ruthenium complexes
Enantioselective hydrogenation using ruthenium complexes of tridentate ligands
... When this project commenced in 2004, only simple model ketones could be hydrogenated effectively using the Noyori system, and the hydrogenation of bulky ketones was completely underdeveloped. As mentioned in section ...
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Lipid bilayers decorated with photosensitive ruthenium complexes
... aqua ruthenium complexes similar to [1] 2+ but containing an unhindered bpy chelate, strongly interact with negatively charged lipid bilayer membranes, and that coordination reaction at membrane- embedded ...
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Recognition of Nucleic Acid Mismatches by Luminescent Ruthenium Complexes
... the ruthenium complex is restricted in the minor groove, it can bind in either a head-on or canted ...of ruthenium by metalloinsertion must have ...the ruthenium recognizes a weak point (the extruded ...
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Ruthenium complexes as antimicrobial agents
... inert ruthenium complexes in eukaryotic ...of ruthenium complexes in a variety of human and animal ...polypyridyl- ruthenium complexes can be readily examined by confocal micro- ...
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The Cellular Uptake of Luminescent Ruthenium Complexes
... the ruthenium complex in complete medium (containing 10% fetal bovine serum), cells were rinsed with Hanks’ Balanced Salt Solution and imaged without fixation (unless otherwise ...The ruthenium ...
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Biological processing of dinuclear ruthenium complexes in eukaryotic cells
... the ruthenium complexes were ...the ruthenium complexes and their intra- cellular ...procedures. Ruthenium complexes (20 mM) were added to pretreated and control cells, followed ...
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Targeting DNA Mismatches with Luminescent Ruthenium Complexes
... mismatch-specific ruthenium complexes may be useful in this ...Luminescent ruthenium polypyridyl complexes, along with other transition metal centers such as iridium, platinum, and rhenium, ...
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Doping ruthenium complexes into a molecular spin-crossover material
... and ruthenium ions, or simply decomposition of the organometallic ruthenium complexes (some precipitation of the intact [Ru(terpy)(terpy*)][BF 4 ] 2 occurred after ...
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The use of (cyclopentadienone)iron tricarbonyl complexes and ruthenium complexes for hydrogen transfer reactions
... iron complexes 50 were tested for the asymmetric activity through use as the hydrogen transfer catalyst for the reaction of acetophenone 24 with formic acid being used as the hydrogen donor compound and ...
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Inhibition of cancer cell growth by ruthenium complexes
... example, complexes possessing plati- num (Pt), such as cisplatin, carboplatin, and oxaliplatin, have been used to treat various cancer types such ovary, stomach, and colon [1, ...Pt complexes inhibit cancer ...
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Chloro(η6 p cymene)(diethyldithiocarbamato κ2S,S)ruthenium(II)
... of ruthenium±thiolate complexes have been reported; however, ruthenium complexes with dithio ligands are rare (Sellmann et ...arene±ruthenium complexes, such as [RuCl 2 (arene)] ...
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Arene Ruthenium(II) Thiosemicarbazone complexes as anticancer agents
... The critical evaluation of the fit results and the structural parameters ob- tained in the theoretical fitting procedure shows that the difference in bond length between Ru-Cl and Ru-S cannot be resolved for the data ...
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Aqueous solution chemistry of ruthenium arene anticancer complexes
... cytotoxicity; complexes which have three monodentate ligands showed no cytotoxicity compared to those with bidentate ligands 56,58 ...the ruthenium complexes, it has been observed that changes to the ...
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Diastereoselective Synthesis and Two-Step Photocleavage of Ruthenium Polypyridyl Complexes Bearing a Bis(thioether) Ligand
... the ruthenium complexes were performed on a Cary 50 Varian spectrometer equipped with a Cary Single Cell Peltier for temperature control (T = 298 K) and ...
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Ruthenium Vinylidene Complexes148-153
... of ruthenium complexes with great potential for applications in organic and polymer ...traditional ruthenium alkylidene pre-catalysts, these alternative ruthenium vinylidene complexes ...
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Eukaryotic cell toxicity and HSA binding of [Ru(Me4phen)(bb7)]2+ and the effect of encapsulation in cucurbit[10]uril
... of ruthenium complexes as potential antimicrobial agents (Li et ...polypyridylruthenium(II) complexes against both Gram-positive and Gram-negative bacteria (Dwyer et ...of ruthenium ...
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Synthesis, Photo Physical Studies and Evaluation of Ruthenium(II) Complexes of Polypyridyl Ligands as Sensitizer for DSSCs
... different ruthenium complexes (Ru-1, Ru-2 and Ru-3) in different solvents depending on their solubility, are shown in Figure ...these ruthenium(II) polypyridyl complexes showed two well ...
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Photoactivatable organometallic pyridyl ruthenium(II) arene complexes
... these complexes bind significantly to 9-EtG but do not bind to ...II complexes 1, 4 and 10, results in a low degree of unwinding (6–7°) which is very similar for the three complexes but smaller than ...
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Organometallic cis Dichlorido ruthenium(II) ammine complexes
... The hydrolysis rate constants and half-lives are listed in Table 2. It can be seen that the first step is fast for both complexes (half-lives ca. 1 min). The aquation rates for the second step are also similar for ...
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Asymmetric catalysis using iron complexes : 'ruthenium lite'?
... precursors. 21,22 Evidence for this came from the observation that complexes 4 and 6 give very similar conversions of ketones to hydrogenation products under the same conditions. Should this be the case, then the ...
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