2''-TERPYRIDINE
← Return to Article Details SYNTHESIS AND CHARACTERIZATION OF BISMERCAPTO (2, 2’:6’, 2’’-terpyridine) Ru(II)-COMPLEXES STABILIZED GOLD NANOPARTICLES AND THEIR ELECTRO CATALYTIC REDUCTION OF NITRITE
... The complex is electrochemically active and exhibits a reversible (83 mV) ruthenium (II/III) process at +0.9 V in MeCN solution of interest for potential applications of this type of complex in electrochemical devices, ...
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Synthesis, Characterization, and Biological Activities of 4’ (1H Benzimidazol 2 yl) 2, 2’:6’, 2’’ terpyridine and its Copper Complex
... resonance signals are listed in Table 3.2. The spectrum of bitpy shows signals due to protons at different positions of terpyridine moiety. Helen Elsbernd and James K.Beattie [24-25] have investigated the 1 H NMR ...
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Crystal structure of dichlorido(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)zinc: a redetermination
... A solution of 2,2′:6′,2′′-terpyridine (0.23 g, 1 mmol) in acetonitrile (20 ml) was mixed with a solution of zinc chloride (0.14 g, 1 mmol) in methanol (5 ml) and refluxed for 4 h. The reaction mixture was ...
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Review Paper Synthesis and Photophysical Application of Functionalised 2,2':6',2"- Terpyridine Metal Complexes
... of 2, 2’:6’, 2''-terpyridine 1 ...pyridines 2 and other substituted pyridines like terpyridines 3 which were used as distinguished building blocks in supramolecular chemistry because of ...
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catena Poly[[(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)(tricyanomethanido κN)nickel(II)] μ tricyanomethanido]
... such as hexamethylenetetramine, 4,4-bipyridyl, 1,2-bi(4-pyridyl)ethane were introduced and the structures as well as magnetic properties of the adjusted complexes have been systematically investigated. Among the Cu(I) or ...
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4′ [2 (Trifluoromethyl)phenyl] 2,2′:6′,2′′ terpyridine
... 4′-(2′′′-trifluoromethylphenyl)-2, 2′:6′,2′′-terpyridine, the three pyridyl rings of the terpyridyl moiety are essentially co-planar as is preferred for maximum conjugative interaction ...
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Aqua[4′ (4 chlorophenyl) 2,2′:6′,2′′ terpyridine]nitratocopper(II) nitrate [4′ (4 chlorophenyl) 2,2′:6′,2′′ terpyridine]dinitratocopper(II) monohydrate
... 4′-(4-Chlorophenyl)-2,2′:6′,2′′-terpyridine (Cl-ptp) has been synthesized by a procedure reported in the literature (Mutai et al. 2001). A solution of Cl-ptp (42.35 mg, 0.124 mmol) in dichloromethane (3 ml) ...
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(Acetonitrile κN)(4′ phenyl 2,2′:6′,2′′ terpyridine κ3N)silver(I) hexafluorophosphate acetonitrile solvate
... terpyridine (0.0390 g, 0.1 mmol). A yellow precipitate was formed after stirring for 3 h and this was isolated by ®ltration. A solution of the resulting solid in acetonitrile was allowed to stand for 5 d and ...
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Bis(4′ phenyl 2,2′:6′,2′′ terpyridine κ3N,N′,N′′)copper(II) bis(tetrafluoroborate)
... dional configuration. The Cu—N distance to the central pyridine ring is significantly shorter than the distances to the outer pyridine rings (Table 1), indicating a compressed octa- hedral geometry. The N—Cu distances ...
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Crystal structure of bis(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)nickel(II) dicyanidoaurate(I)
... tridentate terpyridine ligands define the coordination of the Ni 2+ cation, resulting in a nearly octahedral coordination sphere, although there is not any imposed crystallographic symmetry about the Ni ...
