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supramolecular polymers

Luminescent self assembled supramolecular polymers and microspheres based on Benzene 1,3,5  tricarboxamide (BTA) derivatives

Luminescent self assembled supramolecular polymers and microspheres based on Benzene 1,3,5 tricarboxamide (BTA) derivatives

... As discussed above, BTA derivatives self-assemble by co-operative three fold helical hydrogen bonding. 123, 147 Many versatile derivatives of BTA have been synthesised by incorporating different functional groups such as ...

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Side-chain supramolecular polymers employing conformer independent triple hydrogen bonding arrays

Side-chain supramolecular polymers employing conformer independent triple hydrogen bonding arrays

... of supramolecular chem- ...3 supramolecular adhesives, 4 and sca ff olds for tissue ...requiring supramolecular aggregation ...for supramolecular materials assembly has found widespread ...in ...

8

Double Helical Hydrogen-Bonded AAA-DDD Complexes and Supramolecular Polymers

Double Helical Hydrogen-Bonded AAA-DDD Complexes and Supramolecular Polymers

... demonstrated that two complementary molecules may interact via amidinium-carboxylate salt bridges in a sequence dependent manner resembling the hybridization of ss-DNA. Our group has reported the formation of a double ...

187

Modulation of the cooperativity in the assembly of multistranded supramolecular polymers

Modulation of the cooperativity in the assembly of multistranded supramolecular polymers

... Many molecules assemble into long 1D structures by means of weak intermolecular interactions, leading to supramolecular polymers. 1-3 On account of the weak intermolecular interactions that hold the ...

9

Multivalence cooperativity leading to “all or nothing” assembly: the case of nucleation growth in supramolecular polymers

Multivalence cooperativity leading to “all or nothing” assembly: the case of nucleation growth in supramolecular polymers

... (supramolecular polymers here), even if the building blocks are not ...double-stranded supramolecular polymers formed from Co-metalloporphyrin and bi-pyridine building ...of polymers ...

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Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity

Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity

... nation polymers is far less studied, perhaps due to their inability to withstand desolvation or a lack of structural data associated with the resulting amorphous ...cular polymers for gas adsorption ...

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Periodic "stick-slip" transition within a continuum model for entangled supramolecular polymers

Periodic "stick-slip" transition within a continuum model for entangled supramolecular polymers

... telechelic polymers showed the following results: (i) stress maxima at a constant strain, (ii) shear banding [33], (iii) oscillatory/chaotic transient stress response [36, ...

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Linear shear and nonlinear extensional rheology of unentangled supramolecular side-chain polymers

Linear shear and nonlinear extensional rheology of unentangled supramolecular side-chain polymers

... for supramolecular polymers with side-chain functional groups, relatively few studies have been reported ...the supramolecular interactions originate from association of ionic groups covalently ...

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Linear shear and nonlinear extensional rheology of unentangled supramolecular side-chain polymers

Linear shear and nonlinear extensional rheology of unentangled supramolecular side-chain polymers

... telechelic polymers [77, 78] and unentangled [41, 79–82] or entangled [83–87] supramolecular ...unentangled polymers with supramolecular side-groups, the polymer type relevant to our work, the ...

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Supramolecular Materials

Supramolecular Materials

... living cells and that the siRNA was had intracellular activity. Cytotoxicity was low, although there was scope for further optimisation. Clearly this work builds on well-known cationic lipid strategies to nucleic acid ...

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Supramolecular iridium(III) assemblies

Supramolecular iridium(III) assemblies

... By combining the blue-emitting 1,8-naphtalimide-based gelator G1 with the orange-emitting iridium complex G2 (Figure 14a), Yi and co-workers[101] reported a white-emitting two- components supramolecular gel. G1 ...

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Vol 2, No 10 (2013)

Vol 2, No 10 (2013)

... of polymers in controlling corrosion of metals in various corrosive environment such as acidic medium 2,3,10-12,16-18,21,23,25,27,29,33-36,38,43-44,46-48,50-52,59- 66,68,70-73,77,78,80,82,83,85-86,90-93,95,97,100, ...

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Supramolecular Devices and Materials

Supramolecular Devices and Materials

... unique supramolecular functionalities that are not apparent at either the atomic scale or micrometre scale, and are also the size range at which biological compounds operate (Figure ...

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Crystal structures of (2,2′ bi­pyridyl κ2N,N′)bis­­[N,N bis­­(2 hy­droxy­eth­yl)di­thio­carbamato κ2S,S′]zinc dihydrate and (2,2′ bi­pyridyl κ2N,N′)bis­­[N (2 hy­droxy­eth­yl) N iso­propyl­di­thio­carbamato κ2S,S′]zinc

Crystal structures of (2,2′ bi­pyridyl κ2N,N′)bis­­[N,N bis­­(2 hy­droxy­eth­yl)di­thio­carbamato κ2S,S′]zinc dihydrate and (2,2′ bi­pyridyl κ2N,N′)bis­­[N (2 hy­droxy­eth­yl) N iso­propyl­di­thio­carbamato κ2S,S′]zinc

... tronic structure that enhances the electron density in the chelate ring (Tiekink & Zukerman-Schpector, 2011). This factor explains the strong chelation ability of the dithio- carbamate ligand and at the same time ...

14

Supramolecular nanotheranostics based on pillarenes

Supramolecular nanotheranostics based on pillarenes

... multifunctional supramolecular nanotheranostic material via LbL strategy, in order to improve the efficiency of cancer ...in supramolecular nanovalves to regulate drug ...multifunctional ...

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Supramolecular photoactivatable anticancer hydrogels

Supramolecular photoactivatable anticancer hydrogels

... A lthough hydrogels are mostly water, they behave like solids due to three-dimensional networks of cross-links within them. Hydrogels often consist of cross-linked polymers and have the properties of colloidal ...

5

A Supramolecular Approach for Liver Radioembolization

A Supramolecular Approach for Liver Radioembolization

... Hepatic radioembolization therapies can suffer from discrepancies between diagnostic planning (scout-scan) and the therapeutic delivery itself, resulting in unwanted side-effects such as pulmonary shunting. We reasoned ...

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Supramolecular dendritic liquid quasicrystals

Supramolecular dendritic liquid quasicrystals

... in supramolecular dendrimers, it may be possible to achieve a further increase of two orders of magnitude by using appropriately designed self-assembling dendrons, block copolymers or ...

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Shaping and Structuring Supramolecular Gels

Shaping and Structuring Supramolecular Gels

... The precise shaping and patterning of LMWG-containing gels will increase the complexity of supramolecular gels, and hence enable more sophisticated outcomes than the rheological uses they have already found in ...

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A supramolecular protein chaperone for vaccine delivery

A supramolecular protein chaperone for vaccine delivery

... The supramolecular protein chaperone ...The supramolecular protein chaperone interacted with antigens by physical interactions, which facilitated both the cellular uptake of protein antigens and the release ...

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