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DL/I

I. Polarographic determination of alpha-methyl-DL-cystine II. Synthesis of alpha substituted amino acids.

I. Polarographic determination of alpha-methyl-DL-cystine II. Synthesis of alpha substituted amino acids.

... ► Because of a recent synthesis of a substituted amino ad d, a-methyl-Di- cystine, it became necessary to have a method of determining this com­ pound. The polarographic determina­ tion of the substance in 0.1 N hydro­ ...

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Compositional and in vitro evaluation of nonwoven type I collagen /poly-DL-lactic acid scaffolds for bone regeneration

Compositional and in vitro evaluation of nonwoven type I collagen /poly-DL-lactic acid scaffolds for bone regeneration

... Incorporating high molecular weight PDLLA polymer with type I collagen followed by GD crosslinking produced water stable electrospun fibrous scaffolds. A PDLLA/collagen scaffold composition of 60/40 (w/w) was ...

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DL Histidine DL tartrate

DL Histidine DL tartrate

... This study was undertaken to identify the effects of chirality on the formation of salts, speci®cally the way chirality may affect hydration, as a result of interactions between a chiral drug and a chiral counter-ion. ...

6

DL Phenyl­alaninium nitrate

DL Phenyl­alaninium nitrate

... The phenylalaninium residue forms a strong O—H···O hydrogen bond with the nitrate anion. The amino nitrogen of the phenylalaninium residue forms an N—H···O hydrogen bond with oxygen atoms of the nitrate anion and the ...

9

DL Me­thioninium maleate

DL Me­thioninium maleate

... Fig. 2 shows the packing of molecules of (I), viewed down the b axis. The methioninium and semi-maleate ions aggregate in alternate columns parallel to the a axis. There are no direct hydrogen-bonded interactions ...

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DL Alaninium oxalate

DL Alaninium oxalate

... In the crystal structure of (I), the alanine molecules dimerize across inversion centres through head-to-tail N - H···O hydrogen bonds, as observed in many other amino acid racemates (Soman & Vijayan, 1989). ...

8

DL Valinium perchlorate

DL Valinium perchlorate

... The asymmetric unit contains four crystallographically independent valinium residues (I, II, III and IV) and four independent perchlorate anions (1, 2, 3 and 4). The ClÐO bond distances and OÐClÐO bond angles show ...

12

DL Threoninium tri­chloro­acetate

DL Threoninium tri­chloro­acetate

... Fig. 2 shows the packing of the molecules of (I), viewed down the a axis. The threoninium cations and trichloroacetate anions are linked together by an in®nite network of hydrogen bonds. Atoms O3A and O3B ...

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DL Phenyl­alaninium tri­chloro­acetate

DL Phenyl­alaninium tri­chloro­acetate

... Fig. 2 shows the packing of ions inf (I), viewed along the c axis. It is clearly seen that the aggregation of phenylalaninium cations and trichloroacetate anions form columns along the c axis. These columns have ...

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DL Valinium nitrate

DL Valinium nitrate

... Anions I and II are related to III and IV, respectively, by a pseudo-c-glide with a mirror plane at y = ...Anions I and III are related to II and IV, respectively, by a pseudo-trans- lation of half the unit ...

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DL Threoninium di­hydrogen phosphate

DL Threoninium di­hydrogen phosphate

... Threonine is an essential amino acid, which helps in main- taining the proper balance of protein in the body. It is found in the heart, skeletal muscles and also in the central nervous system. The crystal structures of ...

7

Bis­(DL me­thioninium) sulfate

Bis­(DL me­thioninium) sulfate

... of dl-methionine (Mathieson, 1952), L-methionine (Torii & Iitaka, 1973), dl-methionine hydrochloride (Di Blasio et ...1977), dl-methionine nitrate (Mostad & Natar- ajan, 1985) and ...

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DL Phenyl­alaninium di­hydrogen phosphate

DL Phenyl­alaninium di­hydrogen phosphate

... The title compound, (I), crystallizes in an unusual, but not uncommon, non-centrosymmetric space group, Pc. However, racemates with more than one molecule in the asymmetric unit are found to grow in ...

12

DL Valinium di­hydrogen phosphate

DL Valinium di­hydrogen phosphate

... The valine molecule can have three possible rotational isomers, viz. gauche I, trans and gauche II (Torii & Iitaka, 1970). In the present case, the valinium residue adopts a gauche II conformation (Table ...

7

N Phthaloyl DL alanine

N Phthaloyl DL alanine

... The title compound, (I), was prepared by reaction of phthalic anhy- dride with dl-alanine using a previously reported procedure (Taber & Malcolm, 2001). Suitable crystals were obtained by slow ...

6

Bis(DL me­thioninium) sulfate

Bis(DL me­thioninium) sulfate

... The side-chain conformation angle for the major disorder component of the methioninium cation is trans-trans-gauche II, while it is trans-gauche I-gauche I for the minor component. One of the sulfate anions ...

8

N Acetyl DL phenyl­glycine

N Acetyl DL phenyl­glycine

... The title compound, (I) (Fig. 1), can be used as an inter- mediate for the optical resolution of dl -phenylglycine (Wang et al., 2004). It crystallizes with two molecules in the asym- metric unit, one of ...

8

DL Threoninium oxalate

DL Threoninium oxalate

... Fig. 2 shows the packing of molecules of (I) viewed down the b axis. The semi-oxalate ions form hydrogen-bonded strings generated by the glide plane as in dl-arginine semi- oxalate complex (Chandra et al., ...

9

DL Leucinium nitrate

DL Leucinium nitrate

... The molecular packing arrangement adopted in (I) was previously observed in other compounds, such as l -leucine, l - leucinium nitrate, glycyl- dl -leucine (Bombicz et al., 2000) and d -phenylglycinium ...

7

DL Me­thio­ninium di­hydrogenphosphate

DL Me­thio­ninium di­hydrogenphosphate

... Methionine, an essential amino acid, is one of the two sulfur- containing amino acids and is indispensable for normal metabolism, growth and maintenance of body tissues. Methionine reacts with adenosine triphosphate to ...

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