OXIDATION STATE
EXPLORING THE REACTIVITY OF INDIUM(I) TRIFLATE AND RELATED LOW OXIDATION STATE INDIUM SALTS
... particular oxidation state (or, perhaps more appropriately, valence state) [1] is one of the most simple and ubiquitous models employed by chemists to explain the structural characteristics and ...
209
Low oxidation state Group 15 cations: Synthesis, reactivity and computational studies.
... Finally, a comment about the chemical drawings used in this dissertation is warranted. Because a given molecule can be depicted in various manners, the oxidation state o f the Pn atom contained therein ...
267
The role of the copper oxidation state in the electrocatalytic reduction of CO2 into valuable hydrocarbons
... characterized. The electrochemically prepared copper-redox electro-cathodes yield higher activity for the production of hydrocarbons at lower oxidation state. By combining advanced X-ray spectroscopy and in ...
17
Ultrafast elemental and oxidation state mapping of haematite by 4D electron microscopy
... The Fe L-edge core-loss EELS corresponds to the excitation of an Fe 2p core electron in haematite to an unoccupied 3d or- bital with an energy loss of over 700 eV (Figure 1e and 1f). Its peak position and shape are ...
8
“Higher Oxidation State Organopalladium and Platinum Chemistry”104-109
... two oxidation state interchanges at higher oxidation state levels in organopalladium and organoplatinum ...+IV oxidation state in homogeneous reactions catalysed by organopa ...
6
Crystal structures of two unusual, high oxidation state, 16 electron iridabenzenes
... metallabenzenes. Structural elucidation of (I) and (II) reveals that these isotypic iridabenzenes are unusual, not only in their electron count, but also in their coordination sphere of the Ir III atom where they contain ...
17
Quantification of Fe-oxidation state in mixed valence minerals: a geochemical application of EELS revisited
... Diagenetic chlorites are a common component of many sedimentary rocks. In most settings aluminous dioctahedral chlorites are rarer than ferro-magnesian trioctahedral types, however in some iron oxide- rich ‘red beds’ ...
5
Preparation of Reactive and Additive Flame Retardant with Different Oxidation State of Phosphorus on the Thermal and Flammability of Thermoplastic Polyurethane
... different oxidation state of phosphorus in phosphorus-based flame retardants on the thermal and flame retardant properties of ...different oxidation states of phosphorus (triphenylphosphite (TPPI) ...
11
A Straightforward Electrochemical Approach to Imine- and Amine-bisphenolate Metal Complexes with Facile Control Over Metal Oxidation State
... Synthetic methods to prepare organometallic and coordination compounds such as Schiff-base complexes are diverse, with the route chosen being dependent upon many factors such as metal–ligand combination and metal ...
6
Oxidation State of 229Th Recoils Implanted into MgF2 Crystals
... isomeric state [20]. As will be shown below, the oxidation state of the implanted thorium atoms greatly influences the band ...preferred oxidation state due to the closed shell, ...
11
Modification in polyaniline oxidation state as a consequence of anthracene doping
... in oxidation state of polyaniline was studied with respect to anthracene ...2) oxidation of polyaniline macromolecules by anthracene, through the formation of charge transfer ...the oxidation ...
8
Stabilization and Reactivity of Low Oxidation State Indium Compounds
... normal oxidation state, it is important to define some of the types of models employed to describe coordination chemistry, namely: oxidation state, valence state and coordination ...an ...
191
Oxidation state of a polyurethane membrane after plasma etching
... the oxidation state is most likely Si ...+3 oxidation state is likely to be as a result of coordination with 3 oxygen atoms and 1 carbon atom ((CH 3 ) SiO 3/2 ) [8, ...
12
In vivo comparison of cerebral tissue PO2 and cytochrome aa3 reduction oxidation state in cats during hemorrhagic shock
... To assess the adequacy of oxygen availability and utilization within the cerebral cortex in vivo, we have measured the partial pressure of oxygen in tissue (PtO2), as well as the reduction oxidation state ...
8
Accessing low oxidation state taxanes: is taxadiene 4(5) epoxide on the taxol biosynthetic pathway?
... Having shown that the two step epoxidation/Fe III induced rearrangement mimics that seen in vivo (tobacco) mediated by taxa-4(5),11(12)-diene 5-hydroxylase (CYP725A4), we wondered if the initial oxidation of ...
6
Formation of todorokite from “c-disordered” H+-birnessites: the roles of average manganese oxidation state and interlayer cations
... 11]. Oxidation of the Mn(II) located above or below vacant sites facilitates the forma- tion of a stable todorokite-like structure during marine diagenesis and hydrothermal process ...
11
The oxidation state of deeply subducted, altered oceanic crust: an experimental study and the evidence from natural samples
... If the garnet grains of interest are smaller than 50 microns, and are part of an assemblage containing other Fe-bearing phases, it could conceivably be underlain in a polished section by another iron-bearing phase. ...
307
Intermediate oxidation state tungsten acetylacetonate complexes
... Additionally, the ortho and meta phenyl protons are broad indicating hindered rotation of the phenyl ring. Low temperature NMR studies show sharpening and shifting of alkyne and phenyl resonances, eventually slowing ...
204
Effects of modifier additions on the thermal properties, chemical durability, oxidation state and structure of iron phosphate glasses
... As shown in Fig. 7, glasses containing additions of divalent cations, and particularly BaO and PbO, exhibit aqueous leach rates of ∼ 0.0001 g m −2 d −1 at 90 °C. Such leach rates are exceptionally low, and are comparable ...
22
The +IV Oxidation State in Organopalladium Chemistry2-7
... The organometallic chemistry of palladium is dominated by the + I I oxida- tion state, and the chemistry of complexes containing simple organic groups bonded to palladium in [r] ...
6