Dynamic Metal-Organic Frameworks
Mechanically Interlocked Linkers for Dynamic Metal-Organic Frameworks
... of dynamic motion of the wheel component in the solid- state is crucial to the future development of molecular switches inside these materials and ultimately the ability of the material to function as a molecular ...
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Bioengineering of Metal-organic Frameworks for Nanomedicine
... complex organic chemical that living cells use it to provide energy to drive further many biological ...the metal node of ZIF-90 and ATP can disassemble the structure of ZIF-90, thus releasing the Rhodamine ...
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The Use of Microscopy and Spectroscopy to Probe the Dynamic Behaviours of Metal-Organic Frameworks and their Guests.
... advantages. Organic delivery systems, such as micelles, often suffer from poor drug loadings and inefficient and uncontrolled release of therapeutic ...of frameworks with targeting functionality or via ...
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Dynamic studies of guest molecules in Metal-Organic Frameworks using Solid-State NMR
... First of all, I would like to give my deepest gratitude to my supervisor, Professor Yining Huang. Without him, I would not have started such an amazing journey. With his continuous support, I have had a very pleasant ...
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Reticular Synthesis of Metal-Organic Rotaxane Frameworks
... The incorporation of mechanically interlocked molecules (MIMs) within solid- state materials is an effort to produce these robustly dynamic materials. By restricting the effects of Brownian motion and producing ...
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Characterisation of metal organic frameworks for adsorption cooling
... The adsorption characteristics of Silica gel RD-2060, HKUST-1 and MIL-100 were determined using an advanced gravimetric dynamic vapour sorption analyser (DVS). Results showed that HKUST-1 performed better than ...
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Tunable Metal-Organic Frameworks for Heat Transformation Applications
... MOF materials having a pillared-layer structure using Cu 2+ , Na 2 pzdc (pzdc=pyrazine-2,3- dicarboxylate), and a series of pillar ligands of pyridine derivatives were synthesized by Kitagawa[52] The structure of Cu 2 ...
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Mechanistic insight into the sensing of nitroaromatic compounds by metal-organic frameworks
... and dynamic quenching processes at higher concentration of analytes, the lifetime study showed that the quenching of NACs in water originates mainly from the static ...the dynamic nature of RET being ...
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Host-guest dynamics in copper-based metal-organic frameworks
... and dynamic host-guest interactions of the ...these frameworks are extremely robust and survived dehydration under dynamic vacuum at 150 °C for 24 h to afford crystals of the apohosts 1, 2 and ...
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A molecular simulation study of CO2 adsorption in metal-organic frameworks
... To date, molecular simulations method is regarded as the one of the most prospective technology to predict the gas adsorption properties within porous materials such as MOFs and zeolites. Molecular simulations mainly ...
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Dynamic Studies of Guest Molecules in Metal-Organic Frameworks and Zeolites via Solid-State Nuclear Magnetic Resonance
... the metal centres and organic linkers using SSNMR, the coordination numbers and local chemical environments of metal centres as well as linker orientations and interactions can be ...from ...
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CNRS METAL-ORGANIC FRAMEWORKS
... These materials are organized as mono-, bi- or tri-dimensional networks wherein the metal clusters are linked to each other by spacing ligands periodically. These materials have a crystalline structure and are ...
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Defective Metal-Organic Frameworks
... The targeted incorporation of defects into crystalline matter allows for the manipulation of many properties and has led to relevant discoveries for optimized and even novel technological applications of materials. It is ...
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Metal Organic Frameworks: An overview and their applications
... Synthesis of MOFs MOFs can be synthesized by various conventional methods that are reported in literature such as hydrothermal or solvothermal, sonochemical synthesis, microwave assisted [10], electrochemical [11] and ...
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Strategic immobilisation of catalytic metal nanoparticles in metal organic frameworks
... within metal-organic ...small metal nanoparticles are immobilised within the porous network of the MOF ...support. Metal salts are deposited in the MOF and then reduced to form well-dispersed ...
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Hydrolytic stability in hemilabile metal–organic frameworks
... the metal or the linker) to increase the strength of the bonding in the ...oxidation metal ions, such as Zr IV in MOFs such as UiO-66, 7 and changing the linker units to groups such as pyrazolate, 8 both of ...
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Synthesis of metal organic frameworks by continuous flow
... Introduction Metal-organic frameworks (MOFs) are currently the focus of intense scientific interest due to their wide range of potential applications in gas storage 1,2 and separation, 3 catalysis, ...
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Crystallographic studies of gas sorption in metal-organic frameworks.
... Thus, the interior surfaces of most MOFs permit only rela- tively weak interactions with adsorbed guest molecules, including gases. A growing number of MOFs contain addi- tional functional groups, either as part of ...
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Urea-containing metal-organic frameworks as heterogeneous organocatalysts
... unsaturated metal sites (group I), MOFs with metalloligands (group II), MOFs with functional organic sites (group III) and metal nanoparticles embedded in the MOF cavities (group ...functional ...
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Metal-Organic Frameworks-Based Electrochemical Sensors and Biosensors
... Small organic molecules can be directly detected by electrochemical methods based on the electrochemical oxidation or ...adsorb organic molecules through strong π-π, charge donor–acceptor and electrostatic ...
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