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Halogen bond

A solvent-resistant halogen bond

A solvent-resistant halogen bond

... bonds were rst reported over a century ago by Guthrie 4 but have recently become a focus of attention in the elds of crystal engineering, 5–10 protein–ligand interactions, 11,12 catalysis 13 and supramolecular and ...

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Spectroscopic studies on the nature of the metal halogen bond

Spectroscopic studies on the nature of the metal halogen bond

... is clearest for trans square planar complexes, where infra-red data show a small but significant decrease in metal - phosphorus stretching frequency and hence, presumably, bond strength [r] ...

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On the directionality and non-linearity of halogen and hydrogen bonds

On the directionality and non-linearity of halogen and hydrogen bonds

... the deviation from collinearity of the hydrogen or halogen bond, is displayed as the theoretical value in black, with the experi- mental angle taken from the literature in red. It is immediately apparent ...

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8 Chloro 4 oxo 4H chromene 3 carbaldehyde

8 Chloro 4 oxo 4H chromene 3 carbaldehyde

... no halogen bond in the title ...a halogen bond (Wilcken et ...that halogen bonding is observed in the dichlorinated 3-formylchromone, but is not observed in the monochlorinated ...

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6 Bromo 4 oxo 4H chromene 3 carb­alde­hyde

6 Bromo 4 oxo 4H chromene 3 carb­alde­hyde

... that halogen bonds between the formyl oxygen atom and the halogen atoms at 8-position are formed in those crystals in a similar ...hand, halogen bond is not observed between any oxygen atom ...

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Modeling of Sic Power Semiconductor Devices For Switching Converter Applications

Modeling of Sic Power Semiconductor Devices For Switching Converter Applications

... of halogen bonding and also favor the 180 ...of halogen bonds deviates only slightly from the ideal of 180 ° with respect to the halogen bond ...

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Theoretical Insights into the Nature of Halogen Bonding in Prereactive Complexes

Theoretical Insights into the Nature of Halogen Bonding in Prereactive Complexes

... the halogen-bonding interaction in these systems is determined via an analysis of the fraction of electronic charge transferred between the subunits, and characterising how the interactions change when the ...

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The Synthesis and New Crystal Structures of Three Arylpiperazine Compounds

The Synthesis and New Crystal Structures of Three Arylpiperazine Compounds

... The halogen bond is a noncovalent interaction involving polarizable chlorine, bromine, or iodine molecular ...arylpiperazine halogen derivatives were synthesized to observe if the packing mode was ...

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Neutral iodotriazoles as scaffolds for stable halogen bonded assemblies in solution

Neutral iodotriazoles as scaffolds for stable halogen bonded assemblies in solution

... well-known halogen bond donor 2 and the same set of pyridines. Natural bond order (NBO) analyses (see ESI† for details) demonstrated that, in all six complexes, there are signicant interactions ...

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pH controlled assembly of a self complementary halogen bonded dimer

pH controlled assembly of a self complementary halogen bonded dimer

... form halogen bonds with neutral ...two halogen bonds between the phenoxide anions and the neutral iodotriazoles has been ...no halogen bond mediated assembly either in the solid or in the ...

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Structure of Unsupported Small Palladium Nanoparticles

Structure of Unsupported Small Palladium Nanoparticles

... the bond energy and the CN vary with DTC. The bond energy of each atom is equal to the result of the atomic cohesive energy divided by its ...the bond energy remains ...the bond energy ...

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Liberty Company Bond Teaching Resource:  Using A Zero-Coupon Bond To Clarify Bond Liability Accounting

Liberty Company Bond Teaching Resource: Using A Zero-Coupon Bond To Clarify Bond Liability Accounting

... a bond: 1) a market rate and 2) a contract rate. When explaining bond fundamentals, it is natural to explain the features of a bond, including its contract interest rate, early in the ...a ...

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Bond Swaps

Bond Swaps

... In the 1950s the bond market was considered a safe, con- servative investment. At that time a buy-and-hold strategy was sufficient. However, times changed, in the 1960s inflation in- creased, and interest rates ...

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Grinding Circuit at Mouteh Gold Mine

Grinding Circuit at Mouteh Gold Mine

... Mouteh gold processing plant is located in Esfahan province and a ball mill is in its grinding circuit. The main problem is high energy utilization in the ball mill. An optimization study therefore has been carried out ...

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Wunderlich, Stefan
  

(2010):


	Preparation of Highly Functionalized Aryl and Heteroaryl Organometallics by C-H Activation of Aromatics and Heterocycles Using new Hindered TMP-Amide Bases of Zn, Al, Mn, Fe and La.


Dissertation, LMU München: Fakultät f

Wunderlich, Stefan (2010): Preparation of Highly Functionalized Aryl and Heteroaryl Organometallics by C-H Activation of Aromatics and Heterocycles Using new Hindered TMP-Amide Bases of Zn, Al, Mn, Fe and La. Dissertation, LMU München: Fakultät für Chemie und Pharmazie

... carbon-metal bond increases with the ionic character of this bond due to the difference of the ...carbon-magnesium bond are much more tolerant towards various organic functionalities and very low ...

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Evaluation of a New and Advance Curing Light on the
Shear Bond Strength of Orthodontic Brackets

Evaluation of a New and Advance Curing Light on the Shear Bond Strength of Orthodontic Brackets

... shear bond strength of stainless steel bracket using conven- tional halogen light and light-emitting diode (LED) curing ...by halogen light curing unit by 10 seconds, group II is cured by LED curing ...

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Sea ice dynamics influence halogen deposition to Svalbard

Sea ice dynamics influence halogen deposition to Svalbard

... signal as well as those of other less-reactive species (Pohjola et al., 2002). In such a case, Iodine concentrations will not show an annual cycle but could still be indicative of mean a[r] ...

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Toxicity and Antimicrobial Activities of Ionic Liquids with Halogen Anion

Toxicity and Antimicrobial Activities of Ionic Liquids with Halogen Anion

... 4.1. Power-Time Curves of Bacterial Growth All ILs with halogen anion were tested for antimicrobial activities against E. coli, S. aureus and B. subtilis. The power-time curves of bacterial growth at 310 K in the ...

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CDS bond basis and bond return predictability

CDS bond basis and bond return predictability

... corporate bond market. Basis factor is constructed using double-sorted bond portfolios: bonds are independently sorted by credit rating and residual ...government bond index and the daily T-bill ...

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The usability of tungsten halogen lamps as secondary standards of luminous intensity

The usability of tungsten halogen lamps as secondary standards of luminous intensity

... outside making the the on in used temperature question, one placed thermometer sleeve, control lampholder and the thermometer five which determine number installed table data gathered, t[r] ...

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