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ONE-DIMENSIONAL COORDINATION POLYMER

catena Poly­[[silver(I) μ 2,5 bis­(4 pyridyl) 1,3,4 oxa­diazo­le] nitrate], a one dimensional coordination polymer exhibiting a double chain supramolecular structure through hydrogen bonds

catena Poly­[[silver(I) μ 2,5 bis­(4 pyridyl) 1,3,4 oxa­diazo­le] nitrate], a one dimensional coordination polymer exhibiting a double chain supramolecular structure through hydrogen bonds

... pyridine-based ligands and metal ions has generated a wide variety of solid-state architectures (Hagrman et al., 1999). Recently, an interesting angular dipyridyl ligand, 2,5-bis(4- pyridyl)-1,3,4-oxadiazole, which could ...

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Crystal structure of the BaII based CoII containing one dimensional coordination polymer poly[[aqua{μ4 2,2′ [(4,10 di­methyl 1,4,7,10 tetra­aza­cyclo­do­decane 1,7 di­yl)bis­(methyl­idene)]bis­­(4 oxo 4H pyran 3 olato)}­perchloratocobaltbarium] perchlorat

Crystal structure of the BaII based CoII containing one dimensional coordination polymer poly[[aqua{μ4 2,2′ [(4,10 di­methyl 1,4,7,10 tetra­aza­cyclo­do­decane 1,7 di­yl)bis­(methyl­idene)]bis­­(4 oxo 4H pyran 3 olato)}­perchloratocobaltbarium] perchlorate]

... anions are located in the space between the chains. Weak C—H O hydrogen bonds involving both coordinating and non-coordinating perchlorate anions build the whole crystal architecture. To our knowledge, this is the first ...

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Orientational disorder in the one dimensional coordination polymer catena poly[[bis­­(acetyl­acetonato κ2O,O′)cobalt(II)] μ 1,4 di­aza­bi­cyclo­[2 2 2]octane κ2N1:N4]

Orientational disorder in the one dimensional coordination polymer catena poly[[bis­­(acetyl­acetonato κ2O,O′)cobalt(II)] μ 1,4 di­aza­bi­cyclo­[2 2 2]octane κ2N1:N4]

... This polymer is essentially a one-dimensional coordination polymer, the only structural motif that is present being based on the Co II coordination ...

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[Cd(phen)2{MoO4}]·H2O, a one dimensional coordination polymer with bridging molybdate groups

[Cd(phen)2{MoO4}]·H2O, a one dimensional coordination polymer with bridging molybdate groups

... 1998). In these complexes, the organonitrogen components act not only as charge compensators and space-filling constituents, but also as ligands bonded directly to a secondary metal center. We report here the synthesis ...

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A one dimensional coordination polymer: catena poly­[[tri­aqua­pyridine­cobalt(II)] μ sulfato]

A one dimensional coordination polymer: catena poly­[[tri­aqua­pyridine­cobalt(II)] μ sulfato]

... include coordination bonding and hydrogen-bonding interac- ...a one-dimensional coordination polymer, [Co(C 5 H 5 N)(H 2 O) 3 ...

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A non centrosymmetric one dimensional coordination polymer: catena[[(4,7 phenanthrolin 4 ium κN7)(thio­cyanato κS)copper(I)] μ thio­cyanato κ2N:S]

A non centrosymmetric one dimensional coordination polymer: catena[[(4,7 phenanthrolin 4 ium κN7)(thio­cyanato κS)copper(I)] μ thio­cyanato κ2N:S]

... Non-centrosymmetric coordination polymers have been recently investigated successfully as non-linear optical (NLO) materials for second harmonic generation (Evans & Lin, ...

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A new one dimensional coordination polymer: {[Cu(C10H9NO5S)(H2O)]·H2O}n

A new one dimensional coordination polymer: {[Cu(C10H9NO5S)(H2O)]·H2O}n

... form a one-dimensional in®nite chain structure, is 2.877 (3) AÊ. This bond is much longer than a normal coordinate bond length, so can be called a partly coordinated bond (Procter et al., 1968). The Cu atom ...

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catena Poly[[di­bromo­zinc(II)] μ 1,2 bis­­(4 pyrid­yl)ethane], a one dimensional coordination polymer

catena Poly[[di­bromo­zinc(II)] μ 1,2 bis­­(4 pyrid­yl)ethane], a one dimensional coordination polymer

... networked coordination polymers is of great current interest due to their potential properties in ion exchange, gas storage, molecular sensing and catalysis (Batten & Robson, 1998; Barnett & Champness, ...

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Crystal structure of a one dimensional coordination polymer of tin(IV) bromide with 1,4 di­thiane

Crystal structure of a one dimensional coordination polymer of tin(IV) bromide with 1,4 di­thiane

... S:S 0 ]}, represents the first 1,4-dithiane complex with tin as coordination centre. The asymmetric unit consist of half a formula unit with the tin(IV) atom at the centre of symmetry at 0,0,1/2 (Wyckoff symbol b) ...

