radical polymerization
Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles
... mediated radical polymerization in the presence of 3-aminopropyl triethoxy silane as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy as a ...mediated radical polymerization was ...
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Living Radical Polymerization Catalysts: Synthesis, Application, and Utilization of Polymer Products in the Synthesis of Metal Nanoparticles
... the radical concentration is almost entirely determined by the decay rate of the ...the polymerization since there is a wide range of decay rates for commercially available ...latent radical in the ...
216
Laccase-catalyzed controlled radical polymerization of N-vinylimidazole
... Free radical polymerization (FRP) of ...free radical polymerization reaction, a 100 mL round bottom flask was charged with NVIm (5 mL, ...
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Electrodeposition and Radical Polymerization to Prepare Cross-linked Film of Triazinethiol on Aluminum Surface
... Electrodeposition and radical polymerization technique were applied to fabricate triazinedithiol cross- linked film on aluminum alloy surface. The heterocyclic monomer containing fluorine substituent of 6- ...
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Elucidation of Acceleration Mechanisms by a Photosensitive Onium Salt for Nitroxide Mediated Photocontrolled/Living Radical Polymerization
... controlled/living radical polymerization (CLRP) has been an indispensable technique to design and create highly functional and efficient materials supporting today’s cutting-edge technologies in many ...
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Synthesis and Characterization of a New Multi-Site Phase-Transfer Catalyst: Application in Free Radical Polymerization of Benzyl Methacrylate Under Heterogeneous Condition- A Kinetic Study
... free-radical polymerization of benzyl methacrylate (BMA) in the presence of water soluble initiator potassium perdisulphate (PDS) coupled with 1,4- dihexadecylpyrazine-1,4-diium bromide (MPTC) in ethyl ...
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Nitroxide Mediated Photo Controlled/Living Radical Polymerization of Methacrylic Acid
... controlled radical po- lymerization of methacrylic acid (MAA) was exploited using various ...(RAFT) polymerization produced PMAA with a narrow molecular weight distribution (Mw/Mn < ...Photoiniferter ...
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Compression, supramolecular organization and free radical polymerization of ethylene gas
... of radical polymerization, we applied Kargin and Kabanov theory of polymerization of organized monomer to interpret high pressure free radical polymerization of ...of ...
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Thermosensitive Nanocables Prepared by Surface Initiated Atom Transfer Radical Polymerization
... Abstract Thermosensitive nanocables consisting of Au nanowire cores and poly(N-isopropylacrylamide) sheaths (denoted as Au/PNIPAAm) were synthesized by surface- initiated atom transfer radical ...
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Preparation and characterization of a ruthenium(II) catalyst for radical polymerization of olefins.
... hours with molecular weights reaching 50,000 g/mol and PDI as low as 2.6. Controlled reactions in the absence of complex 3 did not yield polystyrene. 13 C NMR spectroscopy suggests the isolated polystyrene is attactic, ...
92
Kinetics of free radical polymerization of methylacrylate initiated by potassium peroxydisulfate and cetylpyridinium chloride system
... kineticsof polymerization of vinyl monomers were carried out (Thajudeen et ...free radical polymerization of olefinic monomers was reported forthe first Rsmussen and Smith, Rsmussen and Smith, ...
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Kinetic Studies on Bulk Atom Transfer Radical Polymerization of Styrene
... Living Radical Polymerization (LRP) via ATRP technique constitutes one of the key developments in the field of synthetic polymer chemistry, allowing for the synthesis of a variety of polymers with molecular ...
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Kinetics fo Free-Radical Polymerization of 8-Quinolinyl Acrylate
... The synthesis of water insoluble poly 8-quinolinylacrylate was investigated for free radical polymerization. The kinetics of polymerizatio of 8-quinolinylacrylate initiated by AIBN in DMF at 60-100°C were ...
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Surface-initiated Atom Transfer Radical Polymerization and Solution Intercalation Methods for Preparation of Cellulose-G-PS-G-PAN/MMT Bionanocomposite
... Radical polymerization [32] is a chain reaction process consisting of mainly three steps; initiation, propagation, and ...propagating radical is the basis of the step of chain ...free radical ...
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Application of Genetic Algorithm to Determine Kinetic Parameters of Free Radical Polymerization of Vinyl Acetate by Multi-objective Optimization Technique
... free radical polymerization of vinyl acetate based on genetic ...free radical polymerization of vinyl acetate is carried out first and then selected kinetic parameters are optimized by ...
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Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate
... It was found that the rate of reaction is less in case of PEMA than PEA. Under heating conditions, the acryloyl groups polymerize by free radical process. Acrylyl double bonds are sluggish in radical ...
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Towards Stereocontrol in Radical Polymerization
... in radical polymerization 41,45 and radical ...mediated radical polymerization, which is one of the most practical and promising stereocontrol ...LA-mediated radical ...
276
Atom Transfer Radical Polymerization (ATRP)in Amplification-by-Polymerization for DNA Sensing
... It has been reported that the formation of an amide bond near bromine in the ATRP initiator slowed down polymer growth in ATRP. In particular, Matyjaszewski and his coworkers have reported that the polymerization ...
249
Activators Generated by Electron Transfer for Atom Transfer Radical Polymerization in Polymerization-based DNA Sensing.
... The polymerization process at high initiator concentration was further characterized with GPC ...in polymerization-based DNA detection, and increase the portability of ...
197
Synthesis and Characterization of Carboxymethylcellulose Graft Copolymer by Free Radical Polymerization
... A Monthly Double-Blind Peer Reviewed Refereed Open Access International e-Journal - Included in the International Serial Directories International Journal in Physical & Applied Scien[r] ...
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