[PDF] Top 20 Self assembly of cyclic polymers

... of cyclic poly- mers have been exploited in a variety of ...of cyclic diblock co- polymers to prepare thin films for lithography applications, where the reduced volume of the cyclic polymer ... See full document

... equivalent cyclic diblock or linear triblock. In addition, because cyclic polymers possess smaller hydrodynamic volumes than linear polymers, the assembly of the cyclic diblock ... See full document

... These cyclic polymers are highly amenable for imaging by STM, both under UHV, when deposited by electrospray, and under ambient conditions, deposited from ...biomimetic self-assembly, and the ... See full document

... persity polymers than RAFT emulsion polymerization. The diblock copolymers self- assembled in water to form micelles, as analyzed by light scattering (LS) and transmission electron microscopy ...the ... See full document

... We believed that as the polymer chain grew, monomer addition became increasingly more difficult due to steric considerations. Consequently, even at the early stages of polymerization in the presence of high monomer ... See full document

... of self-assembly is expected to be the same for positively and negatively charged compounds, a number of factors are expected to affect the solubility and hydrophilicity of the final compounds, and thus ... See full document

... A new family of amphiphilic block copolymers, known as DNA block copolymers (DBCs), have been described, which are composed of a hydrophobic synthetic polymer component attached to a single-stranded (ss) DNA. 51–53 The ... See full document

... block polymers can adopt a surprising degree of ...block polymers, the ratio of looping and bridging blocks significantly impacts the mechanical performance and other physical ...block polymers. The ... See full document

... this self-assembly is still Adleman’s original technique for creating duplex DNA representing paths through a ...with self-assembly alone? To answer this question, I use the frame- work of ... See full document

... final assembly. Here, 1-arm, 2-arm, and 3-arm conjugated cyclic peptides (Compounds 10, 11, and 12, respectively) were dissolved in either deuterated N,N-Dimethylformaldehyde (d- DMF), deuterated dimethyl ... See full document

... 40 nm in diameter. As the polymers 3.04-3.06 have the same hydrophobic end group as the polymers 2.09 and 2.10, the core sizes should be the same. The cryo-TEM and SANS analysis in Chapter 2 indicated the ... See full document

... on self-assembly principles, theories, structures and functionalisation of the amphiphilic ...undergo self-assembly in order to minimise energetically unfavourable hydrophobe/water ... See full document

... these polymers are dynamic structures , i.e., capable of self-organise into large scale assemblies in response to specific ...dynamic assembly of microtubules and actin filaments, ... See full document

... that form chains through magnetic interactions. Cryogenic TEM measurements of solutions of iron oxide NPs by Philipse and coworkers showed that magnetic NPs spontaneously form disordered chains in solution in zero ... See full document

... degradable polymers needing a more specific stimulus to achieve a more predictable degradation has been resolved with the work on stimuli-responsive polymers ...degradable polymers that have emerged ... See full document

... prepare polymers containing nucleobases ...of polymers containing nucleobase functionalities via RAFT technique, which can enrich the synthesis of nucleobase ... See full document

... the self-assembly of these macromolecules, as lower molecular weight brush BCPs have been shown to achieve thermal equilibrium more rapidly than those with higher molecular ... See full document

... bottlebrush polymers – through successfully obtaining the highly coveted scattering data with contrast matched ...bottlebrush polymers in good and theta solvent (Chapter ... See full document

... metallosupramolecular polymers for smart materials 20 – 22 ; however, the predominant approach has consisted of linking single metal ions into the polymeric backbone, as the incorporation of large pre-organized ... See full document

... assembled under the same conditions as the previous sample (at 20 mg mL 1 , 20 vol% THF with the slow addition of water) (see ESI† for detailed procedure). This copolymer was fully soluble in THF aer a few minutes of ... See full document