κO)nickel(II)] di μ 1,5 dicyanamido κN1:κN5]

catena Poly[[bis­­(N,N di­methyl­formamide κO)nickel(II)] di μ 1,5 dicyanamido κN1:κN5]

... The coordination geometry of the nickel(II) atom is distorted octahedral, being coordinated by four N atoms of four symmetry-related dca ligands in the equatorial plane and two O atoms of two ...

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A novel triple stranded cadmium(II) polymer chain: catena poly[cadmium(II) μ 1,2 bis­­(imidazol 1 yl)­ethane κ2N3:N3′ di μ 1,5 dicyanamido κ4N1:N5]

A novel triple stranded cadmium(II) polymer chain: catena poly[cadmium(II) μ 1,2 bis­­(imidazol 1 yl)­ethane κ2N3:N3′ di μ 1,5 dicyanamido κ4N1:N5]

... the coordination about the cadmium(II) center in ...The coordination geometry of the Cd II atom is distorted octahedral, being coordinated by four N atoms of four symmetry-related dca ...

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Synthetic and Structural Studies of Some Bivalent Transition Metal Complexes with Oxygen and Nitrogen Containing Schiff Base

Synthetic and Structural Studies of Some Bivalent Transition Metal Complexes with Oxygen and Nitrogen Containing Schiff Base

... and coordination proposes through amine nitrogen, imine nitrogen and Carbonyl oxygen atom of semicarbozone ...have octahedral geometry where as distorted octahedral geometry is ...

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Poly[bis­­[μ 1,4 bis­­(imidazol 1 yl)butane]di­cyanato­nickel(II)]

Poly[bis­­[μ 1,4 bis­­(imidazol 1 yl)butane]di­cyanato­nickel(II)]

... The coordination geometry of the Ni II atom is distorted octahedral, with four N atoms from the imidazole rings of the bimb ligands in the equatorial posotions [Ni1—N2 = ...

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cis Bis(8 hy­droxy­quinolinato κ2N,O)­di­phenyl­tin(IV)

cis Bis(8 hy­droxy­quinolinato κ2N,O)­di­phenyl­tin(IV)

... nation geometry at the Sn atom of the more bulky phenyl group as the R ...the coordination geometry about the Sn atom, are given in Table ...usual distorted cis- octahedral ...

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A one dimensional coordination polymer of copper(II) with 2 pyrazine­carboxyl­ate

A one dimensional coordination polymer of copper(II) with 2 pyrazine­carboxyl­ate

... The coordination environment of the copper(II) ion shows a distorted octahedral geometry, arising from an N,O-bidentate pzca ligand, an N atom from a symmetry-related pzca ligand, a bidentate ...

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Bis(1,1,1,5,5,5 hexa­fluoro­acetyl­acetonato κ2O,O′)­bis­­(tetra­hydro­furan κN)­iron(II)

Bis(1,1,1,5,5,5 hexa­fluoro­acetyl­acetonato κ2O,O′)­bis­­(tetra­hydro­furan κN)­iron(II)

... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ...

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SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL STUDIES OF TRANSITION METAL COMPLEXES OF ONO CHELATING SCHIFF BASE HYDRAZONE LIGAND (E) N' (1 (4  HYDROXY 1 METHYL 2 OXO 1,2 DIHYDROQUINOLIN 3  YL)ETHYLIDENE) 4 METHOXY BENZOHYDRAZIDE

SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL STUDIES OF TRANSITION METAL COMPLEXES OF ONO CHELATING SCHIFF BASE HYDRAZONE LIGAND (E) N' (1 (4 HYDROXY 1 METHYL 2 OXO 1,2 DIHYDROQUINOLIN 3 YL)ETHYLIDENE) 4 METHOXY BENZOHYDRAZIDE

... The Mn(II) complex has a magnetic moment 5.66 BM indicating the presence of five unpaired electrons in agreement with high spin octahedral complex. [16,17] The Fe(III) complex shows magnetic moment 5.77 BM ...

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catena Poly[[(2,2′ bi­pyridine κ2N,N′)manganese(II)] μ 3,5 di­nitro 2 oxidobenzoato κ4O,O′:O′,O2]

catena Poly[[(2,2′ bi­pyridine κ2N,N′)manganese(II)] μ 3,5 di­nitro 2 oxidobenzoato κ4O,O′:O′,O2]

... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ...

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