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A one dimensional coordination polymer with alternating CeN3O6 and SrNO7 polyhedra

A one dimensional coordination polymer with alternating CeN3O6 and SrNO7 polyhedra

... The cerium coordination polyhedron is essentially same as that found in the calcium analog. As expected, the Sr—(O,N) distances are longer (by about 0.1 Å) than the Ca—(O,N) distances. The structure is essentially ...

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A one dimensional coordination polymer of copper(II) with 2 pyrazine­carboxyl­ate

A one dimensional coordination polymer of copper(II) with 2 pyrazine­carboxyl­ate

... The coordination environment of the copper(II) ion is distorted octahedral, arising from an N,O- bidentate 2-pyrazinecarboxylate ligand, an N atom from a symmetry-related 2-pyrazinecarboxylate ligand, a bidentate ...

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CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX

CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX

... exhibits one-dimensional coordination polymer structure, which is composed of cyanoacetate bridged lanthanum(III) ...9 coordination surrounding of La cation is completed by oxygen atoms ...

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Crystal structure of catena poly[[di­iodidomer­cury(II)] μ 2,2′ di­thio­bis­­(pyridine N oxide) κ2O:O′]1

Crystal structure of catena poly[[di­iodidomer­cury(II)] μ 2,2′ di­thio­bis­­(pyridine N oxide) κ2O:O′]1

... (pyridine N-oxide) as a spacer ligand (i.e. involving both pyridine N-oxide moieties as coordinating groups). As a continuation of this work, we herein report the crystal struc- ture of a one-dimensional ...

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A one dimensional nickel(II) coordination polymer with pyridine and isophthalate

A one dimensional nickel(II) coordination polymer with pyridine and isophthalate

... phenanthroline (phen) and its analogues (Shen et al., 2005; Ma et al., 2004; Chen & Liu, 2002). However, structure reports on pyridine acting as the secondary monodentate N-donor ligand are not common. In this paper, ...

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The first coordination compound of 6 fluoro­nicotinate: the crystal structure of a one dimensional nickel(II) coordination polymer containing the mixed ligands 6 fluoro­nicotinate and 4,4′ bi­pyridine

The first coordination compound of 6 fluoro­nicotinate: the crystal structure of a one dimensional nickel(II) coordination polymer containing the mixed ligands 6 fluoro­nicotinate and 4,4′ bi­pyridine

... C11) rings, respectively]. The strong hydrogen bonds link the polymeric chains and the lattice water molecules into an infinite three-dimensional network. The structure can be better analysed if viewed down the ...

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The one dimensional zigzag coordination polymer catena poly[[[tri­aqua­zinc(II)] μ N,N′ (benzene 1,4 dicarboxamido)di­acetato κ2O:O′] dihydrate]

The one dimensional zigzag coordination polymer catena poly[[[tri­aqua­zinc(II)] μ N,N′ (benzene 1,4 dicarboxamido)di­acetato κ2O:O′] dihydrate]

... As shown in Fig. 1, the asymmetric unit of (I) consists of one-half of a ligand dianion, one-half of a Zn II ion, one and a half coordinated water molecules, and one uncoordinated water ...

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A one dimensional CoII coordination polymer exhibiting an unusual conformation for 1,2 bis­(4 pyridyl)­ethane

A one dimensional CoII coordination polymer exhibiting an unusual conformation for 1,2 bis­(4 pyridyl)­ethane

... We are interested in the synthesis of novel coordination compounds which contain both carboxylate and 4-pyridyl groups coordinated to metal centres (Almeida Paz et al., 2002). In particular, the use of ...

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A two dimensional copper(I) coordination polymer based on 1 [2 (cyclo­hexyl­sulfan­yl)eth­yl]pyridin 2(1H) one

A two dimensional copper(I) coordination polymer based on 1 [2 (cyclo­hexyl­sulfan­yl)eth­yl]pyridin 2(1H) one

... metric unit comprises two ligand molecules, four copper(I) ions and four iodide ions. Interestingly, the O atoms are bound to the soft copper(I) ions. The stair- step clusters of Cu and I atoms in the asymmetric unit are ...

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Crystal structure of a one dimensional helical type silver(I) coordination polymer: catena poly[[silver(I) μ N (pyridin 4 ylmeth­yl)pyridine 3 amine κ2N:N′] nitrate di­methyl sulfoxide disolvate]

Crystal structure of a one dimensional helical type silver(I) coordination polymer: catena poly[[silver(I) μ N (pyridin 4 ylmeth­yl)pyridine 3 amine κ2N:N′] nitrate di­methyl sulfoxide disolvate]

... of coordination geometries for the Ag I cation, but also their potential applications as functional materials (Lee et ...I coordination chemistry based on symmetrical dipyridyl ligands with nitrogen donor ...

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One dimensional ladder gallium coordination polymer

One dimensional ladder gallium coordination polymer

... A large number of MOF-containing divalent transition- metal ions have been described (Stock & Biswas, 2012; Devic & Serre, 2014). Examples of CPs/MOFs containing main- group elements, such as Al 3+ , Ga 3+ , or ...

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