Lanthanide Complexes
Design and development of novel self assembled luminescent lanthanide complexes in solution and in soft materials
... A reusable gel probe based upon the luminescence of lanthanide complexes that was ‘litmus-like’ in response was developed. However, since the swelled polymer gels had a diffusion control on the ...
359
Utilization of mononuclear trivalent lanthanide complexes for the assembly of heteronuclear (d-f) metal complexes
... Comparison plot of temperature dependent magnetic anisotropics (Ax) calculated from Bleaney's equation (big dashed line), McGarvey's equation (small dashed line) and CONDON (grey line)[r] ...
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DFT study of half sandwich bis (tetramethylaluminate) lanthanide complexes
... evidenced by η 1/2/3 coordination modes [8]. This coordination has been analyzed by AIM approach of Bader and coworkers [19, 20]. This method tells us that there is one bond critical point (BCP) between each pair of ...
9
Synthesis and spectral analysis of some new lanthanide complexes derived from 2,4 and 2,5 dihydroxy acetophenones and screened their antimicrobial activity
... as complexes was tested against some clinically important bacteria by the disc diffusion method [26] using Mueller- Hinton agar ...their complexes were prepared in DMSO (200 ...
6
Structural and reductive chemistry of low valent lanthanide complexes featuring modified porphyrinogens
... The molecular structure of both complexes contain single lanthanide metal centres bound in alternate 1-1 I 11 5 :11 I fashion with Ti I -binding to the anionic pyrrolide nitrogens and 11[r] ...
239
Synthesis, fluorescent studies, antioxidative and α-amylase inhibitory activity evaluation of some lanthanide(III) complexes
... ide(III) complexes are the most important components in pursuit of new lumin- escence ...of lanthanide complexes and their potential applications were the encouragement to continue studies on some ...
14
Synthesis, characterization, fluorescent and antimicrobial properties of new Lanthanide(III) complexes derived from coumarin Schiff base
... Yb(III) complexes have been synthesized with the Schiff base (PHC) derived from the condensation of 8- formyl-7-hydroxy-4-methyl-coumarin with 3-amino ...their lanthanide complexes have been ...
18
Synthesis, Characterization and Photophysical properties of Lanthanide (III) Complexes with dicyandiamide in 2 ethoxyethanol
... novel lanthanide (Tb 3+ , Eu 3+ , Gd 3+ , Sm 3+ and Dy 3+ ) complexes with dicyandiamide in 2- ethoxyethanol were synthesized and ...these complexes were studied using ultraviolet-visible absorption ...
11
SYNTHESIS, SPECTRAL CHARACTERIZATION AND DNA BINDING PROPERTIES OF LANTHANIDE (III) COMPLEXES WITH 2 FORMYLPYRIDINE NICOTINOYLHYDRAZONE
... of lanthanide complexes with polydentate ligands have received considerable attention because of their potential applications in various fields 1-6 ...newer lanthanide complexes is a potential ...
6
Exploring Lanthanum Sulphide Characteristics For Its Physical Properties
... the lanthanide complexes because they possess strong luminescent ...encapsulated lanthanide ion from interaction with the surroundings effectively, and thus help to achieve strong luminescent ...
5
Preparation and Characterization of Lanthanide (III) Chloride Complexes with 2-Aminothiazole (ATZ)
... cationic complexes derived from N-donors could not be isolated from aqueous media prompted the assumption that Ln +3 -N interactions were necessarily weaker than Ln +3 -O ...of lanthanide ions to coordinate ...
7
Tris(thiocyanato κN)tris(triphenylphosphine oxide κO)terbium(III)
... related lanthanide complexes containing triethylphosphine oxide ligands, the larger, lighter lanthanide ions contain three phosphine ligands and the smaller, heavier lanthanide ions contain ...
14
Model Compounds of Trivalent and Tetravalent Lanthanide Metal Complexes for Elucidating Rational Reactivities
... metal complexes with 2,6-bis(dimethylamino)methyl- 4-phenolate (bdmmp – ) were first reported by the van Koten group for Lu(III) and ...copper-lanthanide complexes of bdmmp using Pr(III) and ...
357
ELECTRONIC SPECTRAL CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF LANTHANIDE (III) - CEFTAZIDIME COMPLEXES
... Lanthanide complexes is appealing in bioinorganic and coordination chemistry, because lanthanide ions have a tendency to form complex with coordination number greater than six, even up to twelve ...
9
The Effect of the Secondary Coordination Sphere on the Stabilities of Cerium(III) and Cerium(IV) Coordination Complexes
... naphtholate complexes with lithium, sodium, potassium and tetramethylguanidinium cations in the secondary coordination sphere was ...naphtholate complexes showed solvent-dependent solution and solid state ...
564
Quantum mechanical and synthetic studies of coordination and organometallic complexes of lanthanides and other heavy metals
... the lanthanide series is crossed does not generally result in a significant change of chemical properties, particularly for the Ln^'*’ ...the lanthanide series, despite the different electronic ...
166
Poly[triaqua(μ hydrogen tartrato)(μ tartrato)samarium(III)]
... of lanthanide ions and the inherent flexibility of their coordination geometries might lead to some unprecedented topological architectures (Long et ...using lanthanide ions as nodes in the construction of ...
10
SPECTRAL CHARACTERIZATION AND DNA BINDING PROPERTIES OF LANTHANIDE (III) COMPLEXES WITH 2 ACETYLPYRIDINE NICOTINOYLHYDRAZONE (APNH)
... such complexes is relatively less when compared with transition metal complexes with this class of ...of lanthanide complexes is of interest owing to their applications in biology and ...metal ...
11
Synthetic and theoretical studies of lanthanide imide and alkene complexes
... Also described are the synthesis of dibenzotropylidene based ligands and subsequent Group 1 metal complexes as pre-cursors for lanthanide complexes bearing alkene interactions, of releva[r] ...
262
SPECTROSCOPIC PROPERTIES OF THE Ln-Ge COMPLEXES WITH DIETHYLENETRIAMINEPENTAACETIC ACID
... heteronuclear complexes involves the great interest in coordination ...the complexes internal coordination sphere of which includes simultaneously two different metals and ...heteronuclear lanthanide ...
5