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Metal and anion binding properties of the

Structural, spectroscopic and anion binding properties of 5,10 porphodimethenes, an unusual class of calixphyrins

Structural, spectroscopic and anion binding properties of 5,10 porphodimethenes, an unusual class of calixphyrins

... of metal ions into the hydroporphyrin ...the anion recognition features of sapphyrin dications, it is likely that the closely related PDMs could be used as receptors for small molecules and ...

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Synthesis, Characterization and Anion Binding Properties of Boron-based Lewis Acids

Synthesis, Characterization and Anion Binding Properties of Boron-based Lewis Acids

... of anion recognition has become a very active research area fueled by the role that these species play in biological systems and in the ...azide anion (N 3 − ) possess an analogous biological profile and is ...

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Structure And Metal Binding Properties Of A Poxvirus Resolvase

Structure And Metal Binding Properties Of A Poxvirus Resolvase

... Gregory D. Van Duyne Poxviruses, including smallpox virus, replicate their linear genomes by forming concatemers that must be resolved into monomeric units in order to produce new virions. Poxviruses encode a resolvase ...

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A Computational Study of Procyanidin Binding to Histatin 5 and Thermodynamic Properties of Hofmeister-Anion Binding to a Hydrophobic Cavitand

A Computational Study of Procyanidin Binding to Histatin 5 and Thermodynamic Properties of Hofmeister-Anion Binding to a Hydrophobic Cavitand

... 5 binding to EGCG used 3 mM peptide and ...5 binding studies, the EGCG-Histatin 5 dissociation constant was determined to be about 1 mM with ...EGCG binding sites per peptide, though another study ...

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Activation of Weak Nucleophiles in Anion-Binding Catalysis

Activation of Weak Nucleophiles in Anion-Binding Catalysis

... electronic properties of the protecting groups can strongly influence the stereochemical outcome, the synthesis of a specific linkage pattern requires a tailored approach using a unique combination of substrates ...

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Effects of Secondary Binding Motifs in Arylethynyl Anion Receptors

Effects of Secondary Binding Motifs in Arylethynyl Anion Receptors

... for anion sensing, we also laid-out an array sensing platform with sixteen phenylethynyl bis-urea ...of anion sensing arrays with the receptor scaffolds studied in our ...

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Enantioselective Nucleophilic Dearomatization of Heteroarenes by Anion-Binding-Catalysis

Enantioselective Nucleophilic Dearomatization of Heteroarenes by Anion-Binding-Catalysis

... Triazole-Based Anion-Binding Catalysis for the Enantioselective Dearomatization of N-Heteroarenes with Different Nucleophiles Abstract: The first enantioselective synthesis of chiral heterocyclic α-amino ...

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Building Metal-Anion Layers within a Preovskite Host

Building Metal-Anion Layers within a Preovskite Host

... extensively studied. The distinctive feature of these compounds is the electronic configuration of the d 0 transition metal on the B site. It is known that d 0 cation in a octahedral environment has an ...

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Structures and metal-ion-binding properties of the Ca 2 + -binding helix–loop–helix EF-hand motifs

Structures and metal-ion-binding properties of the Ca 2 + -binding helix–loop–helix EF-hand motifs

... the binding of Ca 2+ to the unbound form stabilizes certain substates at the expense of others, as it results in structural changes in the EF-hands which decrease the frequency with which the closed substates are ...

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Adamantane bisurea derivatives: anion binding in the solution and in the solid state

Adamantane bisurea derivatives: anion binding in the solution and in the solid state

... 3). Titration in DMSO caused less pronounced changes in the UV-vis spectra. This finding correlates with several orders of magnitude smaller values of the association constants due to competition of DMSO for solvation of ...

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Anion exchange separations of metal ions in partially nonaqueous solutions

Anion exchange separations of metal ions in partially nonaqueous solutions

... of metal ions in partially nonaqueous solutions Abstract A systematic approach to anion exchange in partially nonaqueous solvents was ...of metal ions for Dowex 1 X8, chloride form resin in organic ...

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The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7

The hydride anion in an extended transition metal oxide array: LaSrCoO3H0.7

... transition metal oxide hydride, LaSrCoO 3 H ...The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering up to at least 350 ...transition ...

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Metal ion binding properties of Tricium aestivum Ec-1 metallothionein: evidence supporting two separate metal thiolate clusters

Metal ion binding properties of Tricium aestivum Ec-1 metallothionein: evidence supporting two separate metal thiolate clusters

... nondenaturing conditions has been described [35]. In the case of T. aestivum Cd 6 E c -1, the digestion mixture is eluted from the gel filtration column in the form of two peaks, both with longer elution times and thus ...

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Binding Layer Properties

Binding Layer Properties

... of binding at and within the binding layer is slow, the accumulation can still be represented by steady state conditions, but the accumulation at any given time will be less than expected for rapid ...

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Anion Exchange Membrane Production for Protein Molecular Weight Binding Studies.

Anion Exchange Membrane Production for Protein Molecular Weight Binding Studies.

... There are several other options that could replace packed bed chromatography for protein purification. These include bulk, field-based and adsorptive separations. Bulk separations include phase extractions and ...

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Halogen substituted ureas for anion binding: solid state and solution studies

Halogen substituted ureas for anion binding: solid state and solution studies

... for anion binding: solid state and solution ...the anion binding properties of a family of N,N’-diphenylureas L 1 -L 15 , bearing on the aromatic ring(s) halogens (chlorine and iodine) ...

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Metal ion binding properties of L glutamic acid and L aspartic acid, a comparative investigation

Metal ion binding properties of L glutamic acid and L aspartic acid, a comparative investigation

... Inorganic metal ions may serve as a catalyst to further the oxidation and deg- radation of ...that metal ions are not enough shielded. As consequence metal ions can take part in substitution ...

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Supporting Information. Direct Assembly and Metal-Ions Binding Properties of Oxytocin Monolayer on Gold Surfaces

Supporting Information. Direct Assembly and Metal-Ions Binding Properties of Oxytocin Monolayer on Gold Surfaces

... The Zn²⁺ is bonded to two lone pair oxygen atoms; (d) The mean square displacement of Zn²⁺/oxytocin on Au(111) surface... S11[r] ...

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PROPERTIES AND USES OF METAL

PROPERTIES AND USES OF METAL

... 1 PROPERTIES AND USES OF METAL In the seabees, Steelworkers are the resident experts on the properties and uses of ...repair metal items, resurface worn machinery parts, and fabricate all ...

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Metal-oxygen decoordination stabilizes anion redox in Li-rich oxides.

Metal-oxygen decoordination stabilizes anion redox in Li-rich oxides.

... between O redox in LISO and a range of other Li-rich layered oxides 6, 31, 44 suggest that oxygen 469. redox may be generally stabilized in the local coordination environments created [r] ...

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