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TITANIUM(IV) COMPLEX

Synthesis of a Flavone-Titanium (IV) Complex and Its Electrocatalytic Activity

Synthesis of a Flavone-Titanium (IV) Complex and Its Electrocatalytic Activity

... This work reported the synthesis and measurements of a novel complex of primuletin (a flavone of natural origin) and titanium. Through changes in the electron density, the 3HF ligand was found to have the ...

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Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: tri­chlorido­(3,3′ di tert butyl 2′ hy­dr­oxy 5,5′,6,6′ tetra­methyl 1,1′ bi­phenyl 2 olato κO2)(tetra­hydro­furan κO)­titanium(IV)

Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: tri­chlorido­(3,3′ di tert butyl 2′ hy­dr­oxy 5,5′,6,6′ tetra­methyl 1,1′ bi­phenyl 2 olato κO2)(tetra­hydro­furan κO)­titanium(IV)

... bipyramidal titanium coordination complex with three chloride and two oxygen donor ...the titanium(IV) metal cation complexed with three chloride ligands, a tetrahydrofuran molecule, and one ...

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Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex

Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex

... ligand. Complex 2 consists of the previously described ligand and a Ti IV metal atom in an octahedral environment, and is located on an inversion ...center. Complex 2 crystallizes as a dinuclear ...

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Crystal structure of the η4 ketimine titanium complex (di­phenyl­amido κN){3 methyl 6 [(4 methyl­phen­yl)(phenyl­aza­nid­yl)methyl­­idene]cyclo­hexa 2,4 dien 1 yl κ2N,C1}(η5 penta­methyl­cyclo­penta­dien­yl)titanium(IV)

Crystal structure of the η4 ketimine titanium complex (di­phenyl­amido κN){3 methyl 6 [(4 methyl­phen­yl)(phenyl­aza­nid­yl)methyl­­idene]cyclo­hexa 2,4 dien 1 yl κ2N,C1}(η5 penta­methyl­cyclo­penta­dien­yl)titanium(IV)

... al., 2017; Loose et al., 2014), the bonding situation of the ketimine ligand has been of great interest. This ligand is bonded with the nitrogen atom and one of the ortho-carbon atoms of one para-tolyl moiety to the ...

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Combined Subchronic Toxicity of Aluminum (III), Titanium (IV) and Silicon (IV) Oxide Nanoparticles and Its Alleviation with a Complex of Bioprotectors

Combined Subchronic Toxicity of Aluminum (III), Titanium (IV) and Silicon (IV) Oxide Nanoparticles and Its Alleviation with a Complex of Bioprotectors

... at low doses of SiO 2 -NP transient to opposite action at higher doses); ( е ) impact on the percentage of 447. macrophages in the same imprint (superadditivity of unidirectional action[r] ...

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Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers

Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers

... impregnated titanium(IV)tungstate layer in nine solvent system among them three are complex forming acids OA,TA, CA to study the effect of complexation on ...

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Di­fluoro­(η5,η5 propane 2,2 diyldi­cyclo­pentadienyl)titanium(IV)

Di­fluoro­(η5,η5 propane 2,2 diyldi­cyclo­pentadienyl)titanium(IV)

... The titanium–ring centroid (Cg1 and Cg2, referring to the C1- and C6-containing rings, respectively) distances [Ti1— Cg1 = ...dichloride complex TiCl 2 [(C 5 H 4 ) 2 C(CH 3 ) 2 ], ...

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[N,N′ Di­phenyl­ureato(2−)][phthalo­cyaninato(2−)]titanium(IV)

[N,N′ Di­phenyl­ureato(2−)][phthalo­cyaninato(2−)]titanium(IV)

... This metathetical transformation depends very much on the steric bulk of the substituent R of the isocyanate. For small substituents such as phenyl, the imide complex could not be isolated in analytically pure ...

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μ Oxo bis­­[azido­bis­(η5 cyclo­penta­dienyl)­titanium(IV)]

μ Oxo bis­­[azido­bis­(η5 cyclo­penta­dienyl)­titanium(IV)]

... The title compound, (I) (Fig. 1), is the main product of the reaction of titanocene dichloride (TDC) with sodium azide in aqueous solution. It is a dinuclear oxo-bridged complex in which two titanocene units are ...

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Di­chloro­bis­(η5 1,2,4 tri­methyl­cyclo­penta­dienyl)­titanium(IV)

Di­chloro­bis­(η5 1,2,4 tri­methyl­cyclo­penta­dienyl)­titanium(IV)

... to one another. The distribution of the methyl substituents is more complex. Thus, while C7 of one ring almost eclipses C8 of the other, C6 of both rings tends to eclipse one or other of the Cl. This situation is ...

