Nanoparticle synthesis via RAFT emulsion polymerisation
Synthesis of mannosylated and PEGylated nanoparticles via RAFT emulsion polymerisation, and investigation of particle lectin aggregation using turbidimetric and DLS techniques
... (2016) Synthesis of mannosylated and PEGylated nanoparticles via RAFT emulsion polymerisation, and investigation of particle- lectin aggregation using turbidimetric and DLS techniques..[r] ...
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Continuous Flow Platforms for the Synthesis and Optimisation of Polymeric Materials via RAFT Polymerisation
... DCTTC RAFT agent NMR kinetics (Figure ...the polymerisation likely caused by premature termination reducing the number of propagating polymer ...the RAFT agent and monomer. As discussed in chapter 1, ...
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Methacrylic block copolymers by sulfur free RAFT (SF RAFT) free radical emulsion polymerisation
... radical polymerisation systems (NMRP, RAFT and ATRP) under effective emulsion conditions has proved to be somewhat ...based RAFT to see how it compares given its neglect and almost absence ...
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Synthesis of DNA polymer conjugates using RAFT polymerisation
... Other hydrophilic polymers have been attached to DNA, and this has led to conjugates for use in a diverse range of applications. These include carriers for delivery of small interfering RNA, 60 DNA detection, 61-64 ...
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Exploring the design, synthesis and function of novel block copolymer systems prepared via RAFT polymerisation
... proceed via interaction of the positively charged guanidinium group with negatively charged lipid membranes, thus disturbing the membrane ...phase synthesis, a technique which also possesses rather ...
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Fluorescent labelling and biodistribution of latex nanoparticles formed by surfactant free RAFT emulsion polymerisation
... The synthesis is utilized via the use of chain transfer agent (CTA)-end-capped diblock copolymers in ...surfactant-free RAFT emulsion ...
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Synthesis of High Molecular Weight Poly(glycerol monomethacrylate) via RAFT Emulsion Polymerization of Isopropylideneglycerol Methacrylatefree
... obtained via hydrolysis of a cheap commodity monomer, glycidyl methacrylate, in aqueous solution, 26 but in practice it is actually prepared via a protected precursor, isopropylideneglycerol ...
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Synthesis of glyconanoparticles via Emulsion Polymerisation Techniques and their use to probe lectin interactions and in pH responsive drug delivery
... Next to vesicles, protein nanoparticles are one of the most common clinically used nanoparticle formulations. 34, 35 Protein nanoparticles are most commonly composed of a protein conjugated to a drug, in efforts ...
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Sequence controlled methacrylic multiblock copolymers via sulfur free RAFT emulsion polymerization
... quantitative synthesis of sequence-controlled multiblock polymers in discrete stable nanoscale compartments via an emulsion polymerization approach in which a vinyl-terminated macromolecule is used ...
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Synthesis of well-defined epoxy-functional spherical nanoparticles by RAFT aqueous emulsion polymerization
... prepared via RAFT aqueous emulsion polymerization of glycidyl methacrylate using a water-soluble poly(glycerol monomethacrylate) precursor as the stabilizer ...prepared via seeded RAFT ...
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Poly(glycerol monomethacrylate)–Poly(benzyl methacrylate) Diblock Copolymer Nanoparticles via RAFT Emulsion Polymerization: Synthesis, Characterization, and Interfacial Activity
... This water-soluble precursor was chain-extended using styrene to form a series of diblock copolymer nanoparticles. 16 Polymerization-induced self-assembly (PISA) led to the formation of spheres, fi bers or vesicles ...
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Synthesis of ultra high molecular weight ABA triblock copolymers via aqueous RAFT mediated gel polymerisation, end group modifications and chain coupling
... The conversion of a thiocarbonylthio group into a thiol in the presence of nucleophiles or ionic reducing agents is one of the most widely reported techniques of end group modification for RAFT polymers. 19 ...
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Synthesis, characterisation and Pickering emulsifier performance of poly(stearyl methacrylate)–poly(N-2-(methacryloyloxy)ethyl pyrrolidone) diblock copolymer nano-objects via RAFT dispersion polymerisation in n-dodecane
... A high proportion of the phase space shown in Fig. 5 rep- resents mixed phases where two or more morphologies co- exist. The ‘pure’ worm phase is defined as more than 95% of nano-objects analysed by TEM being classified ...
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Epoxy-functional sterically stabilized diblock copolymer nanoparticles via RAFT aqueous emulsion polymerization: Comparison of two synthetic strategies
... the RAFT aqueous emulsion polymerization of glycidyl methacrylate to produce spherical diblock copolymer nanoparticles containing epoxy groups in the core-forming ...the synthesis of spherical ...
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Reversible addition fragmentation chain transfer emulsion polymerisation for preparation of biologically compatible nanoparticles
... of nanoparticle rigidity on the degree, rate and mechanism of uptake by mammalian cells (PC3 and ...uptake via caveolae-mediated endocytosis of hard > ...
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RAFT emulsion polymerization as a platform to generate well defined biocompatible latex nanoparticles
... 6. RAFT emulsion polymerization to produce biocompatible PEGylated nanoparticles is ...This synthesis approach allows for different core composition and particle sizes to be ...high ...
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Looped flow RAFT polymerization for multiblock copolymer synthesis
... prepared via RAFT using a one-pot iterative addition process through careful optimization of polymerisation conditions to achieve quantitative monomer conversion whilst maintaining high end- group ...
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Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems
... on emulsion polymerisation involving in situ formed amphiphilic block copolymers yielded spherical ...accessed via this ...situ polymerisation adds extra complications, such as unreacted ...
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Preparation of inert polystyrene latex particles as microRNA delivery vectors by surfactant free RAFT emulsion polymerization
... successful synthesis of amphiphilic HOOC-PAAm 14 -b-PS 8 diblock copolymer mediated by RAFT ...nanoparticles via surfactant-free RAFT emulsion ...linkers via EDC/NHS ...
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Aqueous RAFT polymerisation of acrylamide monomers
... the RAFT agent and consequently on the ...the RAFT process, and consequently the properties of the newly obtained ...spontaneous polymerisation of AMPS ® was observed when NaOH, was added in ...
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