Metal Organic Framework
Electrochemical and Electrocatalytic Properties of a stable Cu-Based metal-organic Framework
... A redox-active Cu-based metal-organic framework (Cu-MOF) was prepared via a facile solvothermal synthesis. The electrochemical and electro-catalytic properties of the as-prepared Cu-MOF were ...
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Adsorption of propane, propylene and isobutane on a metal–organic framework : molecular simulation and experiment
... new metal-organic framework material, CuBTC, in adsorptive separation processes, particularly in a simulated moving bed (SMB) context using isobutane as a potential ...unsaturated metal sites, ...
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Exceptionally efficient and recyclable heterogeneous metal organic framework catalyst for glucose isomerization in water
... "This is the peer reviewed version of the following article: Oozeerally, Ryan, Burnett, David L., Chamberlain, Thomas W., Walton, Richard I. and Degirmenci, Volkan, Exceptionally efficient and recyclable ...
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The effect of pressure on the post synthetic modification of a nanoporous metal organic framework
... copper-based metal – organic ...axial metal site occurs with methanol, acetonitrile, methylamine and ethylamine within a single-crystal and without the need to expose a free metal site prior ...
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Development of a Metal-Organic Framework for the Sensitive Determination of 2,4-Dichlorophenol
... As prominent crystalline inorganic–organic hybrid materials, MOFs have three-dimensional ordered frameworks, where organic ligands and metal clusters are connected in space [33-36]. MOFs have high ...
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Metal-organic framework nanosheets (MONs): a new dimension in materials chemistry
... – organic framework nanosheets (MONs) are emerging as a novel class of two-dimensional materials with a distinct set of design principles, synthetic approaches, characterisation techniques and ...of ...
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Metal-Organic Framework Nanoparticle-Based Biomineralization: A New Strategy toward Cancer Treatment
... Advanced metal-organic framework nanoparticles (MOFs) are excellent supporting matrices due to the low toxicity of polycarboxylic acids and metals, high encapsulation efficiency, and moderate ...
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Overview Of Metal-Organic Framework Based Drug Delivery Systems
... Metal Organic Framework are compounds consisting of metal ions or clusters coordinated to organic molecules to form one, two or three-dimensional structures that can be porous (Li, ...
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Synthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors
... the metal-organic framework (MOF) from building blocks due to their fascinating structural properties and potential applications in catalysis, host-guest chemistry, enantioselective separation, ...
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Construction of a Sensitive Bisphenol A Electrochemical Sensor based on Metal-organic Framework/Graphene Composites
... Metal–organic framework materials (MOFs), as a new class of hybrid inorganic–organic porous crystalline materials, have attracted considerable attention because of their extraordinarily high ...
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Synthesis and characterisation of metal organic framework materials with carboxylate ligands
... - 5 - Over the past one hundred years these types of materials have been defined as coordination polymers, coordination networks, inorganic-organic coordination polymers, porous coordination polymers and many ...
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Inelastic neutron scattering study of binding of para hydrogen in an ultra microporous metal organic framework
... Metal-organic framework (MOF) complexes are a sub-class of porous solids which show great promise for gas storage and separation due to their high surface area, low framework density, and ...
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Enhancement of CO2 uptake and selectivity in a metal organic framework by incorporation of thiophene functionality
... paddle-wheel building units, which cannot be inter-connected by structurally rigid linear ligands. Dabco is an apparent exception due to its aliphatic nature and the formation of rather strong metal-ligand ...
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<p>DIBc, a nanochelating-based nano metal-organic framework, shows anti-diabetic effects in high-fat diet and streptozotocin-induced diabetic rats</p>
... Aims: Despite daily increase in diabetic patients in the world, currently approved medications for this disease, at best, only reduce its progression speed. Using novel technologies is a solu- tion for synthetizing more ...
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Mn-Metal Organic Framework as Heterogenous Catalyst for Oxidation of Alkanes and Alkenes
... Manganese metal-organic framework (Mn-MOF) containing Mn 2+ ions, benzenetricarboxylic acid (BTC) and N,N-dimethylformamid (DMF) was prepared and used as catalyst for oxidation of alkenes such as ...
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Synthesis and Electrospraying of Nanoscale MOF (Metal Organic Framework) for High Performance CO2 Adsorption Membrane
... temperature synthesis of MOF had found to produce un- desirable by-products such as metal oxides, room temperature synthesis has become a considerable solution for that [19]. Surface and size control of MOFs have ...
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Reversible adsorption and confinement of nitrogen dioxide within a robust porous metal organic framework
... Synchrotron powder X-ray diffraction PXRD data collected upon NO2 adsorption at 298 K revealed two independent binding sites I and II, assigned as NO2 and N2O4 molecules, respectively wi[r] ...
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Synthesis of patterned enzyme–metal–organic framework composites by ink-jet printing
... Ink 4 was used to dissolve BSA at a concentration of 50 mg/mL. Then the protein ink was loaded in Y car- tridge and printed on PET film with a predesigned pat- tern. After drying the film with printed protein pattern at ...
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Rotaxane Ligands for Incorporation into Metal-Organic Framework Materials
... (SSNMR) of a specially designed Zn(II) based MOF, UWDM-4 (University of Windsor Dynamic Material), demonstrated translational motion of a [2]rotaxane—a MIM (mechanically interlocked molecule) linker with one ring and two ...
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Scalable continuous solvothermal synthesis of metal organic framework (MOF-5) crystals
... [27]. MOF-5 has been a material of great interest in the scientific literature due to the high surface area, since the structure was first published in 1999. Although they have been recently surpassed in some key ...
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