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Exploring The Use Of Transition Metals In The Synthesis Of Novel Metal-Ligand Multiple Bonds, Azide Complexes, And Unprecedented Reactivity With The Phosphaethynolato Reagent

Exploring The Use Of Transition Metals In The Synthesis Of Novel Metal-Ligand Multiple Bonds, Azide Complexes, And Unprecedented Reactivity With The Phosphaethynolato Reagent

... the titanium-nitride functionality by using a combination of MO analysis and quantum chemical analysis of the corresponding shielding ...2: Titanium Nitrides: Reactivity Spanning from the Generation of ...

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Divergent skeletal muscle mitochondrial phenotype between male and female patients with chronic heart failure

Divergent skeletal muscle mitochondrial phenotype between male and female patients with chronic heart failure

... of complex I in male patients with HFrEF remains un- clear, but it may be related to a downregulation in complex activity/expression as transcriptional markers were not im- ...

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Titanium (IV) Oxide as Corrosion Inhibitor for Aluminium and Mild Steel in Acidic Medium

Titanium (IV) Oxide as Corrosion Inhibitor for Aluminium and Mild Steel in Acidic Medium

... The aluminium sheets (gauge 9 type, thickness of 0.09cm and purity 0f 97.8%Al) and mild steel sheets (composition of C=0.07%, P=0.08%, Mn=0.34% and Fe=99.51% with thickness of 0.07cm) were obtained locally. The ...

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The SMC Complex MukBEF Recruits Topoisomerase IV to the Origin of Replication Region in Live Escherichia coli

The SMC Complex MukBEF Recruits Topoisomerase IV to the Origin of Replication Region in Live Escherichia coli

... An earlier study of TopoIV in E. coli found that the catalytic subunit, ParC, was associated with the replisome, while the other subunit, ParE, was located in nucleoid-free regions of the cell (31). Based on this and ...

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Kinetics of the Photocatalytic Decomposition of Bisphenol A on Modified Photocatalysts

Kinetics of the Photocatalytic Decomposition of Bisphenol A on Modified Photocatalysts

... of titanium(IV) oxide nano- ...commercial titanium(IV) oxide and modified photocatalysts (composites) based on TiO 2 , activated carbon and elemental ...

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Use of Microwave-Assisted Oxidation for Removal of the Pesticide Chlorpyrifos from Aqueous Media

Use of Microwave-Assisted Oxidation for Removal of the Pesticide Chlorpyrifos from Aqueous Media

... Table IV shows the results of the treatment of samples of chlorpyrifos using system 4, in which microwave radiation was used in combination with UV-radiation, titanium dioxide, and hydrogen ...

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Spectroscopic and electrochemical analysis of psychotropic drugs

Spectroscopic and electrochemical analysis of psychotropic drugs

... Psychotropic drugs, e.g. dibenzoazepines, dibenzocycloheptadienes, thioxanthenes, and phenothiazines, and new generation drugs, e.g. fluoxetine, fluvoxamine, and trazodone form cations which react with some organic ...

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Study of Nano Filler Effect on Electrical Behavior of Polymer Insulating Materials Using Artificial Intelligence

Study of Nano Filler Effect on Electrical Behavior of Polymer Insulating Materials Using Artificial Intelligence

... A single-phase high voltage transformer (100KV -5 KVA) is used to obtain the AC high voltage. (0-220V) variac regulating panel is used to smoothly control the output voltage of the transformer as shown in Fig.(1). The ...

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Di μ eth­oxy bis­­[di­eth­oxy(8 quinolinato)­titanium(IV)]

Di μ eth­oxy bis­­[di­eth­oxy(8 quinolinato)­titanium(IV)]

... similar to those found in the three centrosymmetric dimeric triethoxy±(chelate)±titanium complexes, the acetyacetonate [1.796 (1), 1.805 (1) and 2.064 (1) AÊ; Errington et al., 1998], the glycinate [1.765 (6), ...

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Synthesis and Characterization of Titanium (iv) Oxide Loaded with Silver Nano Particles Thin Films

Synthesis and Characterization of Titanium (iv) Oxide Loaded with Silver Nano Particles Thin Films

... solar cells. A new method has evolved in recent times for increasing the light absorption i.e., the use of nanoparticles with size ranging between 10-1000 nm [3-4]. Nanotechnology is a new branch of technology that ...

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