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Quantum chemical modeling of antioxidant activity of glutathione interacting with hydroxyl- and superoxide anion radicals

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Figure

Fig. 1. “attack directions” of different centers of GSH molecule with hydroxyl and superoxide-anion radicals (free enumeration of atoms; 0 – mass center of GSH molecule)
Fig. 3. Scheme of interaction of GSH molecule with •ОН (arrows point to charges on atoms according to lowdin)
Fig. 4. Scheme of redistribution of electron density of GSH molecule as a result of interaction with radi-cals
Fig. 5. Differential volt-amperograms of reduc-tion of free oxygen radicals on a copper cathode against a background of 0.1 M NaCl in water (1) in the presen ce if various concentrations of GSH (T = 298 K): 2 – 0.24; 3 – 0.47; 4 – 0.74;5 – 0.91; 6 – 1.1·103 М/ml

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