TWO-DIMENSIONAL COORDINATION POLYMER
A two dimensional coordination polymer, μ 1,3 benzenedicarboxylato μ ethylenediaminezinc(II) trihydrate
... the polymer, each Zn atom is coordinated by two monodentate 1,3-benzenedicarboxylate ligands and two ethyl- enediamine ligands which de®ne a distorted tetrahedral ...The two-dimensional ...
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Crystal structure of a two dimensional coordination polymer of formula [Zn(NDC)(DEF)] (H2NDC is naphthalene 2,6 dicarboxylic acid and DEF is N,N diethylformamide)
... by two NDC 2 anions and each Zn atom is linked by a further NDC 2 anion and a DEF molecule ...The two carboxylate groups of the same NDC 2 anion adopt either a 1 ...
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A two dimensional coordination polymer containing copper(II): poly[[(1H benzimidazole κN3)copper(II)] μ3 3 carboxylatophenoxyacetato κ4O,O′:O′′:O′′′]
... square-pyramidal coordination environment, de®ned by one N atom from the terminal benzimidazole molecule and four carboxyl O atoms derived from three different 3-carboxylato- phenoxyacetate (3-CPOA) ...
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The two dimensional coordination polymer poly[[silver(I) di μ 1,5 bis(phenylsulfanyl)pentane] tetrafluoroborate]
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ...
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The two dimensional coordination polymer tetraaquamesaconatobarium(II), [Ba(C5H4O4)(OH2)4]n
... Geometry . All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of ...
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Phyllo poly[[silver(I) di μ2 4 aminomethylpyridine κ2N:N′] hexafluorophosphate]: a two dimensional coordination polymer formed by the reaction of silver(I) hexafluorophosphate with 4 aminomethylpyridine
... Silver(I) coordination polymers are intriguing species that display a wide range of useful ...based coordination polymers of highly flexible 3- and 4- pyridyl-substituted phosphines have produced a number ...
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A two dimensional CdII coordination polymer: poly[diaqua[μ3 5,6 bis(pyridin 2 yl)pyrazine 2,3 dicarboxylato κ5O2:O3:O3,N4,N5]cadmium]
... a two-dimensional coordination polymer (Neels et ...are two crystallographically independent fivefold-coordinated copper atoms present and they all have almost perfect square-pyra- ...
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A two dimensional copper(I) coordination polymer based on 1 [2 (cyclohexylsulfanyl)ethyl]pyridin 2(1H) one
... Geometry . All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in ...
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Poly[triaqua(μ benzene 1,3 dioxyacetato)manganese(II)]: a two dimensional manganese(II) coordination polymer
... the coordination geometry of the metals, the bonding of the ligands and the reaction ...the coordination architecture and the func- tionality of the complex ...
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A two dimensional Zn coordination polymer with a three dimensional supramolecular architecture
... of coordination polymers (CPs) or metal–organic frameworks (MOFs) based on metal ions or clusters and organic ligands has attracted much attention, owing to their intriguing molecular topologies and potential ...
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Poly[cadmium(II) μ4 benzene 1,3 dioxyacetato]: a two dimensional layer cadmium(II) coordination polymer
... various coordination fashions, including bidentate (Gao, Liu, Huo, Zhao & Zhao, 2004b,c; Gao, Liu, Huo, Zhao & Ng, 2004a), tridentate (Gao, Liu, Huo, Zhao & Zhao, 2004a) or tetradentate (Gao, Liu, Huo, ...
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A one dimensional nickel(II) coordination polymer with pyridine and isophthalate
... The water molecule and carboxylate groups form extensive hydrogen-bonding interactions (Table 2). The hydrogen- bonding interactions can be divided into two types according to the different donors. One interaction ...
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A one dimensional coordination polymer of copper(II) with 2 pyrazinecarboxylate
... forming two-dimensional sheets. A three- dimensional framework is constructed alternately from hydrogen bonds between the O atoms of coordinated water and the O atoms of coordinated carboxylate ...
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Crystal structure of a mixed ligand terbium(III) coordination polymer containing oxalate and formate ligands, having a three dimensional fcu topology
... Experimental . SADABS-2014 (Bruker, 2014) was used for absorption correction. wR2(int) was 0.0566 before and 0.0416 after correction. The ratio of minimum to maximum transmission is 0.8789. The λ/2 correction factor is ...
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Crystal structure of a one dimensional coordination polymer of tin(IV) bromide with 1,4 dithiane
... Geometry . All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in ...
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A one dimensional HgII coordination polymer based on bis(pyridin 3 ylmethyl)sulfane
... and two chloride anions. The Hg II ion is four-coordinated, binding to two Cl anions and two pyridine N atoms from two separate symmetry-related L ligands, forming a highly distorted ...
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Synthesis and crystal structure of a two dimensional CoII coordination polymer: poly[(μ3 3 carboxybenzoato)[μ2 5 (pyridin 4 yl) 1H,2′H 3,3′ bi[1,2,4 triazole]]cobalt(II)]
... nation between the Hpyttz ligands and the Co II cations. In the complex, the Hpyttz ligand is almost coplanar, with dihedral angles of 7.48 (4), 6.87 (4) and 4.43 (4) between the pyridine and the two triazole ...
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A one dimensional helical chain polymer: catena poly[[[bis(1H imidazole)zinc(II)] μ 3 carboxylatophenoxyacetato] trihydrate]
... tetrahedral coordination geometry defined by two N atoms from two imidazole molecules and two carboxyl O atoms from two different 3-CPOA 2 ...
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A two dimensional cadmium(II)–iminodiacetate polymer
... consists of a polymeric Cd II –iminodiacetate network and uncoordinated water molecules. One Cd atom located on a general position is surrounded by three iminodiacetate (IDA) dianions, while a second Cd atom located on a ...
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Tris(μ 1,4 benzenedicarboxylate)tetrakis(dimethyl sulfoxide)di μ3 hydroxo tetrazinc dihydrate
... three-dimensional coordination polymer with metal cluster and hydroxide bridges is quite rare in metal±organic polymers (Li et ...adopt two different coordination ...
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