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4′ Chloro 2,2′:6′,2′′ terpyridine
... terpyridine (tpy) in coordination chemistry (Andres & Schu- bert, 2004; Baranoff et al., 2004; Constable, 1986; Hofmeier & Schubert, 2004; Thummel, 2004), few crystal structures of ligands with simple ...
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Iron(II) and cobalt(II) complexes of tris-azinyl analogues of 2,2':6',2''-terpyridine.
... products that are substituted at the central heterocyclic ring. 4,8 We describe here the complex chemistry of a series of tris- azine terpyridine analogues L 1 -L 7 (Scheme 1), concentrating on the parent ...
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Chloro(4,7 diphenyl 1,10 phenanthroline)(2,2′:6′,2′′ terpyridine)ruthenium(II) hexafluorophosphate
... terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,7-diphenyl-1,10-phenanthroline (dpphen) ligand is coordinated in a cis fashion and the Cl atom is trans to one of the dpphen N atoms. The ...
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Acetonitrile(1,10 phenanthroline)(2,2′:6′,2′′ terpyridine)ruthenium(II) bis(hexafluorophosphate)
... The title compound, (I), was synthesized and isolated. The ligand environment about the Ru atom is distorted octahedral; the terpy ligand is coordinated in a meridional fashion, the phen ligand is coordinated in a cis ...
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4′ [4 (Imidazol 1 yl)phenyl] 2,2′:6′,2′′ terpyridine (IPTP)
... ligand terpyridine (terpy) and its functionalized derivatives have been studied exten- sively as outstanding complexing agents for a wide range of transition metal ions (Heller & Schubert, ...of ...
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The crystal structure of 4′ {4 [(2,2,5,5 tetramethyl N oxyl 3 pyrrolin 3 yl)ethynyl]phenyl} 2,2′:6′,2′′ terpyridine
... of terpyridine were included. For purely organic terpyridine compounds, the number of hits was reduced to ...both terpyridine and 2,2,5,5-tetramethyl-N-oxyl-3-pyrroline derivatives did not result in ...
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(2,2′ Bipyridine)chloro(4′ tolyl 2,2′:6′,2′′ terpyridine)iridium(III) bis(hexafluorophosphate) acetonitrile disolvate
... Mean-plane calculations have been performed for the six aromatic rings in the ligands of (I). The six-atom r.m.s. deviations are calculated to be 0.008, 0.013, 0.004, 0.006, 0.008, and 0.006 A ˚ for ring A (atoms ...
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Aquabis(1,1,1,5,5,5 hexafluoroacetylacetonato)[4′ (4 pyridyl) 2,2′:6′,2′′ terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate
... C4 0.045 (2) 0.038 (2) 0.055 (2) 0.0025 (17) 0.0080 (18) 0.0101 (17) C5 0.045 (2) 0.0238 (16) 0.0355 (18) 0.0010 (14) 0.0053 (15) 0.0042 (13) C6 0.043 (2) 0.0243 (15) 0.0320 (17) 0.0026 ...
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Crystal structure of trichlorido(4′ ferrocenyl 2,2′:6′,2′′ terpyridine κ3N,N′,N′′)iridium(III) acetonitrile disolvate
... C10 0.027 (2) 0.019 (2) 0.028 (2) 0.0011 (17) 0.012 (2) −0.0010 (17) C11 0.023 (2) 0.018 (2) 0.031 (3) −0.0020 (18) 0.009 (2) 0.0004 (19) C12 0.027 (3) 0.026 (2) ...
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Redetermination of chlorido(2,2′:6′,2′′ terpyridine κ3N,N′,N′′)gold(I) dichloride trihydrate at 173 K
... C15 0.022 (2) 0.021 (2) 0.033 (3) −0.0013 (18) 0.0076 (19) 0.001 (2) Cl1 0.0363 (6) 0.0386 (7) 0.0230 (6) −0.0093 (5) 0.0120 (5) −0.0003 (5) Cl2 0.0285 (5) 0.0258 (6) 0.0260 (6) 0.0037 (4) 0.0015 (4) ...
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